Selenium concentration in food and blood of residents of Abeokuta Metropolis,Southwestern Nigeria

Selenium like any other element can both be essential and toxic depending upon the concentration at which it occurs in human diet. This paper assessed the level of this trace element in twenty different (20) types of locally produced food items around Abeokuta town and the blood obtained from the antecubital fossa vein of eighty-eight (88) healthy adults resident in Abeokuta.     

High-Resolution Non-Hydrostatic Simulations of Flash-Flood Episodes with Grid-Nesting and Ice-Phase Parameterization

Summary ?Simulations of two heavy rainfall events south of the Alps have been conducted with a non-hydrostatic model at horizontal resolutions ranging from 40 to 2.5 km. Emphasis is placed on the assessment of two recent model developments: a detailed explicit mixed phase microphysical scheme and a two-way interactive grid nesting method. In the high-resolution simulations, the impact of the ice phase was found to be quite substantial, accelerating the propagation of the surface front and modifying the spatial distribution of the rainfall. Simulations carried out with two-way interactive grid nesting yielded more realistic overall precipitation patterns, particularly at the finest horizontal resolution. Received March 22, 1999/Revised June 28, 1999     

Thermodynamics of minerals of variable composition: Andradite-grossularite and pistacite-clinozoisite solid solutions

Exchange-mineral equilibria with Al and Fe³⁺ aqueous chloride solutions (aq.), Andr + AlCl _aq ³ = FeCl _aq ³ + Gros, (1) Psc + AlCl _aq ³ = FeCl _aq ³ + Czo, (2) were studied under the following experimental conditions: 500°;C and 580°;C and 1 and 2 kbar, respectively, with an overall concentration of metals in the aqueous solutions of about 0.5 M and pH 3. The mixing functions of the components in garnet and epidote were calculated from the experimental data. Thermodynamic treatment of experimental evidence for reaction (1) led to the conclusion that, within the accuracy of experiment, garnet in the andradite-grossularite series was an ideal solid solution. However, epidote solid solution markedly departed from the ideal, as was shown by concentration and pressure-temperature (PT) dependencies of Gibbs's molar excess energies and by mixing-volume concentration dependence.     

Developing a large‐scale water‐balance approach to seasonal forecasting: application to the 2012 drought in Britain

Seasonal hydrological forecasts, or outlooks, can potentially provide water managers with estimates of river flows and water resources for a lead time of several months ahead. An experimental modelling tool for national hydrological outlooks has been developed which combines a hydrological model estimate of sub‐surface water storage across Britain with a range of seasonal rainfall forecasts to provide estimates of area‐wide hydrological conditions up to a few months ahead. The link is made between a deficit in sub‐surface water storage and a requirement for additional rainfall over subsequent months to enable sub‐surface water storage and river flow to return to mean monthly values. The new scheme is assessed over a recent period which includes the termination of the drought that affected much of Britain in the first few months of 2012. An illustration is provided of its use to obtain return‐period estimates of the ‘rainfall required’ to ease drought conditions; these are well in excess of 200 years for several regions of the country, for termination within a month of 1 April 2012, and still exceed 40 years for termination within three months. National maps of sub‐surface water storage anomaly show for the first time the current spatial variability of drought severity. They can also be used to provide an indication of how a drought situation might develop in the next few months given a range of possible future rainfall scenarios. © 2013 CEH/Crown and John Wiley & Sons, Ltd.     

Frost risk mapping for landscape planning: A methodology

Summary Minimum air temperatures were measured during three winters with a network of stations in open, undulating terrain. It was observed that the change in minimum air temperature with elevation could be predicted from mean nighttime windspeed, total nighttime net radiation loss and a hill-top reference minimum temperature. It was also found that the deviation of temperatures at individual sites could be predicted from a local terrain parameter which reflects the extent of cold air accumulations. Thus a methodology for frost risk mapping has been developed which is based on regional weather dataand local terrain analysis. This paper describes the model and illustrates the regional weather and terrain effects with three-dimensional block diagrams.With 8 Figures     

Magnetic Anisotropy as an Aid to Identifying CRM and DRM in Red Sedimentary Rocks

To further evaluate the potential of magnetic anisotropy techniques for determining the origin of the natural remanent magnetization (NRM) in sedimentary rocks, several new remanence anisotropy measurement techniques were explored. An accurate separation of the remanence anisotropy of magnetite and hematite in the same sedimentary rock sample was the goal.In one technique, Tertiary red and grey sedimentary rock samples from the Orera section (Spain) were exposed to 13 T fields in 9 different orientations. In each orientation, alternating field (af) demagnetization was used to separate the magnetite and hematite contributions of the high field isothermal remanent magnetization (IRM). Tensor subtraction was used to calculate the magnetite and hematite anisotropy tensors. Geologically interpretable fabrics did not result, probably because of the presence of goethite which contributes to the IRM. In the second technique, also applied to samples from Orera, an anisotropy of anhysteretic remanence (AAR) was applied in af fields up to 240 mT to directly measure the fabric of the magnetite in the sample. IRMs applied in 2 T fields followed by 240 mT af demagnetization, and thermal demagnetization at 90°C to remove the goethite contribution, were used to independently measure the hematite fabric in the same samples. This approach gave geologically interpretable results with minimum principal axes perpendicular to bedding, suggesting that the hematite and magnetite grains in the Orera samples both carry a depositional remanent magnetization (DRM). In a third experiment, IRMs applied in 13 T fields were used to measure the magnetic fabric of samples from the Dome de Barrot area (France). These samples had been demonstrated to have hematite as their only magnetic mineral. The fabrics that resulted were geologically interpretable, showing a strong NW-SE horizontal lineation consistent with AMS fabrics measured in the same samples. These fabrics suggest that the rock's remanence may have been affected by strain and could have originated as a DRM or a CRM.Our work shows that it is important to account for the presence of goethite when using high field IRMs to measure the remanence anisotropy of hematite-bearing sedimentary rocks. It also shows that very high magnetic fields (>10 T) may be used to measure the magnetic fabric of sedimentary rocks with highly coercive magnetic minerals without complete demagnetization between each position, provided that the field magnetically saturates the rock.     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

Relationships between marginal thrusting and movement on major,internal shear zones in the Northern Highland Caledonides,Scotland

The development of the syn-metamorphic Sgurr Beag slide zone, a major ductile shear zone of initially low dip, caused at least 50 km north-western thrust displacement of part of the internal metamorphic complex of the Northern Highland Caledonides of Scotland. Initiation of the zone, and movements upon it, were earlier than formation of the marginal Moine Thrust zone. Movement on the zone followed but overlapped the peak Caledonian metamorphism and the mid to high amphibolite facies mineral assemblages, fabrics and structures produced during the development of the slide zone and those surviving from earlier events, were reworked under greenschist facies conditions during mylonitization associated with initiation of the Moine Thrust zone. Displacements on the slide zone and thrust movements were separated by emplacement of a regional suite of pegmatites and a considerable change of metamorphic grade. Thus, they may not constitute members of a progressive sequence of Caledonian thrusts formed over a short time interval. Rather, preliminary isotopic data may imply an interval of c. 25 Ma between movement on the slide zone and final, ductile translation along the Moine Thrust zone.