The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

Gravel sediment routing from widespread,low- intensity landscape disturbance,Current River Basin,Missouri

During the last 160 years, land-use changes in the Ozarks have had the potential to cause widespread, low-intensity delivery of excess amounts of gravel-sized sediment to stream channels. Previous studies have indicated that this excess gravel bedload is moving in wave-like forms through Ozarks drainage basins. The longitudinal, areal distribution of gravel bars along 160 km of the Current River, Missouri, was evaluated to determine the relative effects of valley-scale controls, tributary basin characteristics, and lagged sediment transport in creating areas of gravel accumulations. The longitudinal distribution of gravel-bar area shows a broad scale wave-like form with increases in gravel-bar area weakly associated with tributary junctions. Secondary peaks of gravel area with 1·8–4·1 km spacing (disturbance reaches) are superimposed on the broad form. Variations in valley width explain some, but not all, of the short-spacing variation in gravel-bar area. Among variables describing tributary drainage basin morphometry, present-day land use and geologic characteristics, only drainage area and road density relate even weakly to gravel-bar areal inventories. A simple, channel network-based sediment routing model shows that many of the features of the observed longitudinal gravel distribution can be replicated by uniform transport of sediment from widespread disturbances through a channel network. These results indicate that lagged sediment transport may have a dominant effect on the synoptic spatial distribution of gravel in Ozarks streams; present-day land uses are only weakly associated with present-day gravel inventories; and valley-scale characteristics have secondary controls on gravel accumulations in disturbance reaches. Copyright © 1999 John Wiley & Sons, Ltd.     

The Reference Manure Concept for Transformation Tests of Veterinary Medicines and Biocides in Liquid Manure

Veterinary medicines and biocides are frequently applied in animal houses of livestock husbandry. Due to these application patterns, they reach liquid manure. So far these substances are not transformed during manure storage, they enter soil by the application of manure as organic fertilizer. Therefore, biodegradability of veterinary medicines and biocides in manure is in the focus of regulatory procedures of environmental risk assessment. Since the representative and reproducible sampling of manures from high volume tanks is considered impossible due to high matrix variabilities, the reference manure concept was developed to utilize liquid bovine and pig manures for reproducible laboratory testing. Accordingly, excrement samples of cattle and pigs individually kept at experimental and conventional animal houses were taken. Tap water was added to matrix characterized excrements in order to prepare bovine and pig reference manures of 10 and 5% dry substance contents, respectively. Subsequently, the long‐term transformation of selected ¹⁴C‐labeled test substances was investigated under strictly anaerobic conditions. The application of different batches of bovine or pig reference manures indicated that extrapolation of transformation rates within the same animal species was possible. However, results cannot be transferred from bovine to pig manure because of substance specific interactions with the different manure matrices. The dependency of metabolic dynamics on different dry substance contents (2.5, 5, 10%) was additionally investigated in both manure matrices. These tests clearly showed that the dry substance content of the reference manure is one of the most relevant factors affecting the transformation of veterinary medicines and biocides. In contrast to highly variable tank manures, the reference manure concept allows for the exact adjustment of this parameter to guarantee reproducible laboratory testing.     

Mercury in some granitoid rocks of the yukon and its relation to gold-tungsten mineralization

Data for the mean mercury contents of some granitoid rocks of the Yukon are presented. A correlation of high mercury content with plutons postulated to be the sources, or genetically related to the sources, of the alluvial gold deposits of the McQuesten area is established. In addition a relation is indicated between high mercury content in one intrusion and high content in the Palaeozoic shale host rock. A limited amount of data is presented on the mercury content of the Proterozoic and Palaeozoic rocks of the sampled area.     

Evaluation of Multi-Frequency-Microwave-Radiometer-System performance for oceanography

A technique is presented for constructing a mathematical model of a Multi-Frequency Microwave Radiometer System. The technique combines the different responses of microwave radiometers with models of the sea surface, the effects of the Earth's atmosphere and of the sky emission. A linear perturbation method and a more accurate non-linear method are outlined for processing of data simultaneously collected by the radiometers. The mathematical model of the Radiometer System combined with the linear data-processing method is useful for predicting in-flight sensor performance. Based on a chosen performance function, an evaluation of a spaceborne Multi-Frequency Microwave Radiometer System is given.     

On the topographic bias in geoid determination by the external gravity field

The topographic bias is defined as the error/bias committed by continuing the external gravity field inside the topographic masses by a harmonic function. We study the topographic bias given by a digital terrain model defined by a spherical template, and we show that the topographic bias is given only by the potential of an inner-zone cap, and it equals the bias of the Bouguer shell, independent of the size of the cap. Then we study the effect on the real Earth by decomposing its topography into a template, and we show also in this case that the topographic bias is that of the Bouguer shell, independent of the shape of the terrain. Finally, we show that the topographic potential of the terrain at the geoid can be determined to any precision by a Taylor expansion outside the Earth’s surface. The last statement is demonstrated by a Taylor expansion to fourth order.     

Geodetic intersection on the ellipsoid

Through each of two known points on the ellipsoid a geodesic is passing in a known azimuth. We solve the problem of intersection of the two geodesics. The solution for the latitude is obtained as a closed formula for the sphere plus a small correction, of the order of the eccentricity of the ellipsoid, which is determined by numerical integration. The solution is iterative. Once the latitude is obtained, the longitude is determined without iteration.