Evaluation of the Diurnal Cycle in the Atmospheric Boundary Layer Over Land as Represented by a Variety of Single-Column Models: The Second GABLS Experiment

We present the main results from the second model intercomparison within the GEWEX (Global Energy and Water cycle EXperiment) Atmospheric Boundary Layer Study (GABLS). The target is to examine the diurnal cycle over land in today??s numerical weather prediction and climate models for operational and research purposes. The set-up of the case is based on observations taken during the Cooperative Atmosphere-Surface Exchange Study-1999 (CASES-99), which was held in Kansas, USA in the early autumn with a strong diurnal cycle with no clouds present. The models are forced with a constant geostrophic wind, prescribed surface temperature and large-scale divergence. Results from 30 different model simulations and one large-eddy simulation (LES) are analyzed and compared with observations. Even though the surface temperature is prescribed, the models give variable near-surface air temperatures. This, in turn, gives rise to differences in low-level stability affecting the turbulence and the turbulent heat fluxes. The increase in modelled upward sensible heat flux during the morning transition is typically too weak and the growth of the convective boundary layer before noon is too slow. This is related to weak modelled near-surface winds during the morning hours. The agreement between the models, the LES and observations is the best during the late afternoon. From this intercomparison study, we find that modelling the diurnal cycle is still a big challenge. For the convective part of the diurnal cycle, some of the first-order schemes perform somewhat better while the turbulent kinetic energy (TKE) schemes tend to be slightly better during nighttime conditions. Finer vertical resolution tends to improve results to some extent, but is certainly not the solution to all the deficiencies identified.     

Modeling regional sediment transport and shoreline response in the vicinity of tidal inlets on the Long Island coast,United States

A new numerical model was developed to simulate regional sediment transport and shoreline response in the vicinity of tidal inlets based on the one-line theory combined with the reservoir analogy approach for volumetric evolution of inlet shoals. Sand bypassing onshore and sheltering effects on wave action from the inlet bar and shoals were taken into account. The model was applied to unique field data from the south coast of Long Island, United States, including inlet opening and closure. The simulation area extended from Montauk Point to Fire Island Inlet, including Shinnecock and Moriches Inlets. A 20-year long time series of hindcast wave data at three stations along the coast were used as input data to the model. The capacity of the inlet shoals and bars to store sand was estimated based on measured cross-sectional areas of the inlets as well as on comprehensive bathymetric surveys of the areas around the inlet. Several types of sediment sources and sinks were represented, including beach fills, groin systems, jetty blocking, inlet bypassing, and flood shoal and ebb shoal feeding. The model simulations were validated against annual net longshore transport rates reported in the literature, measured shorelines, and recorded sediment volumes in the flood and ebb shoal complexes. Overall, the model simulations were in good agreement with the measured data.     

Atom‐probe analyses of nanodiamonds from Allende

Atom‐probe tomography (APT) is currently the only analytical technique that, due to its spatial resolution and detection efficiency, has the potential to measure the carbon isotope ratios of individual nanodiamonds. We describe three different sample preparation protocols that we developed for the APT analysis of meteoritic nanodiamonds at sub‐nm resolution and present carbon isotope peak ratios of meteoritic and synthetic nanodiamonds. The results demonstrate an instrumental bias associated with APT that needs to be quantified and corrected to obtain accurate isotope ratios. After this correction is applied, this technique should allow determination of the distribution of ¹²C/¹³C ratios in individual diamond grains, solving the decades‐old question of the origin of meteoritic nanodiamonds: what fraction, if any, formed in the solar system and in presolar environments? Furthermore, APT could help us identify the stellar sources of any presolar nanodiamonds that are detected.     

The Jovian atmospheric window at 2.7 μm: A search for H2S

The atmospheric transmission window at 2.7 μm in Jupiter's atmosphere was observed at a spectral resolution of 0.1 cm^?1 from the Kuiper Airborne Observatory. From analysis of the CH₄ abundance (～80m-am) and the H₂O abundance (<0.0125cm-am) it was determined that the penetration depth of solar flux at 2.7 μm is near the base of the NH₃ cloud layer. The upper limit to H₂O at 2.7 μm and other recent results suggest that photolytic reactions in Jupiter's lower troposphere may not be as significant as was previously thought. The search for H₂S in Jupiter's atmosphere yielded an upper limit of ～0.1cm-am. The corresponding limit to the elemental abundance ratio [S]/[H] was ～1.7 × 10^?8, about 10^?3 times the solar value. Upon modeling the abundance and distribution of H₂S in Jupiter's atmosphere it was concluded that, contrary to expectations, sulfur-bearing chromophores are not present in significant amounts in Jupiter's visible clouds. Rather, it appears that most of Jupiter's sulfur is locked up as NH₄SH in a lower cloud layer. Alternatively, the global abundance of sulfur in Jupiter may be significantly depleted.     

The composition of asteroid 2 Pallas and its relation to primitive meteorites

High resolution spectroscopic observations of asteroid 2 Pallas from 1.7-3.5 μm are reported. These data are combined with previous measurements from 0.4-1.7 μm to interpret Pallas' surface mineralogy. Evidence is found for low-Fe²⁺ hydrated silicates, opaque components, and low-Fe²⁺ anhydrous silicates. This assemblage is very similar to carbonaceous chondrite matrix material such as is found in type CI and CM meteorites, but it has been subjected to substantial aqueous alteration and there is a major extraneous anhydrous silicate component. This composition is compared to that of asteroid 1 Ceres. Although there are substantial differences in their broad band spectral reflectances, it appears that both asteroids are genetically related to known carbonaceous chondrites.     

Correlation of Winds and Geographic Features with Production of Certain Infrasonic Signals in the Atmosphere

Summary Of the waves which propagate in the atmosphere at acoustic velocity in the period range from 10 to 100 s, one type has been classified by triangulation as arising principally from mountainous regions. These signals were first described as 'northwesters' or '310 ers' by the NBS Geoacoustics Group under R. K. Cook at Washington, D.C., from the predominant direction of arrival. Subsequent operation of an observatory at Boulder, Colorado by Vernon Goerke gave a source region by triangulation in the Pacific Northwest, primarily in Montana and Alberta. Installations of observatories at College, Alaska (Wilson) and Pullman, Washington-Moscow, Idaho (Craine and Thomas) enlarged the data base available, and triangulation showed the principal source areas to be along the coast of British Columbia and in the inland Rocky Mountains of the British Columbia-Alberta border. This paper discusses the presently known characteristics of this class of infrasonic waves, locates the triangulation areas, reviews selected events, and suggests that certain of these waves are produced as aerodynamic sound. The paper shows a correlation between the 500 mb jet stream velocity and direction in these mountainous regions, and the detection of these atmospheric pressure waves.     

Reaching the limits: a geographic approach for understanding food insecurity and household hunger mitigation strategies in Minneapolis-Saint Paul, USA

Research on hunger and food security in the Global South and the Global North has often emphasized different factors and scales of analyses. Unlike newer monitoring systems in the Global South, which evolved substantially following critiques by Amartya Sen, US food security research has rarely combined the two dimensions of food availability and food access. Furthermore, this research has paid scant attention to household coping strategies. This study responds to this lacuna in US hunger research by developing a spatial model for predicting risk to food insecurity based on proxy measures for access (three demographic variables) and availability (grocery store density). The study then employs qualitative methodologies (surveys and semi-structured interviews) to understand household coping strategies in two ethnically distinct areas in Minneapolis-Saint Paul at risk to food insecurity. One neighborhood is dominated by Southeast Asian and East African immigrants and the other by African-Americans. This approach should allow for better targeting of food aid and programs that help alleviate food insecurity.     

Genesis of the post-caldera eastern Upper Basin Member rhyolites, Yellowstone, WY: from volcanic stratigraphy, geochemistry, and radiogenic isotope modeling

An array of samples from the eastern Upper Basin Member of the Plateau Rhyolite (EUBM) in the Yellowstone Plateau, Wyoming, were collected and analyzed to evaluate styles of deposition, geochemical variation, and plausible sources for low δ¹⁸O rhyolites. Similar depositional styles and geochemistry suggest that the Tuff of Sulphur Creek and Tuff of Uncle Tom’s Trail were both deposited from pyroclastic density currents and are most likely part of the same unit. The middle unit of the EUBM, the Canyon flow, may be composed of multiple flows based on a wide range of Pb isotopic ratios (e.g., ²⁰⁶Pb/²⁰⁴Pb ranges from 17.54 to 17.86). The youngest EUBM, the Dunraven Road flow, appears to be a ring fracture dome and contains isotopic ratios and sparse phenocrysts that are similar to extra-caldera rhyolites of the younger Roaring Mountain Member. Petrologic textures, more radiogenic ⁸⁷Sr/⁸⁶Sr in plagioclase phenocrysts (0.7134–0.7185) than groundmass and whole-rock ratios (0.7099–0.7161), and δ¹⁸O depletions on the order of 5‰ found in the Tuff of Sulphur Creek and Canyon flow indicate at least a two-stage petrogenesis involving an initial source rock formed by assimilation and fractional crystallization processes, which cooled and was hydrothermally altered. The source rock was then lowered to melting depth by caldera collapse and remelted and erupted. The presence of a low δ¹⁸O extra-caldera rhyolite indicates that country rock may have been hydrothermally altered at depth and then assimilated to form the Dunraven Road flow.     

A new radiocarbon chronology of Baumkirchen,stratotype for the onset of the Upper Würmian in the Alps

The start of the Upper Würmian in the Alps was marked by massive fluvioglacial aggradation prior to the arrival of the Central Alpine glaciers. In 1984, the Subcommission on European Quaternary Stratigraphy defined the clay pit of Baumkirchen (in the foreland of the Inn Valley, Austria) as the stratotype for the Middle to Upper Würmian boundary in the Alps. Key for the selection of this site was its radiocarbon chronology, which still ranks among the most important datasets of this time interval in the Alps. In this study we re‐sampled all available original plant specimens and established an accelerator mass spectrometry chronology which supersedes the published 40‐year‐old chronology. The new data show a much smaller scatter and yielded slightly older conventional radiocarbon dates clustering at ca. 31 ¹⁴C ka BP. When calibrated using INTCAL13 the new data suggest that the sampled interval of 653–681 m in the clay pit was deposited 34–36 cal ka BP. Using two new radiocarbon dates of bone fragments found in the fluvioglacial gravel above the banded clays allows us to constrain the timing of the marked change from lacustrine to fluvioglacial sedimentation to ca. 32–33 cal ka BP, which suggests a possible link to the Heinrich 3 event in the North Atlantic. Copyright © 2013 John Wiley & Sons, Ltd.     

Degassing of Cl, F, Li, and Be during extrusion and crystallization of the rhyolite dome at Volcán Chaitén, Chile during 2008 and 2009

We investigated the distribution of Cl, F, Li, and Be in pumices, obsidians, and crystallized dome rocks at Chaitén volcano in 2008?C2009 in order to explore the behavior of these elements during explosive and effusive volcanic activity. Electron and ion microprobe analyses of matrix and inclusion glasses from pumice, obsidian, and microlite-rich dome rock indicate that Cl and other elements were lost primarily during crystallization of the rhyolitic dome after it had approached the surface. Glass in pumice and microlite-free obsidian has 888?±?121?ppm Cl, whereas residual glass in evolved microlite-rich dome rock generally retains less Cl (as low as <100?ppm). Estimated Cl losses were likely >0.7?Mt Cl, with a potential maximum of 1.8?Mt for the entire 0.8-km³ dome. Elemental variations reflect an integrated bulk distribution ratio for Cl?>?1.7 (1.7 times more Cl was degassed or incorporated into crystals than remained in the melt). Because Cl is lost dominantly as the very last H₂O is degassed, and Cl is minimally (if at all) partitioned into microlites, the integrated vapor/melt distribution ratio for Cl exceeds 200 (200 times more Cl in the evolved vapor than in the melt). Cl is likely lost as HCl, which is readily partitioned into magmatic vapor at low pressure. Cl loss is accelerated by the change in the composition of the residual melt due to microlite growth. Cl loss also may be affected by open-system gas fluxing. Integrated vapor-melt distribution ratios for Li, F, and Be all exceed 1,000. On degassing, an unknown fraction of these volatiles could be immediately dissolved in rainwater.