Trace element and molecular markers of organic carbon dynamics along a shelf–basin continuum in sediments of the western Arctic Ocean

Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.     

Macrofaunal density and biomass in the Campeche Canyon, Southwestern Gulf of Mexico

The composition, density and community structure of the benthic macrofauna were investigated in sediments of the Campeche Canyon in the SW Gulf of Mexico. Total macrofaunal density ranged from 9466±2736 ind m⁻² at the continental shelf station to 1550±195 ind m⁻² in the canyon. Density values significantly diminished with distance from the coast and depth; only a few stations in the center of the canyon displayed larger density values (E-37 with 4666±1530 ind m⁻², E-36 with 5791±642 ind m⁻² and E-26 with 6925±2258 ind m⁻²). Densities were positively correlated to organic nitrogen in the sediment (r=0.82) and coarse silt (r=0.43), and negatively with depth (r=−0.74) and distance from the coast (r=−0.68). At all stations, the polychaete worms contributed most to the multi-species community structure. The nematodes and Foraminifera displayed their highest densities in the center of the canyon. The biomass values declined significantly with depth. We conclude that the macrofauna density and biomass changed in response to organic matter contents in the sediment, both with distance from the coast and with depth.     

Sediment resuspension events induced by the wake wash of deep-draft vessels

Hydrodynamics and sediment resuspension events, induced at the shoreline by a deep-draft vessel passing nearby, are described. Measurements (pressure, currents and turbidity) were obtained at 4 Hz, on a lower beach ~50 m from a channel where large car ferries operate in Wootton Creek, Isle of Wight. The study focuses on a representative 8-min 32-s-long record, during which two large vessels passed the channel section. At the shore, the passage of each vessel induced a long-period water-level drawdown, followed by a water-level oscillation (seiche) of similar period, and the short-period waves of the wake. Both drawdowns were the main constituents of the prevailing wave pattern. The second drawdown was the largest in amplitude, in response to a higher speed of the ferry, and the influence of the seiche which had been activated during the preceding event. Two successive peaks of turbidity were observed shortly after this drawdown. Analyses of current velocity and direction indicate that the sediments resuspended originated from the shallower upper beach. Anthropogenically induced erosion of the foreshore is predicted at Wootton Creek.     

The fusion crust of the Winchcombe meteorite: A preserved record of atmospheric entry processes

Fusion crusts form during the atmospheric entry heating of meteorites and preserve a record of the conditions that occurred during deceleration in the atmosphere. The fusion crust of the Winchcombe meteorite closely resembles that of other stony meteorites, and in particular CM2 chondrites, since it is dominated by olivine phenocrysts set in a glassy mesostasis with magnetite, and is highly vesicular. Dehydration cracks are unusually abundant in Winchcombe. Failure of this weak layer is an additional ablation mechanism to produce large numbers of particles during deceleration, consistent with the observation of pulses of plasma in videos of the Winchcombe fireball. Calving events might provide an observable phenomenon related to meteorites that are particularly susceptible to dehydration. Oscillatory zoning is observed within olivine phenocrysts in the fusion crust, in contrast to other meteorites, perhaps owing to temperature fluctuations resulting from calving events. Magnetite monolayers are found in the crust, and have also not been previously reported, and form discontinuous strata. These features grade into magnetite rims formed on the external surface of the crust and suggest the trapping of surface magnetite by collapse of melt. Magnetite monolayers may be a feature of meteorites that undergo significant degassing. Silicate warts with dendritic textures were observed and are suggested to be droplets ablated from another stone in the shower. They, therefore, represent the first evidence for intershower transfer of ablation materials and are consistent with the other evidence in the Winchcombe meteorite for unusually intense gas loss and ablation, despite its low entry velocity.     

Coming to the table: Early stakeholder engagement in marine spatial planning

From 2009 to 2011, marine spatial planning (MSP) rapidly gained visibility in the United States as a promising ocean management tool. A few small-scale planning efforts were completed in state waters, and the Obama Administration proposed a framework for large-scale regional MSP throughout the U.S. Exclusive Economic Zone. During that same time period, the authors engaged a variety of U.S ocean stakeholders in a series of dialogs with several goals: to share information about what MSP is or could be, to hear stakeholder views and concerns about MSP, and to foster better understanding between those who depend on ocean resources for their livelihood and ocean conservation advocates. The stakeholder meetings were supplemented with several rounds of in-depth interviews and a survey. Despite some predictable areas of conflict, project participants agreed on a number of issues related to stakeholder engagement in MSP: all felt strongly that government planners need to engage outsiders earlier, more often, more meaningfully, and through an open and transparent process. Equally important, the project affirmed the value of bringing unlike parties together at the earliest opportunity to learn, talk, and listen to others with whom they rarely engage.     

Analytical and experimental investigation on vibrating rectangular plates with two opposite free edges and internal supports while the remaining are elastically restrained against rotation

This paper deals with the determination of an approximate fundamental frequency equation for a rectangular plate with two edges (y = 0, b) elastically restrained against rotation while the edges x=0, a are free but internal supports parallel to the free edges are present in the structural system. The algorithmic procedure can be easily implemented on a micro computer or even a hand, programmable calculator.Good engineering agreement with experimental results is shown to exist in the case of a plate with edges y=0,b rigidly clamped.     

Vibrations of a simply supported plate carrying an elastically mounted concentrated mass

A large number of papers and technical reports are available on the technically important problem of structural elements executing transverse vibrations and carrying concentrated masses. In general it is assumed that the attachment is perfectly rigid. On the other hand, a rather limited amount of published work is available when the mass is elastically connected to the structure. The system then exhibits a more complex behavior than in the case of rigid attachment. The present study deals with the solution of the title problem using the well-known normal mode, sinusoidal eigenfunction expansions.     

Seasonal variation in di-nitrogen fluxes and associated processes (denitrification, anammox and nitrogen fixation) in sediment subject to shellfish farming influences

Seasonal patterns of di-nitrogen fluxes together with denitrification, anammox, and N-fixation rates were studied in sediment in an area subject to strong human pressure via waste water, tributaries and shellfish farming in the Mediterranean Sea (Carteau Cove, NW area of the Gulf of Lion). Ammonium concentration demonstrated no seasonal variation, however, a large increase in its concentration was observed over a 10 years period due to intense biodeposition of organic matter. In contrast, nitrate concentration demonstrated no seasonal or long-term (10 years) variation. The main processes affecting di-nitrogen flux magnitudes were denitrification and N-fixation. Anammox was only detected occasionally, nevertheless it represented at times up to 39% of the N₂-flux. Nitrate reducing processes were variable and denitrification showed a 20-fold increase over the past 10 years and might actually have reached its potential maximal activity. Rates of N₂ production (denitrification and anammox) were generally higher than those of N-fixation, leading to elimination of nitrogen from the ecosystem.     

Becoming coca: A materiality approach to a commodity chain analysis of hoja de coca in Colombia

Coca is a controversial plant, existing on the boundary between legality and illegality. This study aims at providing an analytical technique for discussing the problematic of coca in Colombia. Using new theoretical propositions in human geography, a more‐than‐human approach is adopted to encounter coca holistically. The results are a narrative account of coca's social life as experienced by the researcher following its network of non‐cocaine derivatives. An analytical section invokes the Foucauldian dispositif to the drug trade and utilizes concepts of informed materials and technological zones to describe coca outside a political economy discourse. The research finds that coca's dynamic materiality complicates it as a commodity and that these conventional approaches do not fully encapsulate this complexity. By grappling with the messiness of coca's materiality, this paper reveals the multiplicity and interplay of coca's definitions, which lie at the heart of many conflicts.