Effects of slight anisotropy on surface waves

We present a complete ray theory for the calculation of surface-wave observables from anisotropic phase-velocity maps. Starting with the surface-wave dispersion relation in an anisotropic earth model, we derive practical dynamical ray-tracing equations. These equations allow calculation of the observables phase, arrival-angle and amplitude in a ray theoretical framework. Using perturbation theory, we also obtain approximate expressions for these observables. We assess the accuracy of the first-order approximations by using both theories to make predictions on a sample anisotropic phase-velocity map. A comparison of the two methods illustrates the size and type of errors which are introduced by perturbation theory. Perturbation theory phase and arrival-angle predictions agree well with the exact calculation, but amplitude predictions are poor. Many previous studies have modelled surface-wave propagation using only isotropic structure, not allowing for anisotropy. We present hypothetical examples to simulate isotropic modelling of surface waves which pass through anisotropic material. Synthetic data sets of phase and arrival angle are produced by ray tracing with exact ray theory on anisotropic phase-velocity maps. The isotropic models obtained by inverting synthetic anisotropic phase data sets produce deceptively high variance reductions because the effects of anisotropy are mapped into short-wavelength isotropic structure. Inversion of synthetic arrival-angle data sets for isotropic models results in poor variance reductions and poor recovery of the isotropic part of the anisotropic input map. Therefore, successful anisotropic phase-velocity inversions of real data require the inclusion of both phase and arrival-angle measurements.     

Tectonics of the Nazca-Antarctic plate boundary

We have constructed a new bathymetric chart of part of the Chile transform system, based mainly on an R/V “Endeavor” survey from 100°W to its intersection with the East Ridge of the Juan Fernandez microplate at 34°30′S, 109°15′W. A generally continuous lineated trend can be followed through the entire region, with the transform valley being relatively narrow and well-defined from 109°W to approximately 104°30′W. The fracture zone then widens to the east, with at least two probable en echelon offsets to the south at 104° and 102°W. Six new strike-slip mechanisms along the Chile Transform and one normal fault mechanism near the northern end of the Chile Rise, inverted together with other plate motion data from the eastern portion of the boundary, produce a new best fit Euler pole for the Nazca-Antarctic plate pair, providing tighter constraints on the relative plate motions.     

Pressure-temperature microscopy of coal liquefaction

A pressure-temperature microscopy system (PTM) has been developed for obtaining observations on coals and heavy hydrocarbons at elevated temperatures and hudrogen pressures commonly used in the hydroprocessing of coal, coal liquids, and petroleum residua. A Pittsburgh #8 seam coal, from near New Eagle in Washington County located south of Pittsburgh, Penna., was extensively characterized by petrographic analysis, proximate and ultimate analysis, Gieseler plastometer, and Ruhr dilatometry as well as data on grindability, ash characteristics, and oxidation properties. Novel direct microscopic observations at elevated temperatures and pressures with catalysts give observable changes in phase transition behavior of coal. Direct microscopic observations of fresh vitrain particles at elevated temperature and high nitrogen pressure in the presence of a tin chloride catalyst show plastic deformation. Upon replacement of nitrogen by pressurized hydrogen, individual vitrain particles are observed to liquefy in the presence of molten tin. After liquefaction, further temperature increase at 1950 psig hydrogen results in the formation of mesophase and the segregation of the molten tin.Pressure-temperature microscopy is also presented on the liquefaction behavior of a solvent-refined coal (SRC) from Wilsonville, Ala. Additional pressure-temperature microscopy is presented on the tin-catalyzed co-liquefaction behavior of the solvent-refined coal with the Pittsburgh #8 seam vitrain. The pressure-temperature microscopy of the liquefaction experiments and mesophase development have been video recorded and are available for viewing.     

Saturn's ring and nearby faint satellites

Observations of Saturn's rings during passage of the Earth through the ring plane, coupled with those of others, suggest a ring thickness of 1.3 ± 0.3 km. The wide disparity in the optical depth of Cassini's division found by other investigators is resolved, and for conservative isotropic single scattering, a normal optical depth for Cassini's division of 0.060 ± 0.006 is obtained. We find the mean normal optical depth of ring C to be 0.074 ± 0.007. Analysis of all available observations of faint objects near Saturn indicates the presence of at least one previously undiscovered satellite of Saturn. The orbit for Janus determined by Dollfus is supported. These satellites may be major members of an extended ring.     

Observations of the Saturn D ring

Observations of Saturn at both large and small phase angles were obtained in the 890-nm methane band with a solid state charge coupled device (CCD). When model intensity profiles are convolved with appropriate point spread functions, intensity levels ranging from 5 to 3% of the maximum of ring B are required in the ring D region of the models to match the data, in substantial agreement with previous results obtained through photographic photometry. The normal optical thickness of the D ring is about 0.02 and seems to show the same phase function as the other rings. The division between the C and D ring was not observed, possibly due to the seeing limited image resolution.     

Paleoindian bison procurement and paleoenvironments in Middle Park of Colorado

The Upper Twin Mountain Site, located within a geologic slump scar at 2548 m altitude, provides significant information on Paleoindian bison procurement. As the highest known Paleoindian bison bone bed, the site contained the partial skeletal remains of at least 15 adult Late Pleistocene bison (B. antiquus), Goshen projectile points, and debitage. Radiocarbon dates of 10,240±70 and 10,470±50 yr B.P. place Upper Twin Mountain midway between the northern Plains Goshen and southern Plains Plainview sites. With a late fall or early winter mortality of the bison and the presence of only local stone, year round occupation of Middle Park is indicated. Analysis of the geology, soil, and pollen, from the archaeological and nonarchaeological deposits at the Upper Twin Mountain and elsewhere in the region are used to describe the paleoenvironmental conditions in Middle Park. © 1999 John Wiley & Sons, Inc.     

Controls on Methane Occurrences in Shallow Aquifers Overlying the Haynesville Shale Gas Field,East Texas

Understanding the source of dissolved methane in drinking‐water aquifers is critical for assessing potential contributions from hydraulic fracturing in shale plays. Shallow groundwater in the Texas portion of the Haynesville Shale area (13,000 km²) was sampled (70 samples) for methane and other dissolved light alkanes. Most samples were derived from the fresh water bearing Wilcox formations and show little methane except in a localized cluster of 12 water wells (17% of total) in a approximately 30 × 30 km² area in Southern Panola County with dissolved methane concentrations less than 10 mg/L. This zone of elevated methane is spatially associated with the termination of an active fault system affecting the entire sedimentary section, including the Haynesville Shale at a depth more than 3.5 km, and with shallow lignite seams of Lower Wilcox age at a depth of 100 to 230 m. The lignite spatial extension overlaps with the cluster. Gas wetness and methane isotope compositions suggest a mixed microbial and thermogenic origin with contribution from lignite beds and from deep thermogenic reservoirs that produce condensate in most of the cluster area. The pathway for methane from the lignite and deeper reservoirs is then provided by the fault system.     

Controls on Methane Occurrences in Aquifers Overlying the Eagle Ford Shale Play,South Texas

Assessing natural vs. anthropogenic sources of methane in drinking water aquifers is a critical issue in areas of shale oil and gas production. The objective of this study was to determine controls on methane occurrences in aquifers in the Eagle Ford Shale play footprint. A total of 110 water wells were tested for dissolved light alkanes, isotopes of methane, and major ions, mostly in the eastern section of the play. Multiple aquifers were sampled with approximately 47 samples from the Carrizo‐Wilcox Aquifer (250‐1200 m depth range) and Queen City‐Sparta Aquifer (150‐900 m depth range) and 63 samples from other shallow aquifers but mostly from the Catahoula Formation (depth <150 m). Besides three shallow wells with unambiguously microbial methane, only deeper wells show significant dissolved methane (22 samples >1 mg/L, 10 samples >10 mg/L). No dissolved methane samples exhibit thermogenic characteristics that would link them unequivocally to oil and gas sourced from the Eagle Ford Shale. In particular, the well water samples contain very little or no ethane and propane (C1/C2+C3 molar ratio >453), unlike what would be expected in an oil province, but they also display relatively heavier δ¹³C_methane (>?55‰) and δD_methane (>?180‰). Samples from the deeper Carrizo and Queen City aquifers are consistent with microbial methane sourced from syndepositional organic matter mixed with thermogenic methane input, most likely originating from deeper oil reservoirs and migrating through fault zones. Active oxidation of methane pushes δ¹³C_methane and δD_methane toward heavier values, whereas the thermogenic gas component is enriched with methane owing to a long migration path resulting in a higher C1/C2+C3 ratio than in the local reservoirs.     

An Analysis of the Relationship between Residents' Proximity to Water and Attitudes about Resource Protection*

This article investigates attitudes toward water resource protection among residents in varying proximities to resources, specifically to identify attitudinal differences and the extent to which nearness and adjacency explain attitudes. Proximity was evaluated by measured distances using GIS and reported closeness from a mail survey. Five attitudinal dimensions were assessed: general importance of resource protection, support for government, regulations, and economic measures, and combined overall attitudes. Nearness to water was most significant in explaining economic support, and adjacency for generally expressed importance. Attitudes differed most toward regulations. Overall, the relationship appears nonlinear. Empirical findings have implications for resource management, especially equity criteria in decision making.