Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons.     

94/220 GHz星载雷达双波长比对非球形冰晶云参数敏感性分析

利用不同形状冰晶的散射特性,获得了非球形冰晶云的94/220 GHz测云雷达双波长比,探讨了非球形冰晶云的双波长比与云内微物理参数的关系,分析了衰减前后的星载雷达反射率因子及双波长比的垂直廓线。结果表明:（1）双波长比可以反映小到0.1 mm中值尺度的冰粒子,对粒子总数、谱的形状参数不敏感,对粒子大小、形状、云衰减较敏感。（2）雷达灵敏度一定时,星载雷达可测云厚与雷达波长、冰含水量（IWC）的垂直分布、云厚及衰减有关;没有进行衰减订正时,双波长比和衰减有关,冰含水量越大,波长越短,衰减越大,双波长比最大值与可探测云厚有关。两部雷达可探测冰含水量为0.001—0.1 g/m3、厚2 km的冰云;当云厚5 km、冰含水量垂直分布在0.001—0.2 g/m3时,云厚的94%基本可以被220 GHz云雷达探测到。（3）如果两部雷达气象方程中用水的介电因子,测量回波强度应进行介电因子的订正后再计算双波长比。      

The coastal transition at the mouth of a small mountainous river in Taiwan

The Tseng-wen River is a small mountainous river in southern Taiwan that has distinct dry and flood seasons. Several lines of evidence have revealed that the depositional system at the mouth of the river has transformed from a deltaic system to an estuarine system. The evidence includes long to short-term shoreline changes, geomorphology of the river mouth, mixed sediment sources inside the river mouth, mixing and suspended sediment characteristics inside the river mouth, and the grain-size distribution patterns on the river bed. Unlike the long-term evolution of many other coastal systems, the transformation at the Tseng-wen River mouth is largely caused by the building of a reservoir in the middle reaches of the river. The present study provides an example that coastal environments can be influenced by human activities farther inland on a time scale much faster than what would occur naturally.     

序贯高斯模拟在矿石品位估计中的应用研究

随机模拟是地质统计方法的重要内容。在矿石品位估计方法中克里格方法作为一种无偏估计方法,常被用于矿石品位的估计。但克里格法估值存在平滑效应。作者在分析序贯高斯模拟和普通克里格法基本原理的基础上,运用序贯高斯模拟方法和普通克里格方法对某铁矿体内全铁(TFe)品位进行估计,给出了品位估计结果模型。研究从勘探线方向、垂直勘探线方向和竖直方向分别计算变差函数,对球状模型、指数模型、高斯模型的变差函数拟合效果进行了优选,结果表明球型模型拟合效果最好。针对序贯模拟和克里格品位估值效果进行了分析,结果显示:序贯高斯模拟结果在品位分布形态上更接近样品品位分布形态,其平滑效应更小;克里格方法估计与序贯高斯模拟方法相比仅在品位均值方面更接近样本品位均值。因此,认为序贯高斯模拟方法可以更好地刻画矿体内品位分布状态。     

长江口邻近海域溶解态铝的分布及季节变化

基于2006年6、8、10月对长江口邻近海域的大面调查资料,分析了溶解态Al的分布及季节变化,讨论了水团混合、悬浮颗粒物及浮游植物水华对溶解态铝分布的影响。结果表明,3个航次溶解态铝的水平分布规律相似,都是近岸浓度最高,随着离岸距离的增加浓度降低,6、8、10月溶解态Al的平均浓度分别为(119±77)、(109±80)和(138±73)nmol/L,统计结果表明该海域的溶解态铝具有明显的季节变化。影响溶解态铝分布的主要因素有水团混合、底沉积物的再悬浮以及浮游植物的调节作用。     

绿藻水溶性多糖的研究概况和进展

对近年来绿藻多糖的提纯方法、组成结构及应用的研究进展进行了综述。绿藻多糖的提纯需要经过样品的前处理、提取和精制三个步骤,提取方法包括酸提、酶提、加入钙螯合剂提取、微波及超声波辅助提取。绿藻多糖是水溶性的硫酸化杂多糖。从石莼(Ulva)、浒苔(Enteromorpha)、礁膜(Monostroma)、小球藻(Chlorella)、蕨菜(Bracken)及刚毛藻(Bristles)中提取的多糖的化学组成及结构特征各不相同,而且多糖的化学组成和结构特征受提取方式的影响。绿藻多糖的生物相容性、生物可降解性及抗氧化、抗肿瘤、抗凝血、抗炎、免疫调节等多种生物活性使其在食品、医药、化妆品及农业中具有广泛的应用。有关绿藻多糖的精确结构、提纯方法及化学修饰的进一步研究将使绿藻多糖的应用更加广泛。     

GPS卫星轨道精度对定位结果的影响

卫星轨道误差是影响定位精度的重要误差源,在轨道精度、表示方式和实时性等方面对广播星历、超快速星历、快速星历和精密星历进行了比较分析,得出广播星历与精密星历所提供的卫星轨道相差较大,超快速星历居中,快速星历轨道与精密轨道接近,在测量设备的高精度比对鉴定中,满足不同试验需求对卫星星历的选择提供了依据。     

1961 - 2017年中国东北地区降雪时空演变特征分析

利用东北地区162个气象台站逐日降水量和天气现象数据, 采用统计分析方法, 对近57年（1961 - 2017年）降雪的气候特征和时空演变规律进行了分析。结果表明： 降雪量和降雪日数最多出现在12月, 小雪和中雪最多出现在11月或12月, 大雪和暴雪在冬末春初出现概率最高。降雪分布为山地大于平原, 平原地区自北向南、 自东向西减少, 降雪高值区主要位于大兴安岭北部、 小兴安岭和长白山区, 降雪强度中心位于长白山区和辽宁中部平原地区。年、 秋季、 冬季、 春季降雪量占同期降水量比例分别为4.7%、 7.0%、 84.4%和7.6%; 辽宁省西部山区和南部大连地区日最大降雪量占年总降雪量比例最高, 最长连续降雪日数在2 d以下, 降雪较高纬度地区更为集中。近57年降雪量和降雪强度分别以1.93 mm?（10a）^-1和0.11 mm?d^-1?（10a）^-1的速率显著增加, 降雪日数以2.08 d?（10a）^-1速率显著减少; 降雪量增加主要表现为各等级降雪量的增加, 降雪日数减少主要是微量和小雪日数的减少, 降雪强度增加主要为大雪和暴雪降雪强度的增加。年、 秋季和冬季降雪量占同期降水量比例平均每10年增加0.36%、 0.48%和0.45%, 春季以0.11%?（10a）^-1的速率减少。中雪、 大雪和暴雪对降雪贡献率均呈增加趋势, 小雪降雪量和微量降雪日数贡献率减少; 1987年降雪量和降雪日数突变后, 微量降雪日数和暴雪日数、 小雪降雪量贡献率改变显著。就区域平均而言, 2001 - 2017年的降雪量较1961 - 1980年增加了27.8%, 降雪日数减少了22.4%。     

宜宾市宋家地区土壤元素背景值研究及其意义

作者在表层土壤系统采样调查的基础上,计算出宋家地区土壤元素地球化学背景值,并通过与不同区域土壤元素地球化学背景值、基准值的对比研究,总结了该区土壤元素地球化学基本特征,为该区土壤资源、环境评价和农业经济发展规划提供了实用地球化学信息。     

一种高分辨率遥感影像处理方法及其在电力工程中的应用

随着地球空间信息科学技术的飞速发展,高分辨率卫星遥感技术逐渐成为主流的对地观测手段之一。其生产的高分辨率遥感影像具有数据获取迅速、成本低、不受地域限制等诸多优点,广泛应用于国土、石油、电力、林业等行业部门。但由于其出现年代较新、数据量庞大、分辨率高,高分辨率遥感影像的数据处理与应用尚无完整的理论和方案指导,导致其在电力等行业的应用长期处于探索阶段。本文针对高分辨率遥感影像的关键处理难点,结合电力工程实际需求,提出了一整套数据处理及应用方案,为高分辨率遥感影像数据处理及其电力工程应用提供了技术支持和实践经验。