Hydrous ferric oxide (HFO) colloids formed, in strictly anoxic conditions upon oxidation of Fe2+ ions adsorbed on mineral surface, were investigated under in situ conditions by contact mode atomic force microscopy (AFM). Freshly cleaved and acid-etched large single crystals of near endmember phlogopite were pre-equilibrated with dissolved Fe(II) and then reacted with Hg(II), As(V) and trichlorethene (TCE)-bearing solutions at 25 °C and 1 atm. HFO structures are found to be of nanometer scale. The As(V)–Fe(II) and Hg(II)–Fe(II) reaction products are round (25 nm) microcrystallites located predominantly on the layer edges and are indicative of an accelerated Fe(II) oxidation rate upon formation of Fe(II) inner sphere surface complexes with the phyllosilicate edge surface sites. On the other hand, TCE–Fe(II)–phlogopite reaction products are needle-shaped (45 nm long) particles located on the basal plane along the Periodic Bond Chains (PCBs) directions. Experiments with additions of sodium chloride confirm the importance of the Fe(II) adsorption step in the control of the overall heterogeneous Fe(II)–TCE electron transfer reaction.
Kinetic measurements at the nanomolar level of Hg° formed upon reduction of Hg(II) by Fe(II) in presence of phlogopite particles provide further convincing evidence for reduction of Hg(II)aq coupled to the oxidation of Fe(II) adsorbed at the phlogopite–fluid interface, and indicate that sorption of Fe(II) to mineral surfaces enhances the reduction rate of Hg(II) species. The Hg(II) reduction reaction follows a first-order kinetic law. Under our experimental conditions, which were representative of many natural systems, 80% of the mercury is transferred to the atmosphere as Hg° in less than 2 h.
The reduction of a heavy metal (Hg), a toxic oxyanion (arsenate ion) and a chlorinated solvent (TCE) thus appear to be driven by the high reactivity of adsorbed Fe(II). This is of environmental relevance since these three priority pollutants are that way reductively transformed to a volatile, an immobilizable and a biodegradable species, respectively. Such kinetic data and reaction pathways are important in the evaluation of natural evaluation scenarios, in the optimization of Fe(II)/mineral mixtures as reductants in technical systems, and in general, in predicting the fate and transport of pollutants in natural systems. 相似文献
This paper presents an approach for GIS integrating local participatory land management information used for regional planning, and contributing to a bottom-up approach to land use planning. In participatory planning, the integration between local and regional levels should facilitate the communication and co-operation among the parties at both levels, for an efficient use of available resources. For coherently linking these two levels it is necessary to transform the data produced at one level, in order to be usable by the other. This transformation consists of a spatial procedure, which allows scaling-up the local participatory rural appraisal (PRA) information for regional purposes and scaling down the regional information for local use, using a GIS. Such an integration procedure is presented and discussed using data from a case study in south-western Burkina Faso. 相似文献
A ductile shear zone in a late Precambrian granodiorite, from the Rouergue (southwest part of the French Massif Central) has been studied.A single episode of deformation is responsible for the formation of a foliation and a well-defined lineation which are localized into an elongated zone, a few decimeters wide.The strain features can be attributed to a simple-shear mechanism (Ramsay and Graham, 1970), so that the main parameters of the deformation are defined.At stages of increasing deformation, the quartz isotropic sub-fabric of the undeformed host rock is progressively transformed into an anisotropic fabric composed of a single oblique girdle while the subgrain size progressively decrease and the dislocation density remains constant. It is suggested that the gliding planes of quartz are the basal plane (0001) and a predominant prismatic plane 101̄0 the slip directions may be a for both glide-planes.The results obtained in this investigation provide a basis for a high voltage electron microscope (H.V.E.M.) study which shows that the fabrics development may be related to dislocation processes. The difference of strain rates in the host rock and in the shear zone is calculated from the dislocation microstructures. 相似文献
Seventy-five species and lower taxonomic units of rotifers have been identified in Lake Geneva (= lac Léman); seven species and one form are new for the lake. When using indicators of trophic conditions, the qualitative composition of the biocenosis is still dominated by oligo-mesotrophic lake indicators, mixed with eutrophic and oligotrophic ones. However the rotifer biocenosis has not yet reached a steady state. 相似文献
The Pénestin section (southern Brittany) presents large regular undulations, commonly interpreted as evidence of periglacial
pingos. It is an upper Neogene palaeoestuary of the Vilaine River reactivated during the middle Quaternary (middle terrace).
It is incised into a thick kaolinitic saprolite and deformed by saprolite diapirs. This paper presents the arguments leading
to a mechanistic interpretation of the deformations at Pénestin. Neither recent transpressive tectonics nor diagnostic evidence
of periglacial pingo have been found despite evidence for a late paleo-permafrost. The major deformational process is shale
diapirism, initially triggered by co-seismic water supply, with further loading and lateral spreading on an already deformed
and deeply weathered basement, which allowed the shale diapirism to develop. Deformations are favoured by the liquefaction
of the saprolite and a seaward mass movement and recorded, rather distant, effects of an earthquake (c. 280 ka B.P.) resulting
from the progressive subsidence of the southern Armorican margin. These deformations triggered by an earthquake are similar
to those induced by classical shale diapirism. They are probably common in tectonically active continental environments with
shallow water table. 相似文献
Structural uncertainty exists when associating sparse fault interpretations made from two-dimensional seismic lines or limited outcrop observations. Here, a graph formalism is proposed that describes the problem of associating spatial fault evidence. A combinatorial analysis, relying on this formalism, shows that the number of association scenarios is given by the Bell number, and increases exponentially with the number of pieces of evidence. As a result, the complete exploration of uncertainties is computationally highly challenging. The available prior geological knowledge is expressed by numerical rules to reduce the number of scenarios, and the graph formalism makes structural interpretation easier to reproduce than manual interpretation. The Bron–Kerbosch algorithm, which finds maximal cliques in undirected graphs, is used to detect major possible structures. This framework opens the way to a numerically assisted exploration of uncertainties during structural interpretation.