Magnitude of latent heat in thermally loaded clays

Temperature changes are known to induce specific couplings in clay, in particular, an anomalously high thermal pressurization in undrained conditions or a thermal compaction in drained conditions, both of which are potential threats for the mechanical stability and sealing capacity of the geomaterials. Thermodynamical analysis of those peculiar thermomechanical couplings points to a potentially important latent energy, which in turn could limit the temperature change upon heating or cooling. The direct measurement of latent energy developed during a laboratory geomechanical test is challenging. Instead, proper identification of thermal hardening in conventional experiments with temperature changes provides an alternative route to estimate latent energy. In this work, existing laboratory thermomechanical tests of clays are analyzed with a rigorous thermodynamic framework to quantify the magnitude of latent energy in thermomechanically loaded clays. A thermodynamically consistent constitutive model for fully saturated clays that combines two key features, (a) the temperature dependence of the blocked energy and (b) the framework of bounding plasticity, is proposed. The performance of the model is validated by reproducing results obtained in laboratory tests for Boom and Opalinus clays. The thermomechanical loads considered to validate the model performance were then used to estimate the percentage of work that remains latent in the clayey material during plastic yielding. We find that the magnitude of latent energy is quite significant, typically a few tens of percent of the total dissipated energy, and increases significantly with temperature. Accordingly, it is expected to play an important role in the thermomechanical response of clays.     

Towards more systematic perceptual model development: a case study using 3 Luxembourgish catchments

The synthesis of experimental understanding of catchment behaviour and its translation into qualitative perceptual models is an important objective of hydrological sciences. We explore this challenge by examining the cumulative understanding of the hydrology of three experimental catchments and how it evolves through the application of different investigation techniques. The case study considers the Huewelerbach, Weierbach and Wollefsbach headwater catchments of the Attert basin in Luxembourg. Subsurface investigations including bore holes and pits, analysis of soil samples and Electrical Resistivity Tomography measurements are presented and discussed. Streamflow and tracer data are used to gain further insights into the streamflow dynamics of the catchments, using end‐member mixing analysis and hydrograph separation based on dissolved silica and electrical conductivity. We show that the streamflow generating processes in all three catchments are controlled primarily by the subsolum and underlying bedrock. In the Huewelerbach, the permeable sandstone formation supports a stable groundwater component with little seasonality, which reaches the stream through a series of sources at the contact zone with the impermeable marls formation. In the Weierbach, the schist formation is relatively impermeable and supports a ‘fill and spill’‐type of flow mechanism; during wet conditions, it produces a delayed response dominated by pre‐event water. In the Wollefsbach, the impermeable marls formation is responsible for a saturation‐excess runoff generating process, producing a fast and highly seasonal response dominated by event water. The distinct streamflow generating processes of the three catchments are represented qualitatively using perceptual models. The perceptual models are in turn translated into quantitative conceptual models, which simulate the hydrological processes using networks of connected reservoirs and transfer functions. More generally, the paper illustrates the evolution of perceptual models based on experimental fieldwork data, the translation of perceptual models into conceptual models and the value of different types of data for processes understanding and model representation. Copyright © 2014 John Wiley & Sons, Ltd.     

Nouvelles données pour l’histoire des fluctuations holocènes du niveau du lac de Neuchatel (Suisse): la séquence sédimentaire de Marin-Les Piécettes

Resume. Les fouilles archéologiques réalisées de 1998 à 2002 sur le site néolithique de Marin-Les Piécettes sur la rive nord-ouest du lac de Neuchatel ont offert l’opportunité d’observer deux séquences sédimentaires intéressantes pour la reconstitution des variations holocènes du niveau du lac, en particulier au cours de la période correspondant au changement de cours de l’Aar en direction du nord-est, vers 5650–5500 cal BP. La géométrie des corps sédimentaires et les changements lithologiques permettent de reconna?tre plusieurs phases majeures de bas niveaux relatifs du plan d’eau vers 6870, 5660, 5060–3990, 3580, 2280, 1640 et 1170 cal BP. Le site néolithique de Marin-Les Piécettes s’est développé vers 5454–5433 cal BP à la faveur d’un court épisode de bas niveau du lac qui a interrompu une importante phase de haut niveau au début du Subboréal. Les événements paléohydrologiques identifiés à Marin-Les Piécettes apparaissent cohérents avec ceux reconstitués sur le site de Montilier au bord du lac de Morat, ainsi qu’avec les variations paléohydrologiques reconstituées à partir des lacs du Jura, du Plateau suisse et des Préalpes du Nord fran?aises. Ceci suggère qu’ils témoignent d’un signal climatique. La séquence sédimentaire de Marin-Les Piécettes met enfin en évidence la formation d’un cordon littoral sur la rive nord-ouest du lac juste après 5660 cal BP. Manuscrit re?u le 22 septembre 2004 Révision acceptée le 11 mars 2005     

The information system of the French Peatland Observation Service: Service National d'Observation Tourbières – A valuable tool to assess the impact of global changes on the hydrology and biogeochemistry of temperate peatlands through long term monitoring

Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).     

Response of littoral chironomid communities and organic matter to late glacial lake—level,vegetation and climate changes at Lago dell’Accesa (Tuscany,Italy)

This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological, environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages, organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany, Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development. Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group level, may be necessary to increase the sensibility of the indicators to lake-level changes.     

Sedimentary facies and paleoenvironmental interpretation of a Holocene marsh in the Gironde Estuary in France

1Introduction Since the last glacial maximum, the Holocenehas been marked by a rapid rise in sea level. After6 000 a BP, the present-day level was reached andthe rate of sea-level rise (SLR) decreased rapidly(Morzadec -Kerfourn, 1974; Kidson, 1986 ).These…     

An Overview of BCC Climate System Model Development and Application for Climate Change Studies

This paper reviews recent progress in the development of the Beijing Climate Center Climate System Model(BCC-CSM) and its four component models(atmosphere,land surface,ocean,and sea ice).Two recent versions are described:BCC-CSM1.1 with coarse resolution(approximately 2.8125°×2.8125°) and BCC-CSM1.1(m) with moderate resolution(approximately 1.125°×1.125°).Both versions are fully coupled climate-carbon cycle models that simulate the global terrestrial and oceanic carbon cycles and include dynamic vegetation.Both models well simulate the concentration and temporal evolution of atmospheric CO_2 during the 20th century with anthropogenic CO2 emissions prescribed.Simulations using these two versions of the BCC-CSM model have been contributed to the Coupled Model Intercomparison Project phase five(CMIP5) in support of the Intergovernmental Panel on Climate Change(IPCC) Fifth Assessment Report(AR5).These simulations are available for use by both national and international communities for investigating global climate change and for future climate projections.Simulations of the 20th century climate using BCC-CSMl.l and BCC-CSMl.l(m) are presented and validated,with particular focus on the spatial pattern and seasonal evolution of precipitation and surface air temperature on global and continental scales.Simulations of climate during the last millennium and projections of climate change during the next century are also presented and discussed.Both BCC-CSMl.l and BCC-CSMl.l(m) perform well when compared with other CMIP5 models.Preliminary analyses indicate that the higher resolution in BCC-CSM1.1(m) improves the simulation of mean climate relative to BCC-CSMl.l,particularly on regional scales.     

Grain-size-sensitive flow and shear-stress enhancement at the brittle–ductile transition of the continental crust

Localized shear zones along low-angle normal faults have been identified in regions of extension at the brittle-ductile transition of the continental crust. The possibility of the strain localizing at a depth of 10 km is interpreted here as a consequence of an increase in the equivalent shear stress applied to the flow of the lower crust. This enhancement of the flow stress is seen as a prerequisite for the triggering of brittle deformation mechanisms leading to strain localization. The lower crust rheology used to examine this stress increase is strain-rate, temperature and grain-size dependent, due to the coupling of dislocation and diffusion creep. The model structure proposed consists of a top layer, the upper crust, gliding rigidly above a bottom layer, the lower crust, which deforms in simple shear. During a short time interval (1400 years), the equivalent shear stress is found to increase by a factor of up to 3 (67 MPa for anorthite and 17 MPa for quartz). For anorthite, this stress could explain the activation of a Mohr-Coulomb failure with a friction coefficient of 0.2, which is reasonable at the depth of 10 km. Dislocation creep is activated during a rapid change in the prescribed velocity, whereas diffusion creep dominates if the velocity is held constant, highlighting the importance of grain-size sensitivity for lower crustal rheology.     

Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite

Arsenate, As(V), sorption onto synthetic iron(II) monosulfide, disordered mackinawite (FeS), is fast. As(V) sorption decreases above the point of zero surface charge of FeS and follows the pH-dependent concentration of positively charged surface species. No redox reaction is observed between the As(V) ions and the mineral surface over the time span of the experiments. This observation shows that As(V) dominantly forms an outer-sphere complex at the surface of mackinawite. Arsenite, As(III), sorption is not strongly pH-dependent and can be expressed by a Freundlich isotherm. Sorption is fast, although slower than that of As(V). As(III) also forms an outer-sphere complex at the surface of mackinawite. In agreement with previous spectroscopic studies, complexation at low As(V) and As(III) concentration occurs preferentially at the mono-coordinated sulfide edge sites. The K_d (L g⁻¹) values obtained from linear fits to the isotherm data are ∼9 for As(V) and ∼2 for As(III). Stronger sorption of As(V) than As(III), and thus a higher As(III) mobility, may be reflected in natural anoxic sulfidic waters when disordered mackinawite controls arsenic mobility.