Macrofaunal density and biomass in the Campeche Canyon, Southwestern Gulf of Mexico

The composition, density and community structure of the benthic macrofauna were investigated in sediments of the Campeche Canyon in the SW Gulf of Mexico. Total macrofaunal density ranged from 9466±2736 ind m⁻² at the continental shelf station to 1550±195 ind m⁻² in the canyon. Density values significantly diminished with distance from the coast and depth; only a few stations in the center of the canyon displayed larger density values (E-37 with 4666±1530 ind m⁻², E-36 with 5791±642 ind m⁻² and E-26 with 6925±2258 ind m⁻²). Densities were positively correlated to organic nitrogen in the sediment (r=0.82) and coarse silt (r=0.43), and negatively with depth (r=−0.74) and distance from the coast (r=−0.68). At all stations, the polychaete worms contributed most to the multi-species community structure. The nematodes and Foraminifera displayed their highest densities in the center of the canyon. The biomass values declined significantly with depth. We conclude that the macrofauna density and biomass changed in response to organic matter contents in the sediment, both with distance from the coast and with depth.     

A predictive numerical model for potential mapping of the gas hydrate stability zone in the Gulf of Cadiz

This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.     

The impact of extreme turbidity events on the nursery function of a temperate European estuary with regulated freshwater inflow

Estuaries are used as nursery grounds by numerous marine species despite being usually subject to strong anthropogenic disturbances. Abundances of marine recruits (fish and crustacean decapods) and their main prey (mysids) were monitored by monthly sampling, from June 1997 to February 2009, in the lower reaches of the Guadalquivir estuary (SW Spain). During that period, unusually high and persistent turbidity events (HPTEs) were observed twice. Both HPTEs started with strong and sudden freshwater discharges after relatively long periods of very low freshwater inflow. Data from this time-series were used to test the hypothesis that HPTEs may negatively impact the nursery function of estuaries either by decreasing prey availability or by decreasing survival/arrival of marine recruits. During HPTEs, the commonest mysid (Mesopodopsis slabberi), a key species in the estuarine food web, showed a significant decrease in abundance. Likewise, some marine recruits that prey on M. slabberi and whose peaks of abundance within the estuary occur in summer–autumn (Engraulis encrasicolus and Pomadasys incisus) were less abundant during HPTEs. It is also suggested that HPTEs might have triggered a shift in the distribution of the most euryhaline prey (Neomysis integer) and predator (Dicentrarchus punctatus and Crangon crangon) species, towards more saline waters. This could have contributed to an increase in the inter-specific competition (for food/habitat) within the estuarine nursery area. The results discussed in this study call attention to the need to reduce as much as possible the anthropogenic pressures that may stimulate the occurrence of high and persistent turbidity events (HPTEs) in order to preserve the nursery function of temperate estuaries.     

Determination par activation neutronique des rapports Cl/Br des inclusions fluides de divers gypses. Correlation avec les donnees de la microcryoscopie et interpretations genetiques

Gypsum contains liquid inclusions which fill mainly primary cavities. Analysis of inclusions may give some information about the mineral formation process. In places, diagenetic solutions have filled secondary cavities along cleavage planes or replaced initial liquid inclusions in primary cavities; the presence of such secondary inclusions must, therefore, be taken into consideration. This study presents our results on the Cl/Br ratio of liquid inclusions in gypsum. The Cl/Br ratio is practically constant in present sea water, and has been measured in many different types of waters. The Br content of halite has also been extensively studied to trace the compositional changes of a salt-depositing brine. In gypsum Br is present only in microscopic fluid inclusions. For this reason we used the neutron-activation method. We adopted the technique in order to prevent any contamination and obtain directly Cl/Br ratio within 10% accuracy. In order to ascertain that liquid inclusions reside mainly in primary cavities of gypsum, we selected our samples only after microscopic observation. Fifty-eight samples from different types of gypsum were analysed. The salinities of the inclusions, obtained through the data on freezing, and the Cl/Br ratio, obtained through activation-analysis, give us clues as to the nature of the fluids depositing the gypsum. Recent gypsum deposits from French salt-pans of Mediterranean and Atlantic coasts were sampled. The latter has apparently been diagenetically altered by meteoric water; the salinity of many inclusions having been changed while the Cl/Br ratio (315 and 350) in both remains close to the value of present sea water (#300). Liquid inclusions of Recent crystals from New Caledonia, deposited in mangrove swamps are enriched in Br (Cl/Br = 150 and 200). The enrichment might be related to the presence of abundant organic materials. Inclusions in crystals from Sebkha el Melah (Tunisia) also show high Br content (Cl/Br = 194). In this case, the brine was highly concentrated and was saturated with NaCl. The Upper Miocene gypsum from Sicily was studied to test the various models for the genesis of this important evaporite formation of the Mediterranean. Freezing data show some decrease of salinities, probably by groundwater diagenesis, but the Br content is high. The Cl/Br ratio is 175, and this value is similar to that of Sebkha el Melah. Samples from three thick Eocene and Oligocene sequences near Paris and in the South of France were studied. Freezing data and Cl/Br ratio of their inclusions indicate that those gypsum deposits have crystallized in marine environments receiving considerable influx of river-waters.     

Deglacial palaeoclimate at Puerto del Hambre,subantarctic Patagonia,Chile

The primary objective of this study is to further substantiate multistep climatic forcing of late‐glacial vegetation in southern South America. A secondary objective is to establish the age of deglaciation in Estrecho de Magallanes–Bahía Inútil. Pollen assemblages at 2‐cm intervals in a core of the mire at Puerto del Hambre (53°36′21″S, 70°55′53″W) provide the basis for reconstructing the vegetation and a detailed account of palaeoclimate in subantarctic Patagonia. Chronology over the 262‐cm length of core is regulated by 20 AMS radiocarbon dates between 14 455 and 10 089 ¹⁴C yr BP. Of 13 pollen assemblage zones, the earliest representing the Oldest Dryas chronozone (14 455–13 000 ¹⁴C yr BP) records impoverished steppe with decreasing frequencies and loss of southern beech (Nothofagus). Successive 100‐yr‐long episodes of grass/herbs and of heath (Empetrum/Ericaceae) before 14 000 ¹⁴C yr BP infer deglacial successional communities under a climate of increased continentality prior to the establishment of grass‐dominated steppe. The Bølling–Allerød (13 000–11 000 ¹⁴C yr BP) is characterised by mesic grassland under moderating climate that with abrupt change to heath dominance after 12 000 ¹⁴C yr BP was warmer and not as humid. At the time of the Younger Dryas (11 000–10 000 ¹⁴C yr BP), grass steppe expanded with a return of colder, more humid climate. Later, with gradual warming, communities were invaded by southern beech. The Puerto del Hambre record parallels multistep, deglacial palaeoclimatic sequences reported elsewhere in the Southern Andes and at Taylor Dome in Antarctica. Deglaciation of Estrecho de Magallanes–Bahía Inútil is dated close to 14 455 ¹⁴C yr BP, invalidating earlier dates of between 15 800 and 16 590 ¹⁴C yr BP. Copyright © 2000 John Wiley & Sons, Ltd.     

Estimation of seismic hazard parameters in TERESA test areas

A general overview of some of the problems involved in earthquake catalogue handling is given as part of the works carried out into the ESC/SC8-TERESA project related with the seismic hazard assessment in two selected test areas: Sannio-Matese in Italy and the northern Rhine region (BGN). Furthermore, the necessary input data to be used in the calculation of seismic hazard has been obtained, including earthquake source zones and their seismic hazard parameters.The importance is pointed out of detailed analysis of seismic catalogues, mainly in relation to the use of aftershock information, the historical records of the region, and the possible temporal and spatial variation of seismicity, which could have an important influence on short-term hazard assessment.     

Mineralogical data on a sulphosalt from the Rhodope mountains,Bulgaria

Zusammenfassung Bei dem Versuch, die Kristallstruktur von Bonchevit zu bestimmen, stellte sich heraus, daß dieses Mineral—bis dahin PbBi₄S₇—aus zwei Phasen besteht. Der Hauptanteil wurde eindeutig als Galenobismutit identifiziert. Der Rest wies nach den Gitterkonstanten (a₀=13,58±0,02 Å, b₀=20,51±0,07 Å, c₀=4,09±0,07 Å) auf ein bisher unbekanntes Mineral hin. Die Raumgruppe ist Bbmm. Ein indiziertes Pulverdiagramm und die dazugehörigen d-Werte werden angegeben.Die Emissionsspektralanalyse zeigt Pb und Bi als Hauptkomponenten, Cu und Ag als Nebenkomponenten und Spuren von Zn und Sn. Die Strukturanalyse führte zu der Formel Me₅S₆, wobei die Me-Atome etwa gleich schwer sind, so daß als chemischo Formel nur Pb₃Bi₂S₆ mit Z=4 in Frage kommt.Strukturell gehört das Mineral in die Gruppe Andorit-Ramdohrit-Fizelyit. Die Verwandtschaft bzw. Identität des Minerals mit anderen Mineralen und synthetischen Verbindungen wird diskutiert.

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Mineralogical data on a sulphosalt from the Rhodope mountains, Bulgaria

Summary During an attempt to determine the crystal structure of bonchevite, this mineral was found to consist of two phases. Previously it was thought to have the composition PbBi₄S₇. The main constituent could unambiguously be identified as galenobismutite. For the rest the lattice constants (a₀=13.58±0,02 Å, b₀=20.51±0,07 Å, c₀=4.09±0.07 Å), indicated a new mineral. Space group is Bbmm. An indexed powder diagram (with d-values) is given.The emission spectrographic analysis shows Pb and Bi to be main components, Cu and Ag to be minor components, and traces only of Zn and Sn. The structure analysis has led to the formula Me₅S₆, with Me-atoms of approximately the same atomic number; therefore, the chemical formula has to be Pb₃Bi₂S₆, with Z=4.In a structural classification the mineral belongs to the andoriteramdohrite-fizelyite-group. The relationships to or the identity with other minerals and synthetic compounds are discussed.

     

The study of metal contamination in urban topsoils of Mexico City using GIS

This research presents and discusses information concerning the spatial distribution of heavy metals (Pb, Cu, Zn, Ba, Co, Cr, Ni and V) in the urban environments of Mexico City using geographical information system and statistical analysis. Superficial soil samples (n = 146) were analyzed. The highest contamination indices were found in the north and center zone of the metropolitan area. In contrast, the surrounding rural fields show a lower impact grade. The higher concentrations of Pb, Cu, Zn and Ba were observed as being related to high vehicular traffic, nevertheless other elements such as Co, Cr, Ni and V do not show anthropogenic influence and their content can be attributed to the parental rock. The results are compared with previous surveys carried out in 2003 in order to evaluate temporal deposition trends. No changes were found on reported concentrations except for Cu and Zn, whose concentration has increased in later years. The results suggest that spatial distribution analysis and results in comparison with previous studies could be useful for the management and sustainable development of the metropolitan area of Mexico City.     

Barium-rich fluids and melts in a subduction environment (La Corea and Sierra del Convento mélanges,eastern Cuba)

Whole-rock compositions of muscovite-bearing amphibolite, trondhjemite, pegmatite and quartz-muscovite rocks from Sierra del Convento and La Corea mélanges (eastern Cuba), as well as mineralogy, record complex circulation of Ba-rich fluids and melts in the subduction environment. Partial melting of fluid-fluxed, MORB-derived amphibolite produced trondhjemite magmas that crystallized at depth, in some cases evolving into pegmatites. Qtz-Ms rocks probably crystallized from primary fluids derived from subducted sediments. All these rocks have elevated concentrations of large-ion lithophile elements, especially Ba (up to 11,810 ppm), presumably released from slab sediments by fluids and/or melts. Fluid–rock interaction produced crystallization of phengite in parental amphibolites. The phengite crystallized in all types of rocks is rich in Ba, with concentric zoning, characterized by Ba-rich cores and Ba-poor rims, indicating a compatible behaviour of Ba in the studied systems. Zoning in phengite is governed primarily by the celadonite (tschermak) exchange vector ((Mg,Fe)Si-(Al)_-2), with more moderate contributions of the celsian (BaAl-(KSi)_-1) and paragonite (NaK_-1) exchange vectors. Late remobilization of Ba at relatively low temperature formed retrograde celsian. The compatible behaviour of Ba in the studied rocks strengthens the importance of the stability of phengite for the transfer of LIL elements from the subduction to the volcanic arc environments.