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81.
Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments 总被引:1,自引:0,他引:1
Pyeong-Koo Lee Min-Ju Kang Ho Young Jo Sang-Hoon Choi 《Environmental Earth Sciences》2012,66(7):1909-1923
The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area. 相似文献
82.
The structures of sodium silicate and aluminosilicate glasses quenched from melts at high pressure (6-10 GPa) with varying degrees of polymerization (fractions of nonbridging oxygen) were explored using solid-state NMR [17O and 27Al triple-quantum magic-angle spinning (3QMAS) NMR]. The bond connectivity in melts among four and highly coordinated network polyhedra, such as [4]Al, [5,6]Al, [4]Si, and [5,6]Si, at high pressure is shown to be significantly different from that at ambient pressure. In particular, in the silicate and aluminosilicate melts, the proportion of nonbridging oxygen (NBO) generally decreases with increasing pressure, leading to the formation of new oxygen clusters that include 5- and 6-coordinated Si and Al in addition to 4-coordinated Al and Si, such as [4]Si-O-[5,6]Si, [4]Si-O-[5,6]Al and Na-O-[5,6]Si. While the fractions of [5,6]Al increase with pressure, the magnitude of this increase diminishes with increasing degrees of ambient-pressure polymerization under isobaric conditions. Incorporating the above structural information into models of melt properties reproduces the anomalous pressure-dependence of O2− diffusivity and viscosity often observed in silicate melts. 相似文献
83.
We have characterized the adsorption of Suwannee River humic acid (SRHA) and Cu(II) on calcite from preequilibrated solutions at pH 8.25. Sorption isotherms of SRHA on calcite follow Langmuir-type behavior at SRHA concentrations less than 15 mg C L−1, whereas non-Langmuirian uptake becomes evident at concentrations greater than 15 mg C L−1. The adsorption of SRHA on calcite is rapid and mostly irreversible, with corresponding changes in electrostatic properties. At pH 8.25, Cu(II) uptake by calcite in the presence of dissolved SRHA decreases with increasing dissolved SRHA concentration, suggesting that formation of Cu-SRHA aqueous complexes is the primary factor controlling Cu(II) sorption at the calcite surface under the conditions of our experiments. We also observed that surface-bound SRHA has little influence on Cu(II) uptake by calcite, suggesting that Cu(II) coordinates to calcite surface sites rather than to surface-bound SRHA.Cu K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine-structure (EXAFS) spectroscopic results show that the local coordination of Cu adsorbed at the calcite surface is very similar in the presence and absence of SRHA. Ca backscatterers at ∼3.90 Å indicate that Cu(II) forms tetragonally distorted inner-sphere adsorption complexes in both binary and ternary systems. Subtle differences in the XANES and EXAFS between binary sorption samples and ternary sorption samples, however, prevent us from ruling out the formation of ternary Cu-SRHA surface complexes. Our findings demonstrate that SRHA plays an important role in controlling the fate and transport of Cu(II) in calcite-bearing systems. 相似文献
84.
Il-Sung Zo Joon-Bum Jee Kyu-Tae Lee Bu-Yo Kim 《Asia-Pacific Journal of Atmospheric Sciences》2016,52(4):405-412
Preliminary analysis with a solar radiation model is generally performed for photovoltaic power generation projects. Therefore, model accuracy is extremely important. The temporal and spatial resolutions used in previous studies of the Korean Peninsula were 1 km × 1 km and 1-h, respectively. However, calculating surface solar radiation at 1-h intervals does not ensure the accuracy of the geographical effects, and this parameter changes owing to atmospheric elements (clouds, aerosol, ozone, etc.). Thus, a change in temporal resolution is required. In this study, one-year (2013) analysis was conducted using Chollian geostationary meteorological satellite data from observations recorded at 15-min intervals. Observation data from the intensive solar site at Gangneung-Wonju National University (GWNU) showed that the coefficient of determination (R²), which was estimated for each month and season, increased, whereas the standard error (SE) decreased when estimated in 15-min intervals over those obtained in 1-h intervals in 2013. When compared with observational data from 22 solar sites of the Korean Meteorological Administration (KMA), R2 was 0.9 or higher on average, and over- or under-simulated sites did not exceed 3 sites. The model and 22 solar sites showed similar values of annual accumulated solar irradiation, and their annual mean was similar at 4,998 MJ m?2 (3.87 kWh m?2). These results show a difference of approximately ± 70 MJ m?2 (± 0.05 kWh m?2) from the distribution of the Korean Peninsula estimated in 1-h intervals and a higher correlation at higher temporal resolution. 相似文献
85.
A monotonic transport algorithm for a high-order time integration scheme is described in this paper. The algorithm is a modified version of an existing high-order time integration scheme, and is tested using a simple one-dimensional pulse and two-dimensional deformational flows. It is found that the new formulation can remove the error, caused by new maxima/minima and excessive smoothing, which occurs in scalar transport using the original extrapolation scheme. The results show that there may be potential for the high-order time integration scheme to be applied in numerical weather prediction models. 相似文献
86.
LEE Ben 《中国地球化学学报》2011,30(2):204-216
The Dehe granitic pluton intruded the Xiahe Group which is in the core complex of the North Qinling Orogenic Belt(NQOB).It shows gneissic bedding and possesses typical S-type granite minerals such as muscovite and garnet.LA-ICP-MS U-Pb isotopic dating of the Dehe granite yielded a weighted average age of 925±23 Ma which represents the emplacement age of the pluton.Most of the εHf(t) values are negative,and the two-stage model ages are consistent with the age of the Qinling Group.The isotope data show that the Dehe granite was formed in the following geological setting:in the syn-collision setting of the NQOB in the Neoproterozoic,crustal thickening induced partial melting of materials derived from the Qinling complex,and then the maga upwelled and intruded into the Xiahe Group.The formation of the Dehe S-type granite implied the occurrence of a convergent event in the QOB during the Neoproterozoic. 相似文献
87.
Andesite and dacite genesis via contrasting processes: the geology and geochemistry of El Valle Volcano,Panama 总被引:3,自引:0,他引:3
Mare J. Defant Lee F. Clark Robert H. Stewart Mark S. Drummond Jelle Z. de Boer René C. Maury Hervé Bellon Thomas E. Jackson Juan F. Restrepo 《Contributions to Mineralogy and Petrology》1991,106(3):309-324
The easternmost stratovolcano along the Central American arc is El Valle volcano, Panama. Several andesitic and dacitic lava
flows, which range in age 5–10 Ma, are termed the old group. After a long period of quiescence (approximately 3.4 Ma), volcanic
activity resumed approximately 1.55 Ma with the emplacement of dacitic domes and the deposition of dacitic pyroclastic flows
0.9–0.2 Ma. These are referred to as the young group. All of the samples analyzed are calc-alkaline andesites and dacites.
The mineralogy of the two groups is distinct; two pyroxenes occur in the old-group rocks but are commonly absent in the young
group. In contrast, amphibole has been found only in the young-group samples. Several disequilibrium features have been observed
in the minerals (e.g., oscillatory zoning within clinopyroxenes). These disequilibrium textures appear to be more prevalent
among the old- as compared with the young-group samples and are most likely the result of magma-mixing, assimilation, and/or
polybaric crystallization. Mass-balance fractionation models for major and trace elements were successful in relating samples
from the old group but failed to show a relationship among the young-group rocks or between the old- and young-group volcanics.
We believe that the old-group volcanics were derived through differentiation processes from basaltic magmas generated within
the mantlewedge. The young group, however, does not appear to be related to more primitive magmas by differentiation. The
young-group samples cannot be related by fractionation including realistic amounts of amphibole. Distinctive geochemical features
of the young group, including La/Yb ratios〉15, Yb〈1, Sr/Y〉150, and Y〈6, suggest that these rocks were derived from the partial
melting of the subducted lithosphere. These characteristics can be explained by the partial melting of a source with residual
garnet and amphibole. Dacitic material with the geochemical characteristics of subducted-lithosphere melting is generated
apparently only where relatively hot crust is subducted, based on recent work. The young dacite-genesis at El Valle volcano
is related to the subduction of relatively hot lithosphere. 相似文献
88.
A 4.96-m-long sediment core from the Hanon paleo-maar in Jeju Island, Korea was studied to investigate the paleoclimatic change and East Asian monsoon variations during the latest Pleistocene to early Holocene (23,000-9000 cal yr BP). High-resolution TOC content, magnetic susceptibility, and major element composition data indicate that Jeju Island experienced the coldest climate around 18,000 cal yr BP, which corresponds to the last glacial maximum (LGM). Further, these multi-proxy data show an abrupt shift in climatic regime from cold and arid to warm and humid conditions at around 14,000 cal yr BP, which represents the commencement of the last major deglaciation. After the last major deglaciation, the TOC content decreased from 13,300 to 12,000 cal yr BP and from 11,500 to 9800 cal yr BP, thereby reflecting the weakening of the summer monsoon. The LGM in Jeju Island occurred later in comparison with the Chinese Loess Plateau. Such a disparity in climatic change events between central China and Jeju Island appears to be caused by the asynchrony between the coldest temperature event and the minimum precipitation event in central China and by the buffering effect of the Pacific Ocean. 相似文献
89.
Adsorption characteristics of perchloroethylene in natural sandy materials with low organic carbon content 总被引:2,自引:0,他引:2
Laboratory batch tests were conducted to investigate the sorption isotherms and sorption kinetics of the chlorinated hydrocarbon
perchloroethylene (PCE) in five natural sandy materials with an organic carbon content (f
oc) in the range 0.080–0.540%. The amended non-linear dual-mode model can describe the sorption isotherms in materials with
f
oc in the range 0.080–0.090%. For a sample with a much higher f
oc of 0.54%, the absorption isotherm was found to fit a linear model. These results may indicate that organic carbon is not
the main factor influencing the sorption isotherm. The sorption kinetics of PCE in samples with f
oc in the range 0.080–0.090% are not first-order and are different from those observed in the samples with higher f
oc. The sorption process in the materials with lower f
oc involves fast sorption, fast desorption and an equilibrium stage. The results may imply that the factors affecting sorption
kinetics of PCE in low f
oc media are pore filling and capillary condensation rather than organic carbon content. 相似文献
90.
Hydrologic modelling of the effect of snowmelt and temperature on a mountainous watershed 总被引:2,自引:0,他引:2
Snowmelt-runoff modelling in a mountainous basin is perceived as difficult due to the complexity of simulation. Theoretically, the snowmelt process should be influenced by temperature changes. It is still controversial as how to incorporate the temperature changes into the snowmelt-runoff model in a mountainous basin. This paper presents the results of a study in the North Fork American River basin where the snowmelt-runoff mechanism is modelled by relating the temperature changes to the elevation band in the basin. In this study, a distributed hydrologic model is used to explore the orographic effects on the snowmelt-runoff using the snowfall-snowmelt routine in Soil and Water Assessment Tool (SWAT). Three parameters, namely maximum snowmelt factor, minimum snowmelt factor, and snowpack temperature lag were analysed during the simulation. The model was validated using streamflow data from October 1, 1991 to September 30, 1994 with and without considering the elevation band. The result of this study suggests that the snowmelt-runoff model associated with the elevation band better represents the snowmelt-runoff mechanism in terms of Nash–Sutcliffe coefficient (E NS ), R 2, and Root Mean Square Error (RMSE). 相似文献