Monitoring and reconstructing past biogeomorphic succession within fluvial corridors using stereophotogrammetry

Past fluvial biogeomorphic succession dynamics, i.e. reciprocal interactions and adjustments between vegetation growth and fluvial landform construction, were monitored and reconstructed using stereophotogrammetry. The four‐dimensional spatio‐temporal stereophotogrammetric analyses were based on the use of archival analogue and digital aerial photographs. First, we tested the relevance of the technique to produce floodplain digital terrain models (DTMs) and cover height models (CHMs) of the dynamic River Allier, France, and compared the models derived from photogrammetric procedures to field measurements for CHMs and to LiDAR data for DTMs. Automatic photogrammetric procedures tended to create inaccurate digital models with production of outliers, incomplete sectors and areas of confusion especially for analogue stereo‐pairs. Expert correction using stereoscopic viewing improved the vertical accuracy of the digital models, but the vegetation height tended to be underestimated: approximately 0.50 m for vegetation heights less than 10 m, up to 1.50 m for tree heights higher than 25 m. Second, we applied this method to a wooded point bar located on the channelized River Garonne, France. At the scale of the point bar, accurate biogeomorphic maps that show terrain and vegetation height changes in all three spatial dimensions were produced and accurate vegetation growth curves from the early stages of establishment until maturity were extracted. Assuming that a set of conditions is satisfied (e.g. spatial scale of investigation, quality of the photographs), our results show that the photogrammetric method applied in this research can be used operationally to detect and quantify present fluvial biogeomorphic dynamics (i.e. changes of topography and vegetation canopy height) within fluvial corridors of temperate rivers with satisfactory accuracy. Copyright © 2016 John Wiley & Sons, Ltd.     

Iron isotope fractionation between pyrite (FeS2), hematite (Fe2O3) and siderite (FeCO3): A first-principles density functional theory study

In addition to equilibrium isotopic fractionation factors experimentally derived, theoretical predictions are needed for interpreting isotopic compositions measured on natural samples because they allow exploring more easily a broader range of temperature and composition. For iron isotopes, only aqueous species were studied by first-principles methods and the combination of these data with those obtained by different methods for minerals leads to discrepancies between theoretical and experimental isotopic fractionation factors. In this paper, equilibrium iron isotope fractionation factors for the common minerals pyrite, hematite, and siderite were determined as a function of temperature, using first-principles methods based on the density functional theory (DFT). In these minerals belonging to the sulfide, oxide and carbonate class, iron is present under two different oxidation states and is involved in contrasted types of interatomic bonds. Equilibrium fractionation factors calculated between hematite and siderite compare well with the one estimated from experimental data (ln α⁵⁷Fe/⁵⁴Fe = 4.59 ± 0.30‰ and 5.46 ± 0.63‰ at 20 °C for theoretical and experimental data, respectively) while those for Fe(III)_aq-hematite and Fe(II)_aq-siderite are significantly higher that experimental values. This suggests that the absolute values of the reduced partition functions (β-factors) of aqueous species are not accurate enough to be combined with those calculated for minerals. When compared to previous predictions derived from Mössbauer or INRXS data [Polyakov V. B., Clayton R. N., Horita J. and Mineev S. D. (2007) Equilibrium iron isotope fractionation factors of minerals: reevaluation from the data of nuclear inelastic resonant X-ray scattering and Mössbauer spectroscopy. Geochim. Cosmochim. Acta71, 3833-3846], our iron β-factors are in good agreement for siderite and hematite while a discrepancy is observed for pyrite. However, the detailed investigation of the structural, electronic and vibrational properties of pyrite as well as the study of sulfur isotope fractionation between pyrite and two other sulfides (sphalerite and galena) indicate that DFT-derived β-factors of pyrite are as accurate as for hematite and siderite. We thus suggest that experimental vibrational density of states of pyrite should be re-examined.     

Populus nigra L. establishment and fluvial landform construction: biogeomorphic dynamics within a channelized river

Populations of the riparian pioneer species Populus nigra L. which establish on alluvial bars within river channels modulate sediment dynamics and fluvial landforms. Dense cohorts of P. nigra have colonized gravel point bars along the channelized River Garonne, France, during the last 20 years and have enhanced the vertical, lateral and longitudinal development of the bars. For this period, the geomorphic characteristics of two wooded point bars on this laterally stable river are closely linked to the spatial distribution and intensity of establishment and resistance of different cohorts of P. nigra. Furthermore, P. nigra colonization dynamics were controlled by engineer effects of this same species. This relationship is illustrated by a significant correlation between key geomorphic and biological variables measured in situ and characterized with a set of four aerial photographs taken between 2000 and 2010. The development of wooded point bars, which are discrete biogeomorphic units, over the studied period, appear to result from a specific biogeomorphic positive feedback of matter aggregation and vegetation establishment related to sediment trapping and stabilization by pioneer engineer plants. We propose a conceptual model of biogeomorphic unit construction for channelized, lateral stable rivers. We consider the resultant biogeomorphic units as functional from an ecological point of view because P. nigra enhances at the cohort scale (i) its own inherent capacity to resist hydrogeomorphic disturbances, and (ii) its resilience capacity as a result of successful colonization, especially downstream of mature poplar stands. Copyright © 2016 John Wiley & Sons, Ltd.     

Observations of contrasted glacial-interglacial dissolution of foraminifera above the lysocline in the Bay of Bengal,northeastern Indian Ocean

Site U1446 (19°50’N, 85°44’E, at water depth 1 430 m) was drilled during Expedition 353 (Indian monsoon rainfall) of the International Ocean Discovery Program (IODP). It is located in the Mahanadi offshore basin, on the northern Bay of Bengal. Sedimentation rates and contents of biocarbonates are high at this relatively shallow site. Using a micropaleontological approach, we examined planktonic and benthic foraminifera in the upper around 40 m of this site, spanning the last around 190 ka. A striking feature of the foraminiferal record is the occurrence of strong but varying dissolution although the site is located well above the modern lysocline. Such strong dissolution has never been reported in this area. We estimated the flux of foraminifera and quantified the ratio of benthic foraminifera over total foraminifera (benthic/total foraminifera) along with the foraminifer fragmentation index in order to characterize past changes in this above-lysocline dissolution. This study reveals a clear glacial-interglacial contrast, with a stronger dissolution during marine isotope stages (MISs) 1 and 5 than during MISs 2–4 and 6. Such a difference in preservation is likely to have a strong impact on geochemical proxies measured on foraminifera. Our new observations call for an in-depth study of the causes of such above-lysocline dissolution in the region, and an evaluation of its impact on the foraminifera-based proxies used for paleoenvironmental reconstruction.     

Holocene and historical earthquakes on the Boconó fault system, southern Venezuelan Andes: Trench confirmation

The Boconó fault system is a major NE-SW, right-lateral strike-slip tectonic feature whose trace extends northeastward for 500 km, from the Tachira depression at the Colombian-Venezuelan border (near the city of Cúcuta) to the town of Morón (located on the Caribbean coast of Venezuela), within the Venezuelan (or Mérida) Andes, and slightly oblique to its main axis. The Boconó fault is morphologically expressed by a continuous straight alignment of longitudinal valleys, linear depressions, pull-apart basins, fault scarps, trenches, sag-ponds, linear ridges and saddles that suggest that this major tectonic feature is active. Moreover, several destructive earthquakes (e.g., 1610, 1812, 1894, 1932 and 1950) affecting the Andean region have been usually attributed to it, without any geological confirmation. Therefore, exploratory trenching on this major fault, the only reliable means of corroborating seismotectonic associations, were carried out at two different sites: slightly north of La Grita and few kilometres north of Cordero (Fundo Mis Delirios); both villages being located between the cities of Mérida and San Cristobal, in the southern part of the Venezuelan Andes. Both trenches revealed that the Boconó fault system has been active during Holocene time. On the one hand, the La Grita trench has particularly demonstrated that: a) the 1610 and 1894 earthquakes occurred along the single trace of the Boconó fault in this region; b) the magnitude of those two earthquakes can be estimated between M = 7.1 and 7.3; c) their return period is about 300 yr; and d) the Holocene oblique-slip rate ranges between 4.3 and 6.1 mm/yr (5.2 ± 0.9 mm/yr) along this segment of the fault system. On the other hand, the Boconó fault at the Mis Delirios trench does not show any deformation associated with the 1610, 1894 or any other historical earthquakes. The complexity of the Boconó fault trace—three active strands have been mapped around the Mis Delrios trench—may account for the lack of such recent ruptures on the excavated strand. However, the occurrence of two to three previous Holocene earthquakes on this fault strand is recorded in the alluvial deposits dug at the trench site.     

NO emissions as observed by SPICAV during stellar occultations

Ultraviolet (UV) nightglow data from the SPICAV instrument (SPectroscopy for the Investigation of the Characteristics of the Atmosphere of Venus) onboard the Venus Express spacecraft, currently in orbit around Venus, are presented. In its extended source mode, SPICAV has shown that the Venus nightglow in the UV contains essentially Lyman-α and Nitric Oxide (NO) emissions. In the stellar mode, when the slit of the spectrometer is removed, an emission is also observed at the limb in addition to the stellar spectrum. A forward model allows us to identify this feature as being an NO emission. Due to radiative recombination of N and O atoms produced on the dayside of Venus, and transported to the nightside, NO nightglow provides important constraints to the Solar-to-Anti Solar thermospheric circulation prevailing above 90 km. The forward model presented here allows us to derive the altitude of the peak of emission of the NO layer, found at 113.5±6 km, as well as its scale height, of 3.4±1 km and its brightness. The latter is found to be very variable with emissions between 19 Kilo-Rayleigh (kR) and 540 kR. In addition, the NO nightglow is sometimes very patchy, as we are able to observe two distinct emission zones in the field of view. Finally, systematic extraction of this emission from stellar occultations extends the database of the NO emission already reported elsewhere using limb observations.     

Hydrogeochemical and multi-tracer investigations of arsenic-affected aquifers in semi-arid West Africa

The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.     

Weathering of sandstone lotus petals at the Angkor site: a 1,000-year stone durability trial

This article is based on field investigations carried out at Ta Keo and Banteay Srei temples (Angkor, Cambodia), which have similar environmental histories and display the same recurrent decorative pattern (lotus petal) in three different sandstone lithotypes. Based on two original scales of mechanical and chemical weathering, the degree of deterioration of c.2000 sandstone petals was visually assessed, resulting in the proposal of a durability scale. An explanatory scheme was provided, based on laboratory analyses of stone materials (ICP-AES, XRD, SEM-EDS, polarizing microscopy and mercury injection). The key drivers of sandstone durability are both mineralogical and petrophysical. The remarkable preservation of the pink sandstone is due to the quartzose nature of its clasts, the non-swelling clay content of its abundant matrix (kaolinite) and its porosity structure (large connected pores and probable non-connected porosity). The overall good preservation of the green sandstone is due to its extremely low porosity and specific surface area, associated with its strong cementation. The severe deterioration of the grey sandstone is due to its laminated structure (oriented biotites), the susceptibility to hygric swelling and solution of its binding agents (chlorite/smectite and calcite) and its porosity structure, which evolves during a two-stage weathering sequence. The first stage is characterized by a bimodal porosity due to the partial clogging of macropores by swelling clays, and the second stage by a substantial increase in porosity and the penetration of salts (barite and anhydrite). Conversely, oxidation phenomena associated with weathering can lead to a drastic reduction of porosity.