A comparison between the precession–nutation variations in right ascension referred to the CIO and the equinox

The article analyzes the precession–nutation variations in right ascension of stars after the introduction Celestial Intermediate Origin (CIO) as a new origin of the right ascensions. It points out that changes in right ascension depend not only on the motion of the origin, but also on the changes of the pole and hour circles, depending on the position of stars. This explains the apparent paradox that, for certain groups of stars, despite the almost complete elimination of the precession and nutation motion of the CIO on the equator, the magnitude of the variations in right ascension related to the CIO can exceed the magnitude of the classic variations referred to the equinox.     

Organic and inorganic geochemistry of Ljubija siderite deposits,NW Bosnia and Herzegovina

The Ljubija siderite deposits, hosted by a Carboniferous sedimentary complex within the Inner Dinarides, occur as stratabound replacement-type ore bodies in limestone blocks and as siderite–sulfides veins in shale. Three principal types of ore textures have been recognized including massive dark siderite and ankerite, siderite with zebra texture, and siderite veins. The ore and host rocks have been investigated by a combination of inorganic (major, trace, and rare earth element concentrations), organic (characterization of hydrocarbons including biomarkers), and stable isotope geochemical methods (isotope ratios of carbonates, sulfides, sulfates, kerogen, and individual hydrocarbons). New results indicate a marine origin of the host carbonates and a hydrothermal–metasomatic origin of the Fe mineralization. The differences in ore textures (e.g., massive siderite, zebra siderite) are attributed to physicochemical variations (e.g., changes in acidity, temperature, and/or salinity) of the mineralizing fluids and to the succession and intensity of replacement of host limestone. Vein siderite was formed by precipitation from hydrothermal fluids in the late stage of mineralization. The equilibrium fractionation of stable isotopes reveals higher formation temperatures for zebra siderites (around 245°C) then for siderite vein (around 185°C). Sulfur isotope ratios suggest Permian seawater or Permian evaporites as the main sulfur source. Fluid inclusion composition confirms a contribution of the Permian seawater to the mineralizing fluids and accord with a Permian mineralization age. Organic geochemistry data reflect mixing of hydrocarbons at the ore site and support the hydrothermal–metasomatic origin of the Ljubija iron deposits.     

The new helium-weak star HR 446

The CP star HR 446 (HD 9531, B8p V,m=5.69) is one of the CP stars with no definitely assigned peculiarity type. In this contribution it is shown by application of the synthetic spectra, that the star is a helium-weak type of the titanium-strontium subgroup. Photometric observations confirmed the rotational period of 0.6684 d discovered earlier. Our photometric observations do not permit to find rapid variability exceeding 0.005 mag within the limits of 5–300 min.Paper presented at the 11th European Regional Astronomical meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Determination of Gold in e‐Waste Dust Samples and Geological Matrices by ICP‐MS after Extraction by an HClO4‐HBr‐HI‐Aqua Regia Mixture

This study describes two methods (Procedures‐1 and ‐2) for the direct extraction of Au by an inorganic acid mixture (HClO₄‐HBr‐HI‐aqua regia) from complex sample matrices. Standard PTFE jars at 200 °C were used to decompose test portions of 0.5–1 g, with subsequent precise and accurate analysis by ICP‐MS without any other preconcentration or separation. Procedure‐1 decomposed samples effectively without the necessity of leaching with HF and was developed for dust samples from e‐waste (electronic waste) processing; however, testing on geological reference materials showed very good results. The analyses of replicate decompositions (n = 5) from both procedures yielded very good precision (< 5% RSD) for most of the reference materials. The accuracy achieved was better than ± 10%, with the exception of NIST SRM 2782 data from Procedure‐1. Two unknown samples of dust from e‐waste processing (P‐1 and VM‐1) exhibited elevated concentrations of Au (21.31–61.64 μg g^?1) with precision better than 10% (n = 5). The proposed techniques are simple, sensitive and sparing in the use of chemicals, and are designed for a variety of e‐waste dust samples. No significant influences were observed for the predicted spectral interferences on mass ¹⁹⁷Au.     

Determination of Trace Elements in Calcite Using Solution and Laser Ablation ICP-MS: Calibration to NIST SRM Glass and USGS MACS Carbonate, and Application to Real Landfill Calcite

We report new data on the trace element concentrations of Mg, Cr, Mn, Co, Ni, Cu, Zn, Sr, Cd, Ba, La, Ce, Nd, Pb and U in USGS carbonate reference materials (MACS-1 and MACS-2) and compare solution ICP-MS and LA-ICP-MS trace element determinations on landfill calcites using calibration to different reference materials (MACS-1 and MACS-2 carbonate and NIST SRM 612 glass). Very good agreement (differences below 10% relative) was found between laser ablation and solution ICP-MS data for MACS-1 with higher concentrations of trace elements (values between 100 and 150 μg g⁻¹), with the exception of Cu and Zn. Similarly good agreement was found for MACS-2 with lower trace element concentrations (units to tens of μg g⁻¹), with the exception of Cr, Co and Zn. The MACS-1 reference material for calibration of LA-ICP-MS was found to be extremely useful for in situ determination of trace elements in real-world carbonate samples (landfill calcites), especially those present in calcite in higher concentrations (Mn, Sr, Ba; < 5% RSD). Less accurate determinations were generally obtained for trace elements present at low concentrations (∼ units of μg g⁻¹). In addition, good agreement was observed between the instrument calibration to MACS and NIST SRM 612 glass for in situ measurements of trace elements in landfill calcites K-2, K-3 and K-4 (differences below 15% relative for most elements). Thus, the application of MACS carbonate reference materials is promising and points to the need for the development of new carbonate reference materials for laser ablation ICP-MS.     

On some aspects of the albedo effect application to the ERS-1 satellite

Some aspects of the perturbative influence of radiation reflected by the Earth's surface on the motion of an artificial satellite are discussed. We concentrate on consequences of the extreme models with anisotropic reflection on the Earth's surface (specular reflection, clouds with anisotropic phase function). The possible effects of Lála's modification of the Earth's albedo nominal value are investigated. The role of the satellite surface optical properties is pointed out in the context of the albedo effect. All mentioned models are purely numerical. The whole message of the paper can be summarized in the following items

-It is very doubtful that the 10^?8 ÷ 10^?9 m s^?2 level is reached when determining the perturbing accelerations caused by the albedo effect in the case of the ERS-1 satellite due to poorly defined optical characteristics of the Earth's atmosphere, the Earth and the satellite's surface.

-In the general case this albedo effect uncertainty level is about 50% with respect to the averaged values, and probably as high as 100% with respect to the instantaneous values of the perturbing accelerations.

     

Tests of the 2011 Tohoku earthquake source models using free-oscillation data from GOPE

Data from a superconducting gravimeter were obtained from the Geodetic Observatory Pecny (GOPE), Czech Republic, and compared with acceleration data from a broadband seismometer at the same location. We calculated synthetic seismograms for several point- and finite-source fast solutions of the 2011 Tohoku earthquake obtained from surface waves and tested them only against the observed gravity data because of high-noise levels in the low-frequency seismic data. We have obtained a good fit of the synthetic amplitude spectrum with the data up to 1.7 mHz without an additional increase of the moment magnitude M_w. In this aspect, the 2011 Tohoku earthquake was similar to the 2010 Maule earthquake and different from the 2004 Sumatra-Andaman earthquake, where the free-oscillations studies resulted in an increase of the early M_w values. The degree-one mode ₃S{ia1} dominates the ₃S_1?C2S_2?C1S₃ triplet at the GOPE station.     

Proton flares in the variation of the auroral electrojet in solar cycle no 21

Summary The effects of the solar proton flare product on ionospheric circumpolar currents (Auroral Electrojet Index) for the interval 1978–1986 (solar cycle No 21) are investigated. A significant increase of the AE two days after the zero-day of appearance of the proton flare was displayed.     

Phantom midge-based models for inferring past fish abundances

We sampled living and subfossil phantom midge (Diptera: Chaoboridae) larvae from surface sediments of 21 small lakes in Southern Sweden to examine the influence of fish and selected abiotic variables on the abundance and species composition of chaoborid assemblages. We expected total Chaoborus abundance to be inversely correlated with fish abundance and Chaoborus species most sensitive to fish predation to be found only in fishless lakes. We aimed to use the observed relationships to develop models to reconstruct past fish abundances from chaoborid remains and the abiotic environment. C. flavicans occurred in almost every lake, whereas subfossil C. obscuripes were found in the surface sediments of only one fishless lake. The density of living C. flavicans larvae correlated negatively with fish abundance, lake order and size. The concentration of C. flavicans subfossils was negatively associated with pH, lake size, water transparency and fish abundance. Regression models that included lake morphometry and landscape position as additional predictors of fish abundance performed better than models that used only Chaoborus predictors. The explained variance in fish abundance varied from 52 to 86%. Leave-one-out cross-validation indicated moderate performance of the two best models. These models explained 51 and 56% of the observed untransformed fish density and biomass, respectively. In addition, all Chaoborus models were unbiased in closely following the 1:1 reference line in plots of observed versus predicted values. These results are a promising step in developing midge-based paleolimnological reconstructions of past fish abundance, and the approach might be improved by including chironomid remains in the models.     

Motion of dust in mean motion resonances with planets

Effect of stellar electromagnetic radiation on the motion of spherical dust particle in mean motion orbital resonances with a planet is investigated. Planar circular restricted three-body problem with the Poynting–Robertson (P–R) effect yields monotonic secular evolution of eccentricity when the particle is trapped in the resonance. Planar elliptic restricted three-body problem with the P–R effect enables nonmonotonous secular evolution of eccentricity and the evolution of eccentricity is qualitatively consistent with the published results for the complicated case of interaction of electromagnetic radiation with nonspherical dust grain. Thus, it is sufficient to allow either nonzero eccentricity of the planet or nonsphericity of the grain and the orbital evolutions in the resonances are qualitatively equal for the two cases. This holds both for exterior and interior mean motion orbital resonances. Evolutions of argument of perihelion in the planar circular and elliptical restricted three-body problems are shown. Numerical integrations show that an analytic expression for the secular time derivative of the particle’s argument of perihelion does not exist, if only dependence on semimajor axis, eccentricity and argument of perihelion is admitted. Connection between the shift of perihelion and oscillations in secular eccentricity is presented for the planar elliptic restricted three-body problem with the P–R effect. Period of the oscillations corresponds to the period of one revolution of perihelion. Change of optical properties of the spherical grain with the heliocentric distance is also considered. The change of the optical properties: (i) does not have any significant influence on the secular evolution of eccentricity, (ii) causes that the shift of perihelion is mainly in the same direction/orientation as the particle motion around the Sun. The statements hold both for circular and noncircular planetary orbits.