Seasonal variations in river discharge and nutrient export to a Northeastern Pacific estuary

Seasonal variations in dissolved nitrogen and silica loadings were related to seasonal variability in river discharge. Dissolved nutrient concentrations measured weekly at three stations in the Yaquina River, Oregon from 1999 through 2001, and then monthly in 2002 were used as the basis for developing a nutrient loading regression as part of a larger agency program for evaluating nutrient processes. Because realistic models of nutrient transport require dense data sets to capture both long and short term fluctuations in nutrient concentrations, data at one freshwater station also were collected hourly for the same years using an in-stream monitor.The effects of storm events on dissolved nutrient transport were examined during three storms, including one in a high rainfall-discharge year, and two in average years, one of which followed a drought year. During the drought year (WY2001), total dissolved nitrate input was considerably less than in wetter years. Dissolved nitrate concentrations, however, were unusually high in the first winter storm runoff after the drought. The freshwater dissolved nitrate nitrogen loads varied from 40,380 kg day⁻¹ during a high-flow storm event to 0.11 kg day⁻¹ during late summer, low flow conditions. Dissolved silica dynamics differed from those of nitrate because during storm events, silica concentrations in the Yaquina River decreased to near zero at the storm height, probably due to dilution by near surface or overland flow, and later recovered.During the time interval studied, over 94% of the dissolved nitrate and silica were transported from the watershed during the winter months of greater rainfall, indicating that seasonality and river flow are primary factors when considering nutrient loadings from this watershed system.     

Uptake and transformation of C-labelled tributyltin chloride by the dog-whelk, nucella lapillus: Importance of absorption from the diet

The importance of the diet as a source of tributyltin (TBT) in Nucella lapillus was studied using [¹⁴C]tributyltin chloride. In N. lapillus provided with prelabelled mussels, Mytilus edulis, in labelled water (mean 20·5 ng/litre TBT) the rate of accumulation of total ¹⁴C was 2–3 times that in unfed animals. Owing to its degradation in the tissues of both fed and unfed animals, concentrations of [¹⁴C]TBT tended to reach a plateau after only 28 days. However, total concentrations of ¹⁴C were still increasing after 49 days. Under experimental conditions (15°C, ample food, no disturbance) the diet accounted for about 50% of the body burden of TBT in N. lapillus after 49 days exposure: concentration factors (dry tissue/water) for [¹⁴C]TBT in both male and female N. lapillus were similar at about 60 000 in fed and 30 000 in unfed animals. It is concluded that the diet may contribute less than half of the body burden of TBT found in natural populations subjected to life-long exposure.     

Trace metal-binding proteins in marine molluscs and crustaceans

Some marine invertebrates, such as the American oyster, Crassostrea virginica, the blue crab, callinectes sapidus and the American lobster, Homarusamericanus, concentrate trace metals in their tissues. The occurrence of metallothionein, a low molecular weight, sulfur-containing metal-binding protein, has been correlated with elevated levels of trace metals in these organisms. It is our hypothesis that, whilst metallothioneins are involved in the sequestration of elevated levels of trace metals, they primarily function in regulating normal metal metabolism. In this paper we describe recent field and laboratory experiments designed to examine how oysters, blue crabs and lobsters manage accumulated cadmium, copper and zinc. The possible rôles of metallothionein, as well as the tissue distribution of metals, are emphasized. Metallothioneins were found in all animals we examined; concentrations of metallothioneins and the the amount of bound trace metals are related to time of exposure. We have also demonstrated that the laboratory developed metallothionein models for blue crabs and lobsters may be useful in predicting the partitioning of trace metals in animals living in environments polluted with trace metals.     

Semisubmersible response to transient ice forces

The paper presents an analytical and experimental study on the transient response of semisubmersibles to bergybit impact and the strength of bergybit ice to high strain-rate loadings. Two approaches have been proposed for the solution of the semisubmersible-bergybit interaction problem, one using the energy approach and the other using the conventional structural dynamics approach with initial velocity conditions. In addition the local behaviour of the impacted regions have been analysed for deformation and failure. Numerical results have been given for local behaviour of an impacted column and global behaviour of semisubmersible-bergybit system. Experimental study has been reported on the impact strength of iceberg ice at strain rates of 10⁻³, 10⁻² and 10⁻¹; the indentation impact strength of ice is found to be 3–4 times the unaixial compressive strength, at the same strain rate.     

Magnetic anomalies in the canary basin and the Mesozoic evolution of the central North Atlantic

The data from a recent magnetic compilation by Verhoefet al. (1991) off west Africa were used in combination with data in the western Atlantic to review the Mesozoic plate kinematic evolution of the central North Atlantic. The magnetic profile data were analyzed to identify the M-series sea floor spreading anomalies on the African plate. Oceanic fracture zones were identified from magnetic anomalies and seismic and gravity measurements. The identified sea floor spreading anomalies on the African plate were combined with those on the North American plate to calculate reconstruction poles for this part of the central Atlantic. The total separation poles derived in this paper describe a smooth curve, suggesting that the motion of the pole through time was continuous. Although the new sea floor spreading history differs only slightly from the one presented by Klitgord and Schouten (1986), it predicts smoother flowlines. On the other hand, the sea floor spreading history as depicted by the flowlines for the eastern central Atlantic deviates substantially from that of Sundvik and Larson (1988). A revised spreading history is also presented for the Cretaceous Magnetic Quiet Zone, where large changes in spreading direction occurred, that can not be resolved when fitting magnetic isochrons only, but which are evident from fracture zone traces and directions of sea floor spreading topography.Deceased 11 November 1991     

Detection of buried targets using a synthetic aperture sonar

This paper presents observations of buried target detections made using a 20-kHz synthetic aperture sonar. At grazing angles below the critical angle, surprisingly high signal-to-noise detections were made of cylindrical targets buried at depths of 15 and 50 cm. During a separate set of measurements, buried spheres were clearly seen at steep grazing angles, but were generally not seen below the critical angle. Since scattering from wave-generated sand ripples may contribute to detections at grazing angles below critical angle, the information available on the ripple fields is discussed and used in acoustic backscatter simulations for the buried spheres. Lack of information on the ripple height precludes a definitive explanation for the absence of buried sphere detections at subcritical grazing angles.     

Studies on the determination of inorganic iodine in seawater

Existing methods for the determination of the various forms of iodine present in seawater are laborious or unwieldy in use. This paper describes modified forms of the iodate and total iodine methods described by Barkley and Thompson (1960), a spectrophotometric procedure for iodate determination derived from Johannesson's (1958) work, and an automatic method for total iodine determination. Procedures for iodate and total-iodine determination which are suitable for use aboard ship, are recommended. Both procedures for iodate determination returned a standard deviation close to 0.5 μg/l when several replicate samples of a seawater containing approximately 30 μg/l of iodate-iodine were analysed. The automatic method for total iodine determination yielded a standard deviation of 0.8 μg/l by the repeated analysis of a seawater containing a total of approximately 50 μg/l of iodine. Suitable methods for the filtration and storage of seawater are also described.