Monitoring of Irgarol 1051 concentrations with concurrent phytoplankton evaluations in East Coast areas of the United States

The objectives of this study were to measure: (1) Irgarol and GS26575 (major metabolite) during the peak 2004 boating season at selected marinas and reference areas in the Carolinian Zoogeographic Province of the Eastern United States; (2) Irgarol and GS26575 at selected stations during the summer months in the Back Creek/Severn River area in Maryland in 2003 and 2004; and (3) structural and functional characteristics of resident phytoplankton communities concurrently with Irgarol and GS26575 monitoring in Back Creek/Severn River area. Irgarol concentrations from 14 marinas in the Carolinian Province ranged from non-detectable (<1 ng/L) to 85 ng/L; concentrations were less than 16 ng/L at all reference sites. The probability of exceeding the plant 10th centile for Irgarol (251 ng/L) was less than 0.6% for all marinas and 0.01% for all reference areas. These data suggest low ecological risk from Irgarol exposure for both marina and reference areas in the Carolinian Province. Irgarol concentrations ranged from 5 ng/L at the Severn River reference site to 1,816 ng/L in Port Annapolis marina during the two year study. Ecological risk from Irgarol exposure was high for the Port Annapolis marina sites based on a probability of exceeding the plant 10th centile. However, risk was low for Severn River and Severn River reference sites. Functional and structural measures of resident phytoplankton communities in the Back Creek and Severn River did not suggest that these target species are impaired in the Port Annapolis marina area where probabilistic analysis predicted adverse effects from Irgarol exposure.     

The eruptive history of the Tequila volcanic field, western Mexico: ages, volumes, and relative proportions of lava types

The eruptive history of the Tequila volcanic field (1600 km²) in the western Trans-Mexican Volcanic Belt is based on ⁴⁰Ar/³⁹Ar chronology and volume estimates for eruptive units younger than 1 Ma. Ages are reported for 49 volcanic units, including Volcán Tequila (an andesitic stratovolcano) and peripheral domes, flows, and scoria cones. Volumes of volcanic units 1 Ma were obtained with the aid of field mapping, ortho aerial photographs, digital elevation models (DEMs), and ArcGIS software. Between 1120 and 200 kyrs ago, a bimodal distribution of rhyolite (~35 km³) and high-Ti basalt (~39 km³) dominated the volcanic field. Between 685 and 225 kyrs ago, less than 3 km³ of andesite and dacite erupted from more than 15 isolated vents; these lavas are crystal-poor and show little evidence of storage in an upper crustal chamber. Approximately 200 kyr ago, ~31 km³ of andesite erupted to form the stratocone of Volcán Tequila. The phenocryst assemblage of these lavas suggests storage within a chamber at ~2–3 km depth. After a hiatus of ~110 kyrs, ~15 km³ of andesite erupted along the W and SE flanks of Volcán Tequila at ~90 ka, most likely from a second, discrete magma chamber located at ~5–6 km depth. The youngest volcanic feature (~60 ka) is the small andesitic volcano Cerro Tomasillo (~2 km³). Over the last 1 Myr, a total of 128±22 km³ of lava erupted in the Tequila volcanic field, leading to an average eruption rate of ~0.13 km³/kyr. This volume erupted over ~1600 km², leading to an average lava accumulation rate of ~8 cm/kyr. The relative proportions of lava types are ~22–43% basalt, ~0.4–1% basaltic andesite, ~29–54% andesite, ~2–3% dacite, and ~18–40% rhyolite. On the basis of eruptive sequence, proportions of lava types, phenocryst assemblages, textures, and chemical composition, the lavas do not reflect the differentiation of a single (or only a few) parental liquids in a long-lived magma chamber. The rhyolites are geochemically diverse and were likely formed by episodic partial melting of upper crustal rocks in response to emplacement of basalts. There are no examples of mingled rhyolitic and basaltic magmas. Whatever mechanism is invoked to explain the generation of andesite at the Tequila volcanic field, it must be consistent with a dominantly bimodal distribution of high-Ti basalt and rhyolite for an 800 kyr interval beginning ~1 Ma, which abruptly switched to punctuated bursts of predominantly andesitic volcanism over the last 200 kyrs.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial responsility: J. Donnelly-NolanThis revised version was published online in January 2005 with corrections to Tables 1 and 3.An erratum to this article can be found at     

Statistical arguments for asteroidal jet streams

The distribution of asteroid orbits in space is studied and a detailed investigation for Hirayama's Flora family is presented. Some tendencies to (5-dimensional) clustering are found by means of comparing actual with random distribution simulated on a computer.     

Interannual variation of Gulf Stream heat transport in a high-resolution model forced by reanalysis data

The variability present in a 1/6th degree Atlantic ocean simulation forced by analysed wind stress and heat flux over a 20-year period is investigated by means of heat transport diagnostics. A section is defined which follows the Gulf Stream and its seaward extension, and transport of heat across this section is analysed to reveal the physical mechanisms responsible for intergyre heat exchanges on a variety of time scales. Heat transport across another section that crosses the Gulf Stream is also diagnosed to reveal the temporal behaviour of the gyre circulation. The Ekman response to wind stress variations accounts for the annual cycle and much of the interannual variability in both measures. For the intergyre heat transports, cancellation by transient-mean flow terms leads to a very weak annual cycle. Transient eddies account for approximately half the total intergyre transport of 0.7 Petawatts. They also account for a significant fraction of the interannual variability, but separate experiments with repeated-annual-cycle forcing indicate that the transient eddy component of the heat transport variability is internally generated. Links between the intergyre transport, the wind-driven gyre circulation, the surface heat budget and the atmospheric North Atlantic Oscillation are discussed.     

The ellipsoidal corrections to the topographic geoid effects

The topographic effects by Stokes formula are typically considered for a spherical approximation of sea level. For more precise determination of the geoid, sea level is better approximated by an ellipsoid, which justifies the consideration of the ellipsoidal corrections of topographic effects for improved geoid solutions. The aim of this study is to estimate the ellipsoidal effects of the combined topographic correction (direct plus indirect topographic effects) and the downward continuation effect. It is concluded that the ellipsoidal correction to the combined topographic effect on the geoid height is far less than 1 mm. On the contrary, the ellipsoidal correction to the effect of downward continuation of gravity anomaly to sea level may be significant at the 1-cm level in mountainous regions. Nevertheless, if Stokes formula is modified and the integration of gravity anomalies is limited to a cap of a few degrees radius around the computation point, nor this effect is likely to be significant.AcknowledgementsThe author is grateful for constructive remarks by J Ågren and the three reviewers.     

Mean and eddy motion in the Skagerrak/northern North Sea: insight from a numerical model

Insight regarding the mean and eddy motion in the Skagerrak/northern North Sea area is gained through an analysis of model-simulated currents, hydrography, kinetic energy and relative vorticity for the 2 years 2000 and 2001. In this a -coordinate ocean model is used. Since the tidal currents are generally strong in the area, care is exercised to distinguish the mesoscale (eddy) motion from higher-frequency motion such as tides, before computing the mean and eddy kinetic energy. The model-simulated response is first compared with available knowledge of the circulation in the area, and when available, also with sea-surface temperature obtained from satellite imagery. It is concluded that the model appears to faithfully reproduce most of what is known, in particularly the upper mixed layer circulation. An analysis of the mean and eddy kinetic energy reveals that many of the mesoscale structures found in the area are recurrent. This is particularly true for the structures off the southern tip of Norway. Also in general, areas of strong mean and eddy kinetic energy are co-located. The exception is the area off the southern tip of Norway, where the eddy kinetic energy is much larger than its mean counterpart. An analysis of the relative vorticity reveals that the variability found is due to the occurrence of recurrent anticyclonic eddies. It is hypothesized that these eddies are generated due to an offshore veering of the Norwegian coastal current (NCC) as it reaches the eastern end of the Norwegian Trench plateau. Here it becomes a free jet, which is then vulnerable to either barotropic instability caused by the horizontal shear in the jet-like structure of the NCC at this point, or a baroclinic (frontal) instability. The latter may come into play when the NCC veers offshore and its relatively fresh water meets the inflowing saline water of Atlantic origin, a frontogenesis that may become strong enough for cyclogenesis to take place. Due to the depth-independent nature of the model-generated eddies, the barotropic instability is the most likely candidate. It remains to resolve the reason for the offshore veering of the NCC. The most likely candidate mechanisms are vortex squeezing or simply that the coastline curvature is large enough for the NCC to separate from the coast in a hydraulic sense.Responsible Editor: Phil Dyke     

Tidal currents,energy flux and bottom boundary layer thickness in the Clyde Sea and North Channel of the Irish Sea

A high-resolution three-dimensional model of the Clyde Sea and the adjacent North Channel of the Irish Sea is used to compute the major diurnal and semidiurnal tides in the region, the associated energy fluxes and thickness of the bottom boundary layer. Initially, the accuracy of the model is assessed by performing a detailed comparison of computed tidal elevations and currents in the region, against an extensive database that exists for the M₂, S₂, N₂, K₁ and O₁ tides. Subsequently, the model is used to compute the tidal energy flux vectors in the region. These show that the major energy flux is confined to the North Channel region, with little energy flux into the Clyde Sea. Comparison with the observed energy flux in the North Channel shows that its across-channel distribution and its magnitude are particularly sensitive to the phase difference between elevation and current. Consequently, small changes in the computed values of these parameters due to slight changes of the order of the uncertainty in the open-boundary values to the model, can significantly influence the computed energy flux. The thickness of the bottom boundary layer in the region is computed using a number of formulations. Depending upon the definition adopted, the empirical coefficient C used to determine its thickness varies over the range 0.1 to 0.3, in good agreement with values found in the literature. In the North Channel, the boundary layer thickness occupies the whole water depth, and hence tidal turbulence produced at the sea bed keeps the region well mixed. In the Clyde Sea, the boundary layer thickness is a small fraction of the depth, and hence the region stratifies.Responsible Editor: Phil Dyke     

Use of biliary PAH metabolites as a biomarker of pollution in fish from the Baltic Sea

During field campaigns of the BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems) in 2001-2002, metabolites of polycyclic aromatic hydrocarbons (PAHs) were determined in bile samples from three fish species, flounder (Platichthys flesus), perch (Perca fluviatilis) and eelpout (Zoarces viviparus), from four separate areas in the Baltic Sea. Two determination methods were applied: fixed wavelength fluorescence (FF) for pyrene-type metabolites and high-performance liquid chromatography with fluorescence detection (HPLC). There was a good correlation between the FF method and 1-OH pyrene determined by HPLC. Normalisation of the FF data for absorbance at 380 nm or bile protein concentrations greatly increased variance in one third and decreased it in two thirds of the cases and resulted in a loss of significant differences (protein normalisation) between the sampling stations, but normalisation of the HPLC data had little effect on the results. The biliary PAH metabolite content was usually higher in males than in females. In perch and eelpout the biliary PAH contents were at similar levels, whereas in flounder the levels were lower. The sampling areas arranged in decreasing order of biliary PAH contents were: Wismar Bay > Gulf of Gdansk > Lithuanian coast > Kvadofj?rden (reference area). It is concluded that FF with un-normalised data is a reliable and simple method for monitoring purposes and only one sex of a selected species should be used.     

The positions of H+, Li+ and Na+ impurities in beryl

Electron Paramagnetic Resonance (EPR) measurements show that Li⁺ impurities are located at two different positions in beryl, one in the crystal lattice and the other in the crystal channel. The position of the Li⁺ impurity in the lattice is generally assumed to be at the site of a missing Be²⁺ ion. It is shown that this is not the case, but that the Li⁺ ion is located in a tetrahedron formed by the oxygens of one side of the Be tetrahedron and the nearest oxygen in the channel ring. This Li site has the coordinates (0.423, 0.344, 0.167) and can only be occupied when the neighbouring Be site is empty. There are four such sites around every Be tetrahedron at the distance of 1.46 Å from the Be site. The distance from the Li site to the oxygens of the Li tetrahedron is 1.84 Å. This compares favourably with the much smaller distance of 1.65 Å in the Be tetrahedron. Protons in beryl are trapped at or near these Li sites. Na⁺ is known to be located at the 2b position at the center of the silicate rings, where it is stabilized by one water molecule located at each of the two surrounding 2a sites. This is also the position of Li⁺ in the beryl channel. It is found that the presence of Na⁺ in the ring of six oxygens reduces the radius of this ring. The Na⁺ impurity has also been supposed to be located at position 2a alone and at 2b stabilized by only one water molecule. It is now proposed that Na⁺ and H₂O are located together in the Al–Be plane when only one water molecule is associated with Na⁺. The water oxygen is located at or near 2a and Na is closer to the Be site in tetrahedral beryl and closer to the Al site in octahedral beryl. It is proposed that the water protons are also located in the Al–Be plane, which would mean that there exists a third type of water in beryl. The origin of protons and OH^? ions in beryl is discussed and it is suggested that the plugs in the beryl channels are CO ₃ ^2? ions. Diffusion of OH^? ions and natural radiation may have led to the creation of NO₃ and the blue colour of Maxixe beryl.