Reassessment of the garnet-clinopyroxene Fe−Mg exchange thermometer: I. Evaluation of the Pattison and Newton (1989) experiments

This is Part 1 of a two-part study on the garnet(Grt)-clinopyroxene(Cpx) Fe−Mg exchange equilibrium widely used in geothermometry of amphibolites, granulites and eclogites. The experimental data set previously published by Pattison and Newton (PN) on this equilibrium comprises potentially the largest source of data used for extraction of thermodynamic properties for Grt and Cpx and for formulation of a new thermometer expression (Part 2 of this study). However, the experiments suggested unusual Grt and Cpx solution properties and resulted in a geothermometer expression that generally returns low temperatures for granulites. To verify the reliability of the experiments, and to test the experimental technique of Grt buffering used in the PN study, 69 of the 125 PN runs were reanalysed using wavelength dispersive spectroscopic analysis guided by backscattered electron images. Special attention was given to analysis of compositional changes in Grt in addition to Cpx. With minor exceptions, the reanalysis supports the analytical results of the original PN study. The mechanism of equilibration in the runs was a multicomponent solution-precipitation process involving dissolution of metastable Grt and Cpx starting materials and precipitation of newly formed Cpx and Grt, the latter assumed to represent equilibrim compositions. The experiments cannot be regarded either as reversed or as strictly bracketing. Nevertheless, Cpx compositional parameters, including Mg#, Na, Ca and Al, show the same smooth variations with temperature, pressure and composition as found by PN, suggestive of a close approach to equilibrium. Grt in run products retained the moderate heterogeneity of the starting Grt, although there are subtle compositional trends indicating small changes in Grt Mg# consistent with mass balance constraints. These results uphold the essential validity of the technique of Grt buffering used in the experiments. Nevertheless, it is possible that the final Grt compositional may not coincide with the nominal starting Grt compositions, requiring assignment of compositional uncertainties to Grt for purposes of thermodynamic modelling of the data. Cpx analyses also require assignment of non-zero compositional uncertainties.     

Noble gases dissolved in groundwater in a volcanic aquifer: Helium isotopes in the Kumamoto Plain

This study Investigates a tracing method using dissolved noble gases to survey the groundwater flow in a large groundwater basin. The tracing method is based on measuring the concentrations of noble gases and the ratio of helium isotopes in groundwater samples. Since it is very difficult to detect trace amounts of noble gases and helium with high accuracy in a 15-ml groundwater sample, dissolved gases were extracted and purified, then a high-resolution mass spectrometer was used for measurement and comparison with standard samples. We used this method with samples from a confined aquifer formed by the deposition of pyroclastic flow in the Kumamoto Plain on the west side of Mt. Aso in central Kyushu, Japan. The groundwater basin under the plain is divided into four small basins, based on the helium concentrations and isotope ratios, with two major groundwater flows. One flow is buried by the Aso pyroclastic flow along the old Kase River; the other is along the Tsuboi River Valley. These two groundwater flows were identified from the different helium isotope-ratios. The helium component from the deep mantle is mixed into the groundwater under the Kumamoto Plain. Finally, data on the concentrations and ratios of³He to⁴He in groundwater samples were used to determine the location of faults in the volcanic aquifer.     

Centuries of artificial recharge on the southern edge of the Sierra Nevada (Granada,Spain)

In the Alpujarra (southern Spain), every year between the March and June, an ancestral practice continues in the form of diverting water from the rivers by way of an extensive network of irrigation channels (acequias) to well-defined, highly permeable areas. This practice, known ascareos, constitutes an ancient example of artificial recharge. The objective is to guarantee a supply of drinking water during the dry months, as well as improve the physicochemical characteristics of the water. In addition, this system helps maintain moisture in the immediate environment, and thus has a positive effect on local vegetation.     

Grim4-C1, -C2p: combination solutions of the global earth gravity field

On the basis of the GRIM4-S1 satellite-only Earth gravity model, being accomplished in a common effort by DGFI and GRGS, a combination solution, called GRIM4-C1, has been derivcd using 1° × 1° mean gravity anomalies and 1° × 1° Seasat altimeter derived mean geoid undulations. In the meantime improvements could be achieved by incorporating more tracking data (GEOSAT, SPOT2-DORIS) into the solution, resulting in the two new parallel versions, the satellite-only gravity model GRIM4-S2 and the combined solution GRIM4-C2p (preliminary). All GRIM4 Earth gravity models cover the spectral gravitational constituents complete up to degree and order 50.In this report the emphasis is on the discussion of the combined gravity models: combination and estimation techniques, capabilities for application in precise satellite orbit computation and accuracies in long wavelength geoid representation. It is shown that with the new generation of global gravity models general purpose satellite-only models are no longer inferior to combination solutions if applied to satellite orbit restitution.     

Atmospheric electricity measurements over the Indian Ocean

Summary Results of measurements of the atmospheric electrical conductivity and potential gradient made during the sixth Scientific Cruise of the Indian Oceanographic Ship INS Kistna in the Bay of Bengal during February–March 1963 are presented. Observations were made when the skies were generally clear and the sea calm, in the geographical area 8°N to 17°N and 80°E to 95°E, on the outward journey of INS Kistna from Madras (80°E, 13°N) to Port Blair (93°E, 12°N) and on the return journey to Madras.Over the ocean where there are no local sources of pollution, the measured values of conductivity and potential gradient are in agreement with theoretical values, assuming that an ion equilibrium exists, that ions are destroyed primarily by collision with small ions of opposite sign and that small ions are produced only by cosmic radiation. The values of electrical conductivity obtained are generally of the same order as those to be expected from theoretical considerations and in general agreement with those obtained during the Carnegie cruises in the Indian Ocean in 1920. There are, however, significant variations near the coast where the electric structure above the ocean is affected by continental sources of pollution. Conductivity values near the land are about half that in the unpolluted air over the ocean but prevailing winds prevent the extension of pollution beyond 100–200 km from the coast in this season.

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Zusammenfassung Es wird über Messungen der luftelektrischen Leitfähigkeit und des Potentialgefälles berichtet, welche während der Sechsten Wissenschaftlichen Kreuzfahrt des indischen Ozeanographischen Forschungsschiffes Ins Kistna in der Bengalischen Bucht im Februar und März 1963 ausgeführt wurden. Die Beobachtungen sind im allgemeinen bei klarem Himmel und ruhiger See gemacht worden, und zwar in dem geographischen Bereich zwischen 8 und 17°N und 80 und 95°E während der Ausfahrt der INS Kistna von Madras (80°E, 13°N) nach Port Blair (93°E, 12°N) und auf der Rückreise nach Madras. In den Bereichen des Ozeans, in denen keine örtlichen Pollutionsquellen bestehen, stimmen die gemessenen Werte der Leitfähigkeit und des Potentialgefälles mit den theoretischen Werten überein, die man erhält, wenn man annimmt, dass ein Ionengleichgewicht besteht, dass die schnellen Ionen vorwiegend durch Zusammenstoss mit schnellen Ionen des entgegengesetzten Vorzeichens vernichtet werden, und dass die schnellen Ionen nur durch die kosmische Höhenstrahlung erzeugt werden. Die Werte der Leitfähigkeit stimmen mit denen überein, die man aus theoretischen Überlegungen gewinnt, und auch mit denen, die während der Kreuzfahrten des Forschungsschiffes Carnegie im Indischen Ozean im Jahre 1920 gemessen Küste sind jedoch bedeutsame Abweichungen festzustellen, wo die elektrischen Verhältenisse über dem Ozean durch Pollutionsquellen auf dem Lande beeinflusst werden. Die Leitfähigkeitswerte nahe dem Land sind nur ungefähr halb so gross wie die in der pollutionsfreien Luft des offenen Ozeans-jedoch haben die während der Mess-Jahreszeit vorherrschenden Winde eine Ausbreitung der Pollutionszone auf einen Bereich von 100 bis 200 km von der Küste beschränkt.

     

Measurement of small ions and condensation nuclei over the sea near the land

Summary To study the ionization equilibrium, simultancous measurements of the concentration of small ions (n), concentration of condensation nuclei (Z), and the diffusion coefficient of condensation nuclei (D) have been carried out over the sea. If we take the variation ofD into consideration, the correlation among them was found to be well expressed by the simple formula;q=n Z. The dependence of the effective attachment coefficient of small ions () upon the size of nuclei (2r) were also studied, and was found to correlate well withD orr. Slight differences of the dependence of uponD orr over the sea from that over the land seem to be well explained by the difference of charged states of nuclei over the sea and land.

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Zusammenfassung Zur Untersuchung des Ionisationsgleichgewichts wurden gleichzeitige Messungen der Konzentration schneller Ionen (n), der Konzentration der Kondensationskerne (Z) und des Diffusions-Koeffizienten der Kondensationskerne (D) über dem Meere ausgefürt. Unter Berücksichtigung des Diffusions-Koeffizienten (D) konnte der Zusammenhang zwischen den beiden anderen Grössen recht gut durch eine einfache Formel ausgedrückt werden:q=n Z. Die Abhängigkeit des wirksamen Anlagerungskoeffizienten für schnelle Ionen () von der Grösse der Kondensationskerne (2r) wurde ebenfalls untersucht, und es wurde gefunden, dass recht gut mitD oderr korreliert. Kleinere Unterschiede in der Abhängigkeit von vonD oderr, welche bei einem Vergleich der Messungen über See und über Land festgestellt wurden, liessen sich gut durch den Unterschied der geladenen Zustände der Kondensationskerne über See und Land erklären.

     

Tensile strength of rock by the double-punch method

Summary This paper presents an experimental study of the newly developed double-punch test method for determination of the tensile strength of rocks. The method for preparation of test specimens and test procedure is reported and discussed. Comparisons of tensile strength determined from double-punch and split-cylinder tests are also presented.With 5 Figures     

Estimation of long wave radiation by an empirical method

Summary Utilising two years data collected at two tropical coastal stations, Madras (13°04N, 80°15E) and Waltair (17°42N, 83°18E) and for one tropical continental station, Nagpur (21°09N, 79°07E), the authors have re-evaluated the constants ofBrunt's regression equation. Analyses of the observations for Waltair and Nagpur show good correlation coefficients (r) between the values of the effective emissivity of the atmosphere (the effective emissivity is the ratio of incoming long-wave sky radiation at the surfaceR _s , to black body radiation T ⁴) and the square root values of surface vapour pressuree (mb). The value ofr for Waltair from radiometer observations is 0.98. It is also determined for Waltair and Nagpur from Ångström compensation pyrgeometer observations as 0.83 and 0.91 respectively. A low correlation co-efficient 0.56 is obtained for Madras. It might be due to higher surface vapour pressure values at Madras than at Waltair and Nagpur. The applicability of the reduced regression equations are examined for different years for the different stations. The agreement between the computed values with the new regression equations and the observed long-wave sky radiation at the surface seems to be quite good.