Mineral associations and character of isotopically anomalous organic material in the Tagish Lake carbonaceous chondrite

We report a coordinated analytical study of matrix material in the Tagish Lake carbonaceous chondrite in which the same small (?20 μm) fragments were measured by secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), electron energy-loss spectroscopy (EELS), and X-ray absorption near-edge spectroscopy (XANES). SIMS analysis reveals H and N isotopic anomalies (hotspots), ranging from hundreds to thousands of nanometers in size, which are present throughout the fragments. Although the differences in spatial resolution of the SIMS techniques we have used introduce some uncertainty into the exact location of the hotspots, in general, the H and N isotopic anomalies are spatially correlated with C enrichments, suggesting an organic carrier. TEM analysis, enabled by site-specific extraction using a focused-ion-beam scanning-electron microscope, shows that the hotspots contain an amorphous component, Fe-Ni sulfides, serpentine, and mixed-cation carbonates. TEM imaging reveals that the amorphous component occurs in solid and porous forms, EDS indicates that it contains abundant C, and EELS and XANES at the C K edge reveal that it is largely aromatic. This amorphous component is probably macromolecular C, likely the carrier of the isotopic anomalies, and similar to the material extracted from bulk samples as insoluble organic matter. However, given the large sizes of some of the hotspots, the disparity in spatial resolution among the various techniques employed in our study, and the phases with which they are associated, we cannot entirely rule out that some of the isotopic anomalies are carried by inorganic material, e.g., sheet silicates. The isotopic composition of the organic matter points to an initially primitive origin, quite possibly within cold interstellar clouds or the outer reaches of the solar protoplanetary disk. The association of organic material with secondary phases, e.g., serpentine and carbonates, suggests that the organic matter was susceptible to parent-body processing, and thus, isotopic dilution.     

Stratigraphic evidence for multiple drainings of glacial Lake Missoula along the Clark Fork River, Montana, USA

Glacial Lake Missoula, a source of Channeled Scabland flood waters, inundated valleys of northwest Montana to altitudes of ∼ 1265 m and to depths of  >600 m, as evidenced by shorelines and silty lacustrine deposits. This study describes previously unrecognized catastrophic lake-drainage deposits that lie stratigraphically beneath the glacial-lake silts. The unconsolidated gravelly flood alluvium contains imbricated boulder-sized clasts, cross-stratified gravel with slip-face heights of 2-> 35 m, and 70- to 100-m-high gravel bars which all indicate a high-energy, high-volume alluvial environment. Gravel bars and high scablands were formed by catastrophic draining of one or possibly more early, high lake stands (1200-1265 m). Most glacial-lake silt, such as the Ninemile section, was deposited stratigraphically above the earlier deposits, represents a lower lake stand(s) (1050-1150 m), and was not deposited in lake(s) responsible for the highest discharge events. The glaciolacustrine silt-covered benches are incised by relict networks of valleys formed during the drainage of the last glacial lake. Significant erosion associated with the last lake draining was confined to the inner Clark Fork River canyon.     

Ferrihydrite dissolution by pyridine-2,6-bis(monothiocarboxylic acid) and hydrolysis products

Pyridine-2,6-bis(monothiocarboxylate) (pdtc), a metabolic product of microorganisms, including Pseudomonas putida and Pseudomonas stutzeri was investigated for its ability of dissolve Fe(III)(hydr)oxides at pH 7.5. Concentration dependent dissolution of ferrihydrite under anaerobic environment showed saturation of the dissolution rate at the higher concentration of pdtc. The surface controlled ferrihydrite dissolution rate was determined to be 1.2 × 10⁻⁶ mol m⁻² h⁻¹. Anaerobic dissolution of ferrihydrite by pyridine-2,6-dicarboxylic acid or dipicolinic acid (dpa), a hydrolysis product of pdtc, was investigated to study the mechanism(s) involved in the pdtc facilitated ferrihydrite dissolution. These studies suggest that pdtc dissolved ferrihydrite using a reduction step, where dpa chelates the Fe reduced by a second hydrolysis product, H₂S. Dpa facilitated dissolution of ferrihydrite showed very small increase in the Fe dissolution when the concentration of external reductant, ascorbate, was doubled, suggesting the surface dynamics being dominated by the interactions between dpa and ferrihydrite. Greater than stoichiometric amounts of Fe were mobilized during dpa dissolution of ferrihydrite assisted by ascorbate and cysteine. This is attributed to the catalytic dissolution of Fe(III)(hydr)oxides by the in situ generated Fe(II) in the presence of a complex former, dpa.     

High-Pressure crystal chemistry of spinel (MgAl2O4) and magnetite (Fe3O4): Comparisons with silicate spinels

High-pressure crystal structures and compressibilities have been determined by x-ray methods for MgAl₂O₄ spinel and its isomorph magnetite, Fe₃O₄. The measured bulk moduli, K, of spinel and magnetite (assuming K′=4) are 1.94±0.06 and 1.86±0.05 Mbar, respectively, in accord with previous ultrasonic determinations. The oxygen u parameter, the only variable atomic position coordinate in the spinel structure (Fd3m, Z=8), decreases with pressure in MgAl₂O₄, thus indicating that the magnesium tetrahedron is more compressible than the aluminum octahedron. In magnetite the u parameter is unchanged, and both tetrahedron and octahedron display the 1.9 Mbar bulk modulus characteristic of the entire crystal. This behavior contrasts with that of nickel silicate spinel (γ-Ni₂SiO₄), in which the u parameter increases with pressure because the silicon tetrahedron is relatively incompressible compared to the nickel octahedron.     

Radiocarbon Ages and Environments of Deposition of the Wono and Trego Hot Springs Tephra Layers in the Pyramid Lake Subbasin, Nevada

Uncalibrated radiocarbon data from core PLC92B taken from Wizards Cove in the Pyramid Lake subbasin indicate that the Trego Hot Springs and Wono tephra layers were deposited 23,200 ± 300 and 27,300 ± 300¹⁴C yr B.P. (uncorrected for reservoir effect). Sedimentological data from sites in the Pyramid Lake and Smoke Creek–Black Rock Desert subbasins indicate that the Trego Hot Springs tephra layer was deposited during a relatively dry period when Pyramid Lake was at or below its spill point (1177 m) to the Winnemucca Lake subbasin. The Wono tephra layer was deposited when lake depth was controlled by spill across Emerson Pass sill (1207 m) to the Smoke Creek–Black Rock Desert subbasin.¹⁸O data from core PLC92B also support the concept that the Trego Hot Springs tephra fell into a relatively shallow Pyramid Lake and that the Wono tephra fell into a deeper spilling lake.     

Integrated Interpretation of Interwell Connectivity Using Injection and Production Fluctuations

A method to characterize reservoirs, based on matching temporal fluctuations in injection and production rates, has recently been developed. The method produces two coefficients for each injector–producer pair; one parameter, λ, quantifies the connectivity and the other, τ, quantifies the fluid storage in the vicinity of the pair. Previous analyses used λ and τ separately to infer the presence of transmissibility barriers and conduits in the reservoir, but several common conditions could not be easily distinguished. This paper describes how λ and τ can be jointly interpreted to enhance inference about preferential transmissibility trends and barriers. Two different combinations are useful: one is a plot of log (λ) versus log (τ) for a producer and nearby injectors, and the second is a Lorenz-style flow capacity (F) versus storativity (C) plot. These techniques were tested against the results of a numerical simulator and applied to data from the North Buck Draw field. Using the simulated data, we find that the F–C plots and the λ–τ plots are capable of identifying whether the connectivity of an injector–producer well pair is through fractures, a high-permeability layer, multiple-layers or through partially completed wells. Analysis of data from the North Buck Draw field shows a reasonable correspondence between τ and the tracer breakthrough times. Of two possible geological models for Buck Draw, the F–C and λ–τ plots support the model that has less connectivity in the field. The wells in fluvial deposits show better communication than those wells in more estuarine-dominated regions.     

Application of statistical approaches to analyze geological,geotechnical and hydrogeological data at a fractured-rock mine site in Northern Canada

Mine site characterization often results in the acquisition of geological, geotechnical and hydrogeological data sets that are used in the mine design process but are rarely co-evaluated. For a study site in northern Canada, bivariate and multivariate (hierarchical) statistical techniques are used to evaluate empirical hydraulic conductivity estimation methods based on traditional rock mass characterisation schemes, as well as to assess the regional hydrogeological conceptual model. Bivariate techniques demonstrate that standard geotechnical measures of fracturing are poor indicators of the hydraulic potential of a rock mass at the study site. Additionally, rock-mass-permeability schemes which rely on these measures are shown to be poor predictors of hydraulic conductivity in untested areas. Multivariate techniques employing hierarchical cluster analysis of both geotechnical and geological data sets are able to identify general trends in the data. Specifically, the geological cluster analysis demonstrated spatial relationship between intrusive contacts and increased hydraulic conductivity. This suggests promise in the use of clustering methods in identifying new trends during the early stages of hydrogeological characterization.     

The geochemistry and provenance of Apollo 16 mafic glasses

The regolith of the Apollo 16 lunar landing site is composed mainly of feldspathic lithologies but mafic lithologies are also present. A large proportion of the mafic material occurs as glass. We determined the major element composition of 280 mafic glasses (>10 wt% FeO) from six different Apollo 16 soil samples. A small proportion (5%) of the glasses are of volcanic origin with picritic compositions. Most, however, are of impact origin. Approximately half of the mafic impact glasses are of basaltic composition and half are of noritic composition with high concentrations of incompatible elements. A small fraction have compositions consistent with impact mixtures of mare material and material of the feldspathic highlands. On the basis of major-element chemistry, we identified six mafic glass groups: VLT picritic glass, low-Ti basaltic glass, high-Ti basaltic glass, high-Al basaltic glass, KREEPy glass, and basaltic-andesite glass. These glass groups encompass 60% of the total mafic glasses studied. Trace-element analyses by secondary ion mass spectroscopy for representative examples of each glass group (31 total analyses) support the major-element classifications and groupings. The lack of basaltic glass in Apollo 16 ancient regolith breccias, which provide snapshots of the Apollo 16 soil just after the infall of Imbrium ejecta, leads us to infer that most (if not all) of the basaltic glass was emplaced as ejecta from small- or moderate-sized impacts into the maria surrounding the Apollo 16 site after the Imbrium impact. The high-Ti basaltic glasses likely represent a new type of basalt from Mare Tranquillitatis, whereas the low-Ti and high-Al basaltic glasses possibly represent the composition of the basalts in Mare Nectaris. Both the low-Ti and high-Al basaltic glasses are enriched in light-REEs, which hints at the presence of a KREEP-bearing source region beneath Mare Nectaris. The basaltic andesite glasses have compositions that are siliceous, ferroan, alkali-rich, and moderately titaniferous; they are unlike any previously recognized lunar lithology or glass group. Their likely provenance is within the Procellarum KREEP Terrane, but they are not found within the Apollo 16 ancient regolith breccias and therefore were likely deposited at the Apollo 16 site post-Imbrium. The basaltic-andesite glasses are the most ferroan variety of KREEP yet discovered.     

Environmental impact of salmon net-pen culture on marine benthic communities in Maine: A case study

The environmental impacts of salmon net-pen aquaculture on the benthic environment were investigated at a commercial fish farm located in coastal Maine waters. This site has a sandy mud bottom and low current velocities, is subjected to episodic sediment resuspension, and way in production for 3 yr prior to this study: We examined both the increase in carbon flux to the benthos caused by the net-pen and the effects of the elevated flux on sediment biogeochemistry and the microbenthic communities. The experimental design involved the establishment of two study sites, an ambient site ca. 100 m from the net-pen and a treatment site around the pen. Sediment traps deployed 1 m above the sediment-water interface indicated that carbon flux to the benthos was increased 1-fold to 6-fold (to a maximum of 5 g m^?2d^?1) at the edge of the net-pen with little or no increase in carbon flux 10 m from the pen. Unlike carbon flux rates, sediment organic matter inventories showed a complex pattern of change over time. Mineral surface area, organic carbon and nitrogen, digestible protein, and sterol content were initially (April 1991) lower beneath the pen than in ambient sediments. During 1991 ambient sediment accumulated organic matter until July after which it decreased, to a low during November. In contrast, organic matter inventories of sediment beneath the pen remained low until July and then increased to a high during November. These latter gains were associated with the development of bacterial mats at the sediment-water interface. Beneath the pen, microbial and macrofaunal communities were shifted toward those commonly associated with organic enrichment but seasonal trends and storm-related resuspension events also significantly affected these sediment communities. When abundant, most epibenthic organisms were more numerous near the pen than in adjacent ambient areas. These results suggest that net-pen aquaculture can alter the benthic ecosystem in Maine Coastal waters but indicate that the effects are spatially limited.