Sand ridges on the inner Atlantic shelf of North America: Morphometric comparisons with Huthnance stability model

Sand ridge fields on the inner shelf of the Middle Atlantic Bight are generally thought to have formed in response to northeasterly storm flows as the shoreface underwent erosional retreat with postglacial sea-level rise. However, the hydrodynamic mechanism is poorly unerstood. Coastal boundary models see the ridges as responses of the seafloor to distortions in the flow induced by the coastal boundary. Stability models propose that an irregular initial topography will evolve toward an ordered array of bedforms in response to repeated flow events. The two classes of models are not mutually exclusive, nor are members within each class mutually exclusive. Results of measurements of ridge spacing on the inner Atlantic shelf of North America agree with the predictions of stability models.     

Radium and lead-210 in marine barite

Measurements of ²²⁶Ra and ²¹⁰Pb in barite samples separated from different depths of a piston core from the eastern equatorial Pacific are reported. ²²⁶Ra is enriched in the barite as would be expected from the chemistries of Ra and Ba; the ${}^{226}\text{Ra}\text{Ba}$ ratio centers around 1.5 · 10¹⁴ atoms/mole. The results suggest that barite is concentrating Ra at a rate comparable to its decay rate, viz. 5.78 · 10^?3 yr^?1. The gross ²¹⁰Pb depletion with respect to ²²⁶Ra is indicative of ²²²Rn loss due to the smallness of the barite crystals.     

Water colour index of the Guinean sector of the Atlantic Ocean

The distribution of the colour index is considered in the region bounded by 8–11°N and 13°30–18°30W based on the results of measurements made on board vessels of the Marine Hydrophysical Institute of the Ukrainian SSR Academy of Sciences (MHI) in 1977–1985. Mean values and statistical characteristics are calculated for the colour index variability over one-degree squares. A map of its multi-yearly average distribution is plotted.Translated by M. M. Trufanov.     

Grain-size distribution of quartz and feldspar extracts and implications for flocculation processes

Quartz and feldspar extracts, obtained by chemical dissolution of the clay minerals, provide insight into the inorganic flocculation and mineralogical influences upon the texture of fine-grained glaciomarine deposits. Glacial comminution in higher latitudes explains the relatively high contents of quartz and feldspars. Quartz and feldspar are better sorted and were apparently less influenced by flocculation than were phyllosilicates, except for particles less than approximately 16 μm, which are poorly sorted due to their inclusion in flocs. The 16-μm boundary is suggested to be useful for approximately separating fines that are usually involved in flocculation and coarse silt and larger grains that are less influenced.     

Four-dimensional analysis of the variability of hydrophysical fields in the tropical atlantic and on the shelf of guinea

The problem of monitoring of the mesoscale variability of hydrophysical fields in the shelf zone is considered. The usefulness of the data available in regional information centres is discussed. The possibility of monitoring the dynamics of the oceanic fields in the tropical Atlantic encompassing separate observation sites is demonstrated using the oceanographic databank of the scientific research centre (CERESCOR) in Conakry-Rogbane as an example. The results of assimilation of the hydrophysical survey data derived on the shelf in a telescopic model of the region are given.Translated by Mikhail M. Trufanov.     

Three Kings Ridge: a west-facing arc

The Three Kings Ridge has been described as a remnant arc or an east-facing arc on the western side of the South Fiji Basin under which symmetric South Fiji Basin magnetic anomaly lineations have been lost. We find evidence of neither arc-trench morphology on the eastern flank of the ridge nor collision tectonism within the adjacent South Fiji Basin that might have obliterated it. We believe there is room for the missing magnetic lineations within the South Fiji Basin and we recognize the distinctive island-arc morphology characteristic of a west-facing arc on the western flank of the Three Kings Ridge. Our interpretation requires that arc volcanism postdated formation of much of the South Fiji Basin and that oceanic lithosphere from the adjacent Norfolk Basin must have been subducted beneath the west-facing Three Kings Arc.     

Mineralogical and geochemical features of authigenic carbonates on seepings and hydrothermal fields (By the examples of the Black Sea reefs and the mounds of the lost city field)

Two genetically different types of authigenic carbonate mounds are studied: those within an active hydrothermal field related to serpentinite protrusions in the zone of intersection of a transform fracture zone and the Mid-Atlantic Ridge, and those in an active field of methane seepings in the Dnieper canyon of the Black sea. The general geochemical conditions under which authigenic carbonate formation occurs in the two fields considered were found. They include the presence of reduced H₂S, H₂, and CH₄ gases at the absence of free oxygen; the high alkalinity of the waters participating in the carbonate formation; the similarity of the textural and structural features of authigenic aragonite, which represents the initial mineral of the carbonate matter of the mounds; the paragenesis of aragonite with sulfide minerals; and the close relation of carbonate mounds with communities of sulfate-reducing and methane-oxidizing microorganisms. A new mechanism of formation of hydrothermal authigenic carbonates is suggested; it implies their microbial sulfate reduction over the hydrogen of the fluid in the subsurface zone (biosphere) of mixing between the hydrothermal solution and the adjacent seawater.     

Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.