ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.     

Impact of Sea-Spray on the Atmospheric Surface Layer

The feedback effects of sea-spray on the heat and momentum fluxes under equilibrium conditions associated with winds of tropical cyclones are investigated using a one-dimensional coupled sea-spray and atmospheric surface-layer (ASL) model. This model is capable of simulating the microphysical aspects of the evaporation of saline water droplets of various sizes and their dynamic and thermal interaction with the turbulence mixing that is simulated by the Mellor–Yamada 1.5-order closure scheme. Sea-spray droplet generation is described by a state-of-the-art parametrization that predicts the size spectrum of sea-spray droplets for a given surface forcing. The results from a series of simulations indicate the way in which evaporating droplets of various sizes modify the turbulence mixing near the surface, which in turn affects further droplet evaporation. All these results are direct consequences of the effects of sea-spray on the balance of turbulent kinetic energy in the spray-filled surface layer. In particular, the overall impact of sea-spray droplets on the mean wind depends on the wind speed at the level of sea-spray generation. When the wind speed is below 40 m s⁻¹, the droplets are small in size and tend to evaporate substantially and thus cool the spray-filled layer, while for wind speeds above 50 m s⁻¹, the size of the droplets is so large that they do not have enough time to evaporate much before falling back into the sea. The sensible heat carried by the droplets is released to the ambient air, increasing the buoyancy of the surface layer and enhancing the turbulent mixing. The suspension of sea-spray droplets reduces the buoyancy and makes the surface layer more stable, decreasing the friction velocity and the downward turbulent mixing of momentum. The results from the numerical experiments also suggest that, in order not to violate the constant flux assumption critical to the Monin–Obukhov similarity theory, a displacement equal to the mean wave height should be included in the logarithmic profiles of the wind and thermal fields.     

Retrospective and prospective model simulations of sea level rise impacts on Gulf of Mexico coastal marshes and forests in Waccasassa Bay, Florida

The State of Florida (USA) is especially threatened by sea level rise due to extensive low elevation coastal habitats (approximately 8,000?km²?<?1?m above sea level) where the majority of the human population resides. We used the Sea Level Affecting Marshes Model (SLAMM) simulation to improve understanding of the magnitude and location of these changes for 58,000?ha of the Waccasassa Bay region of Florida??s central Gulf of Mexico coast. To assess how well SLAMM portrays changes in coastal wetland systems resulting from sea level rise, we conducted a hindcast in which we compared model results to 30?years of field plot data. Overall, the model showed the same pattern of coastal forest loss as observed. Prospective runs of SLAMM using 0.64?m, 1?m and 2?m sea level rise scenarios predict substantial changes over this century in the area covered by coastal wetland systems including net losses of coastal forests (69%, 83%, and 99%, respectively) and inland forests (33%, 50%, and 88%), but net gains of tidal flats (17%, 142%, and 3,837%). One implication of these findings at the site level is that undeveloped, unprotected lands inland from the coastal forest should be protected to accommodate upslope migration of this natural community in response to rising seas. At a broader scale, our results suggest that coastal wetland systems will be unevenly affected across the Gulf of Mexico as sea level rises. Species vulnerable to these anticipated changes will experience a net loss or even elimination.     

Pathogenic fungi: an unacknowledged risk at coastal resorts? New insights on microbiological sand quality in Portugal

Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.     

Representing Grounding Line Dynamics in Numerical Ice Sheet Models: Recent Advances and Outlook

Recent satellite observations of the Antarctic and Greenland ice sheets show accelerated ice flow and associated ice sheet thinning along coastal outlet glaciers in contact with the ocean. Both processes are the result of grounding line retreat due to melting at the grounding line (the grounding line is the contact of the ice sheet with the ocean, where it starts to float and forms an ice shelf or ice tongue). Such rapid ice loss is not yet included in large-scale ice sheet models used for IPCC projections, as most of the complex processes are poorly understood. Here we report on the state-of-the art of grounding line migration in marine ice sheets and address different ways in which grounding line migration can be attributed and represented in ice sheet models. Using one-dimensional ice flow models of the ice sheet/ice shelf system we carried out a number of sensitivity experiments with different spatial resolutions and stress approximations. These are verified with semi-analytical steady state solutions. Results show that, in large-scale finite-difference models, grounding line migration is dependent on the numerical treatment (e.g. staggered/non-staggered grid) and the level of physics involved (e.g. shallow-ice/shallow-shelf approximation).     

Phosphate defects and apatite inclusions in coral skeletal aragonite revealed by solid-state NMR spectroscopy

Recent development of paleo-nutrient proxies based on the phosphorus/calcium (P/Ca) ratio in tropical- and deep-water corals (also known as cold-water corals) require an understanding of the processes by which P is incorporated into the coral skeletal aragonite. Here, we apply single- and double-resonance solid-state nuclear magnetic resonance (NMR) spectroscopy to determine the speciation of P in coral aragonite. The results show that the majority of P occurs as phosphate defects in the aragonite structure, but in many samples a significant fraction of the P occurs also in crystalline hydroxylapatite inclusions. Quantification of the amount of hydroxylapatite indicates that its presence is not related simply to external environmental factors and that it can occur at varying abundances in different parts of the same corallite. Since there is currently no model available to describe the relationship between dissolved inorganic phosphate and its incorporation as apatite inclusions into carbonates, careful screening of samples which contain only phosphate in the aragonite structure or selective microsampling could improve proxy development.     

On the use of IPCC-class models to assess the impact of climate on Living Marine Resources

The study of climate impacts on Living Marine Resources (LMRs) has increased rapidly in recent years with the availability of climate model simulations contributed to the assessment reports of the Intergovernmental Panel on Climate Change (IPCC). Collaboration between climate and LMR scientists and shared understanding of critical challenges for such applications are essential for developing robust projections of climate impacts on LMRs. This paper assesses present approaches for generating projections of climate impacts on LMRs using IPCC-class climate models, recommends practices that should be followed for these applications, and identifies priority developments that could improve current projections. Understanding of the climate system and its representation within climate models has progressed to a point where many climate model outputs can now be used effectively to make LMR projections. However, uncertainty in climate model projections (particularly biases and inter-model spread at regional to local scales), coarse climate model resolution, and the uncertainty and potential complexity of the mechanisms underlying the response of LMRs to climate limit the robustness and precision of LMR projections. A variety of techniques including the analysis of multi-model ensembles, bias corrections, and statistical and dynamical downscaling can ameliorate some limitations, though the assumptions underlying these approaches and the sensitivity of results to their application must be assessed for each application. Developments in LMR science that could improve current projections of climate impacts on LMRs include improved understanding of the multi-scale mechanisms that link climate and LMRs and better representations of these mechanisms within more holistic LMR models. These developments require a strong baseline of field and laboratory observations including long time series and measurements over the broad range of spatial and temporal scales over which LMRs and climate interact. Priority developments for IPCC-class climate models include improved model accuracy (particularly at regional and local scales), inter-annual to decadal-scale predictions, and the continued development of earth system models capable of simulating the evolution of both the physical climate system and biosphere. Efforts to address these issues should occur in parallel and be informed by the continued application of existing climate and LMR models.     

Contribution of horizontal deformation of the seafloor into tsunami generation near the coast of Japan on March 11, 2011

Based on the USGS slip distribution data (Finite Fault Model), the vector field of the seafloor deformation in the source of the tsunami that occurred on March 11, 2011, was calculated. The field of seafloor deformation and distribution of depths in the area of the source were used for reconstruction of the initial elevation of the water surface in the tsunami source. It was found that the contribution of horizontal deformations into the amplitude of the initial elevation, into the displaced water volume, and into the potential energy of the initial elevation is at about 20–25%. Within the framework of the linear theory of long waves, numerical simulation of evolution of the initial elevation was made. The simulation results were compared to the signals recorded by the four deep water stations DART which were the nearest to the source. It was shown that account of the horizontal deformation of the seafloor provides a more precise coincidence between the model and real data. Insignificant differences in arrival times of the model and real signals were interpreted as manifestation of phase dispersion and finite duration for the seafloor deformation to form.     

The dynamics of the snow avalanche affected areas in Piatra Mica mountains (Romania)

This article is intended to explain the snow avalanche occurrence, as a natural phenomenon directly influenced by the local natural conditions, for the well-delimited area represented by the Piatra Mica massif, belonging to the Piatra Craiului mountain range (southern Carpathians). In this respect, depending on the factors that may trigger or encourage the avalanches, some vulnerable areas with avalanche occurring conditions have been identified, based on the analysis of the relationships among the factors controlling the avalanche vulnerability in the study area. These factors are mainly represented by the slope aspect, which induces from the very beginning some specific features for each type of slope (north-, east-, south and west-facing slopes), the geological structure, slope gradient and topography. At the same time, the general climatic and biological features have been taken into account, from the point of view of their importance for avalanche occurrence and distribution. Depending on the microrelief exhibited by the avalanche chutes, one can establish distinct dynamical features for each of the four major slopes of the massif. It is worth mentioning that for this study area, this is the first paper dealing with avalanche phenomenon, vulnerable space, control factors and landscape dynamics. In accomplishing this demarche, we used detailed mappings in the field in several stages, the processing of satellite images, analytical (declivities, the exposure of slopes, etc.) and synthetic maps from which the dynamic of sectors with avalanches resulted. The findings of this investigation may further be employed for solving the problems raised by avalanche-prone areas, as well as for devising a better strategy for the effective management of the mountain realm.