Iodine differentiation between different sized fractions in natural waters

Membrane filtration technique was applied to study the distribution of iodine and some other chemical elements (iron, manganese, aluminum, and silicon) in natural waters between different sized fractions (>0.45, 0.45–0.22, 0.22–0.1, and <0.1 μm). The paper presents analysis of factors able to modify the proportions of the adsorbed and dissolved species of the elements in waters. It is proved that up to 90% of the total amount of the iodine ion occurs in aquatic environments in the form of dissolved species (according to the current standard, in the fraction < 0.45 μm), with approximately 49% of the total concentration corresponding to the fraction of <0.10 μm. An increase in the acidity of the waters and their enrichment in finely divided organic and mineral material, and also an increase in Fe and Mn concentrations, may increase in the concentrations of the trace element in the particulate matter (up to 26% of the total iodide concentration). The greatest variations in iodine distribution between different fractions are found in the surface waters.     

New field and laboratory evidence for the origin of hyaloclastite flows on seamount summits

New field observations with the submersible ALVIN and photographic evidence from a study of the summits of seamounts near the East Pacific Rise show that hyaloclastite deposits occur commonly. Hyaloclastite outcrops were found on six volcanoes at depths from 1240 to 2500 m. These new observations plus laboratory study of new hyaloclastite specimens extend the results of previous studies. Most of the hyaloclastite samples are of hydrovolcanic eruptive origin, but a few show evidence of a predominantly sedimentary origin. Primarily from morphology, we identify several vent areas from which hyaloclastite presumably erupted. The surface appearance of the hyaloclastite deposits varies with distance to these vents, leading us to propose a facies model for deep-sea hyaloclastites on seamount summits. Hyaloclastites of hydromagmatic origin exhibit weak normal grading and bedding-parallel alignment of platy shards. They consist of blocky, sliver and fluidal basalt glass shards and lithics in a matrix that contains pelagic sediment. The shards themselves are remarkably free of even the tiniest crystals and are usually chemically homogeneous. We propose that the shards form mainly by cooling-contraction granulation, but cannot rule out the possibility of limited steam explosivity. Hyaloclastites are closely associated with submarine pahoehoe and we propose that a very rapid eruption rate, promoting clastic-dominated versus flow-dominated eruptive behavior, is the dominant control on hyaloclastite formation. We propose that shard formation occurs during submarine lava fountaining. Gravitational instability of the resulting slurry of shards, sea water and possibly steam causes gravity flow that carries the shards outward from the vent. Further field and modelling studies are needed to test these ideas and more quantitatively constrain the ascent mechanism, eruption dynamics and deposition of deep-sea hyaloclastites.     

Conditional statistics of vertical heat fluxes in local advection conditions

Turbulent fluctuations have been investigated in the internal boundary layer (IBL) which forms after a dry-to-wet surface transition. The IBL is defined as that part of the atmospheric surface layer where the influence of the downstream surface is noticeable. The results of the application of three different quadrant analysis techniques are presented. The three techniques, in increasing order of the amount of information supplied, provide:

1. the diurnal variation of quadrant contribution (C _i), number fraction (T _i) and conditional average (% MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% GaeyykJeUabm4DayaafaGabm4CayaafaGaeyOkJe-aaSbaaSqaaiaa% dMgaaeqaaaaa!4215!\[\langle w's'\rangle _i \], with s = T or q) of vertical sensible and latent heat fluxes,
2. the quadrant contribution and number of samples of different sizes depending on the relative magnitude of each sample, and
3. the distribution of the nondimensional probability density function.

The results show that in the IBL the vertical flux of sensible heat is maintained by (i) a small fraction of large samples with warm air carried upwards, and (ii) a larger fraction of small samples with cool air carried downwards. Both processes are almost equal in importance. In the morning and near the top of the IBL negative temperature fluctuations are limited by the near-uniform temperature conditions upstream and above the IBL. This limitation reduces, at that location, the conditional average of the sinking motions of cool air. Closer to the wet surface the negative temperature fluctuations are less susceptible to the above mentioned limitation. As a consequence contributions from all four quadrants are almost equal leading to a very small vertical heat flux. In the presence of a temperature inversion over both the upstream and the downstream terrain, shear-generated turbulence appears to be the cause of the relative abundance of sinking motions of warm air and rising motions of cool air, leading to a reversal of the sensible heat flux. The latent heat flux is positive (i.e. directed away from the surface) at all times and is maintained in almost equal amount by (i) a small number of large magnitude samples with moist air carried upwards, and (ii) small magnitude samples with sinking motions of dry air. These sinking motions of dry air are far more numerous, especially in the morning, but their conditional average is very small. The abundance of sinking motions of dry air is attributed to the fact that over the downstream terrain evaporation is greatly enhanced, leading to a skewed w′q′ signal. This skewness is clearly visible in the w′q′-probability density distribution of the morning runs. In the evening the asymmetry between these two different contributions disappears. This is because evaporation is greatly reduced and large positive humidity fluctuations no longer occur.     

The use of7LiOH-impregnated filters for the collection of acidic gases and analysis by instrumental neutron activation analysis

A simple system was designed using⁷LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M⁷LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO₂ and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO₂ may not be collected quantitatively since SO₂ is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected.     

Weissbergite (TlSbS2) and Avicennite (Tl2O3), Rare Thallium Minerals: First Findings in Yakutia

Geology of Ore Deposits - Rare thallium minerals, avicennite and weissbergite, were found for the first time within the karst zones of the Khokhoy field of the Verkhnyaya Amga gold area, South...