Reversing Water Exchange Patterns at the Entrance to a Semiarid Coastal Lagoon

Water velocity and density profiles were obtained in late-spring and late-winter to document reversing mean circulation patterns at the entrance to a semiarid coastal lagoon, the Bay of Guaymas, in the Gulf of California, Mexico. The lagoon is shallow but the bathymetry at its entrance is similar to that of temperate estuaries with an asymmetrically positioned channel flanked by shoals. In late-spring the mean circulation at the entrance to the lagoon was driven by horizontal density gradients that arose from excess evaporation over precipitation in the area as evidenced by water density profiles. The lagoon exported relatively warm (25·8 °C) and salty (36·2) water to the Gulf of California through the channel. This export was consistent with inverse estuarine circulation influenced by bathymetry. In late-winter, the circulation at the entrance of the lagoon was mostly driven by wind stress that blew from the northwest, roughly along the main axis of the lagoon. Relatively cool (16·0) °C) and less salty (35·1) water from the Gulf of California was driven into the lagoon within the channel. Density gradients inside the lagoon seem to have played a secondary role in driving the circulation. The late-winter circulation was then estuarine-like, with outflow in the direction of the wind over the shallow areas and a compensatory inflow appearing in the channel as expected from theory of wind-driven flow over bathymetry. This estuarine-like circulation developed despite the lack of measurable freshwater input to the lagoon and was the opposite to that observed in late-spring. These observations then document a reversal in water exchange patterns from season to season in a semiarid coastal lagoon. The observations also constitute one of the few reported examples of flow over shoals driven in the same direction as the wind stress with a compensatory flow in the channel.     

Effects of pulp bleach plant effluents on hepatic xenobiotic biotransformation enzymes in fish: Laboratory and field studies

The present preliminary report on studies of the influence of pulp bleach plant effluents on hepatic biotransformation enzymes in fish is a part of a major characterisation of biochemical and physiological effects of effluents from pulp industries in Sweden. Our studies on the xenobiotic biotransformation enzymes demonstrate, so far, that the pulp effluents have the potential to strongly induce 7-ethoxyresorufin-O-deethylase activity (EROD) in fish liver and that fish living in the receiving water of an effluent from a pulp bleach plant have induced hepatic EROD activities as well as higher hepatic UDP glucuronyltransferase activities than those living in an unpolluted area. It is thus apparent that measures of induction of biotransformation enzymes in fish liver may be a useful approach in monitoring the presence of potential hazardous compounds released from pulp industries.     

Freezing as a method of sample preservation for the analysis of dissolved inorganic nutrients in seawater

It is often desirable or necessary to store collected seawater samples prior to analysis for dissolved inorganic nutrients. It is therefore important to establish preservation and storage techniques that will ensure sample integrity and will not alter the precision or accuracy of analysis. We have performed a series of experiments on the storage of nutrient samples collected at the oligotrophic North Pacific benchmark Station ALOHA, using both standard autoanalyses and low-level techniques. Our results reveal that for oligotrophic oceanic waters, the immediate freezing of an unfiltered water sample in a clean polyethylene bottle is a suitable preservation method. This procedure is simple, it avoids potentially contaminating sample manipulations and chemical additions, and it adequately preserves the concentrations of nitrate + nitrite, soluble reactive phosphate, and soluble reactive silicate within a single water sample.     

Prolonged Magmatic and Tectonic Development of the Caribbean Igneous Province Revealed by a Diving Submersible Survey

Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by ⁴⁰Ar/³⁹Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces.     

Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Application of cluster analysis to study the relationship between the fine stratification and the background hydrological conditions in the ocean

Cluster analysis is discussed in the context of its application to map various test areas in the sea. By analysing the correspondence of the identified categories to areas with specific hydrological conditions, an attempt is made to relate the types of fine structure to diverse background conditions. With two test areas mapped, a conclusion is made as to the possible application of cluster analysis to this end.Translated by Vladimir A. Puchkin.     

Evaluation of drift current parameters using an analytical model

The paper is concerned with the evaluation of the drift current parameters derived through the use of an analytical model. In this model, effective when stratification is stable and indifferent, the vertical turbulence coefficient profile is prescribed by the power function, and hydrodynamic quantities are prescribed using the external parameters of the problem (wind stress, the Coriolis parameter, and the dimensionless stratification parameter). Model data are compared with the observations of the upper mixed layer in the vicinity of the oceanic Station C, conducted during one year. It is shown that, under the spring-summer-time warming conditions, the model at issue is capable of adequately simulating the upper ocean layer dynamics. Translated by Vladimir A. Puchkin.