Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.     

Corundum-group minerals in rocks of the Khibiny alkaline pluton,Kola Peninsula

Five minerals of the corundum group have been identified in the Khibiny pluton with certainty. Corundum proper and karelianite occur only in hornfels after volcanic and sedimentary rocks. Xenoliths of hornfels mark the ring faults that bound foidalite within the field of foyaite. Hematite occurs in hydrothermally altered nepheline syenite and crosscutting hydrothermal veins related to the ring faults. Minerals of the ilmenite-pyrophanite series are present in all rocks of the pluton, including veins. Accessory ilmenite in foyaite varies from the manganese variety and pyrophanite in the inner and outer parts of the pluton to manganese-free ilmenite in zone of the Main Ring Fault. In xenoliths of volcanic rocks and alkaline ultramafic rocks, ilmenite is enriched in magnesium. The zoning in distribution of the above-mentioned minerals and the character of variation in their compositions from margins of the pluton to its center are consistent with the petrochemical zoning formed as a result of foyaite alteration of near ring faults.     

The role of granites in volcanic-hosted massive sulphide ore-forming systems: an assessment of magmatic�Chydrothermal contributions

Assessment of geological, geochemical and isotopic data indicates that a significant subgroup of volcanic-hosted massive sulphide (VHMS) deposits has a major or dominant magmatic?Chydrothermal source of ore fluids and metals. This group, which is typically characterised by high Cu and Au grades, includes deposits such as those in the Neoarchean Doyon-Bousquet-LaRonde and Cambrian Mount Lyell districts. These deposits are distinguished by aluminous advanced argillic alteration assemblages or metamorphosed equivalents intimately associated with ore zones. In many of these deposits, ??³⁴S_sulphide is low, with a major population below ?3??; ??³⁴S_sulphate differs from coexisting seawater and ??³⁴S_{sulphate?Csulphide}????20?C30??. These characteristics are interpreted as the consequence of disproportionation of magmatic SO₂ as magmatic?Chydrothermal fluids ascended and cooled and as a definitive evidence for a significant magmatic?Chydrothermal contribution. Other characteristics that we consider diagnostic of significant magmatic?Chydrothermal input into VHMS ore fluids include uniformly high (>3 times modern seawater values) salinities or very ¹⁸O-enriched (??¹⁸O?>?5??) ore fluids. We do not consider other criteria [e.g. variable salinity, moderately high ??¹⁸O_fluid (2?C5??), ??³⁴S_sulphide near 0??, metal assemblages or a spatial association with porphyry Cu or other clearly magmatic-hydrothermal deposits] that have been used previously to advocate significant magmatic?Chydrothermal contributions to be diagnostic as they can be produced by non-magmatic processes known to occur in VHMS mineral systems. However, in general, a small magmatic?Chydrothermal contribution cannot be excluded in most VHMS systems considered. Conclusive data that imply minimal magmatic?Chydrothermal contributions are only available in the Paleoarchean Panorama district where coeval seawater-dominated and magmatic?Chydrothermal systems appear to have been physically separated. This district, which is characterised by chloritic and sericitic alteration assemblages and lacks aluminous advanced argillic alteration assemblages, is typical of many VHMS deposits around the world, suggesting that for ??garden variety?? VHMS deposits, a significant magmatic?Chydrothermal contribution is not required. Other than deposits associated with advanced argillic alteration assemblages, the only deposit for which we ascribe a major magmatic?Chydrothermal contribution is the Devonian Neves Corvo deposit. This deposit differs from other deposits in the Iberian Pyrite Belt and around the world in being extremely Sn-rich, with the Sn closely associated with Cu and in having formed from high ¹⁸O-rich fluids (??¹⁸O_fluid ??8.5??). We consider these characteristics, particularly the last, as diagnostic of a significant magmatic hydrothermal contribution. Our analysis indicates that two subgroups of VHMS deposits have a major magmatic?Chydrothermal contribution: Cu/Au-rich deposits with aluminous alteration assemblages and reduced, very Sn-rich deposits in which Sn was introduced in a high-temperature ore assemblage. Comparison with ??normal?? VHMS deposits suggests that these subgroups of VHMS deposits may form in specialised tectonic environments. The Cu/Au-rich deposits appear to form adjacent to magmatic arcs, an environment conducive to the generation of hydrous, oxidised melts by melting metasomatised mantle in the wedge above the subducting slab. This contrasts with the back-arc setting of ??normal?? VHMS deposits in which relatively dry granites (In this contribution, we use the term granite sensu latto) formed by decompression melting drive seawater-dominated hydrothermal circulation. The tectonic setting of highly Sn-rich VHMS deposits such as Neves Corvo is less clear; however, thick continental crust below the ore-hosting basin may be critical, as it is in other Sn deposits.     

Contemporary methods for retrieving the integrated atmospheric water-vapor content and the total cloud liquid-water content

A review of contemporary methods for determining integrated parameters of the water content in the atmosphere―atmospheric water-vapor content and cloud liquid-water content―is presented. Fields of these parameters can only be mapped spatially on the basis of using data of satellite measurements. The least errors of the retrieval of atmospheric water-vapor content and cloud liquid-water content is provided by methods based on using measurements of the satellite-borne scanning multichannel microwave radiometers over the ice-free ocean areas in the absence of precipitation. Most methods for retrieving the atmospheric water-vapor content and cloud liquid-water content from the data of microwave radiometers are based on results of numerical simulation of brightness temperatures of the upwelling microwave radiation of the ocean–atmosphere system. The evolution of satellite-borne microwave radiometers and methods for the retrieval of integrated parameters of water content is presented.     

Shear sense inversion in the Hilti mantle section (Oman ophiolite) and active mantle uprise

Structural analyses in the well-exposed Hilti mantle section in the Oman ophiolite suggest a model of forceful horizontal flow in the uppermost mantle at the edge of a diapir below a oceanic spreading center. Detailed structural mapping, focussed on high-T deformation (i.e., asthenospheric flow), revealed a gently undulated flat structure with a uniform east-west flow direction. When it is related to the N–S to NNW–SSE trending, vertical sheeted dike complex located to the east, this mantle flow is parallel to the spreading direction. Because the Moho is so flat lying, a large dunite occurrence at the south-western region is possibly ascribed to the Moho Transition Zone. Kinematic analysis shows that the shear direction generally changes from top-to-the west in the upper level, to top-to-the east in the lower level with respect to the Moho. This shear sense inversion is explained by a model of forceful flow due to an active mantle uprise and it is not compatible with a passive mantle uprise. In the plan section, the boundary of the shear sense inversion is subparallel to the flow direction and subperpendicular to the spreading axis. In cross section, the boundary appears to occur at various depths in the range of 200 m to 500 m. It shows that the active mantle uprise in the diapir center resulted in a channelled horizontal flow.     

Offshore sand sources for beach replenishment: Potential borrows on the continental shelf of the Eastern Gulf of Mexico

Erosion of sandy beaches is a worldwide problem that elicits innovative geoengineer‐ing techniques to reduce adverse impacts of shoreline retreat. Beach replenishment has emerged as the “soft”; shore‐stabilization technique of choice for mitigating beach erosion. This method of shore protection involves the addition of sand to the littoral sediment budget for sacrificial purposes. Because inland sand sources are often uneconomical or impractical to use, and known nearshore sources are limited, finding adequate quantities of suitable sand on the inner continental shelf is often vital to beach replenishment projects. The technical studies of survey and materials analysis that identify and delineate usable sand sources are sometimes almost as expensive as small‐project dredging, pumping, and placing the sand on the beach as fill. Inadequate quantity or substandard quality of shelf sand, as well as often‐prohibitive overhead expenses, thus compel shoreline managers to seek suitable sand sources offshore.

In the study area off the central‐west coast of Florida, offshore potential borrow areas (PBAs) were identified on the basis of studies conducted in reconnoitory and detailed phases. Sophisticated state‐of‐the‐art equipment used in this investigation provided more detailed subbottom mapping information than is normally obtained with conventional seismic equipment. An example of sand exploration studies was incorporated in a 215‐km² survey of offshore areas by conducting bathymetric surveys and subbottom seismic profiling, collecting jet probes, grab samples, and vibrocores, and analyzing sediment grading in subsamples from vibrocores. These combined analyses indicated that at least 8.8 ×10⁶ m³ of sand is available in potential borrow areas from 7.0 to 12 km offshore in water depths of 8.0 to 11.5 m. In the PBAs, mean grain size of sand falls into the range 0.13–0.53 mm, sorting averages 0.65–1.31ø, and the overall silt content varies from 3.9–8.5%. High silt contents (13–19%) mapped in some areas make these sedimentary deposits unsuitable as fill for artificial beach renourishment.     

Errors due to the anisotropic-common-ray approximation of the coupling ray theory

The common-ray approximation eliminates problems with ray tracing through S-wave singularities and also considerably simplifies the numerical algorithm of the coupling ray theory for S waves, but may introduce errors in travel times due to the perturbation from the common reference ray. These travel-time errors can deteriorate the coupling-ray-theory solution at high frequencies. It is thus of principal importance for numerical applications to estimate the errors due to the common-ray approximation applied. The anisotropic-common-ray approximation of the coupling ray theory is more accurate than the isotropic-common-ray approximation. We derive the equations for estimating the travel-time errors due to the anisotropic-common-ray (and also isotropic-common-ray) approximation of the coupling ray theory. The errors of the common-ray approximations are calculated along the anisotropic common rays in smooth velocity models without interfaces. The derivation is based on the general equations for the second-order perturbations of travel time.