The value of a physically based model versus an empirical approach in the prediction of ephemeral gully erosion for loess-derived soils

A data set on soil losses and controlling factors for 58 ephemeral gullies has been collected in the Belgian loess belt from March 1997 to March 1999. Of the observed ephemeral gullies, 32 developed at the end of winter or in early spring (winter gullies) and 26 ephemeral gullies developed during summer (summer gullies). The assessed data have been used to test the physically based Ephemeral Gully Erosion Model (EGEM) and to compare its performance with the value of simple topographical and morphological indices in the prediction of ephemeral gully erosion.Analysis shows that EGEM is not capable of predicting ephemeral gully cross-sections well. Although conditions for input parameter assessment were ideal, some parameters such as channel erodibility, critical flow shear stress and local rainfall depth showed great uncertainty. Rather than revealing EGEM's inability of predicting ephemeral gully erosion, this analysis stresses the problematic nature of physically based models, since they often require input parameters that are not available or can hardly be obtained.With respect to the value of simple topographical and morphological indices in predicting ephemeral gully erosion, this study shows that for winter gullies and summer gullies, respectively, over 80% and about 75% of the variation in ephemeral gully volume can be explained when ephemeral gully length is known. Moreover, when previously collected data for ephemeral gullies in two Mediterranean study areas and the data for summer gullies formed in the Belgian loess belt are pooled, it appears that one single length (L)–volume (V) relation exists (V=0.048 L^1.29; R²=0.91). These findings imply that predicting ephemeral gully length is a valuable alternative for the prediction of ephemeral gully volume. A simple procedure to predict ephemeral gully length based on topographical thresholds is presented here. Secondly, the empirical length–volume relation can also be used to convert ephemeral gully length data extracted from aerial photos into ephemeral gully volumes.     

The use of7LiOH-impregnated filters for the collection of acidic gases and analysis by instrumental neutron activation analysis

A simple system was designed using⁷LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M⁷LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO₂ and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO₂ may not be collected quantitatively since SO₂ is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected.     

Ecotoxicological monitoring in lakes of Northwestern and Central European Russia situated in specially protected natural areas

An ecotoxicological assessment is given to the state of small lakes in specially protected natural areas in Northwestern and Central European Russia, which suffer from aerotechnogenic acidification. The toxicity of water and bottom sediments is shown to increase with decreasing water pH. The most sensitive characteristics of aquatic organisms in different trophic groups are chosen, allowing the state of lakes to be monitored.     

Optimal instrumentation of structures on flexible base for system identification

A criterion previously developed by Heredia-Zavoni and Esteva for selecting optimal sensor locations is used to analyse the optimal instrumentation of structures on soft soils. The stochastic response of a linear structural system on a flexible base is formulated for use of the criterion. The case of MDOF shear systems on flexible base, with uncertain lateral stiffness and subjected to random earthquake ground motions, is studied. The optimal location of accelerometers, the reduction of prior uncertainty on the lateral stiffness, the effects of the base flexibility, the relative influence of translation and rocking of the base, and the influence of recording noise are assessed and discussed. Copyright © 1999 John Wiley & Sons, Ltd.     

新疆近50a来降水量时空变化及其突变分析

基于新疆53个气象台站1960—2005年逐月降水资料,通过Mann-Kendall非参数趋势检验方法,对新疆近50 a来年降水量和12个月降水量的趋势进行了分析,并计算12个月对年降水量的贡献率,同时通过SequentialMann-Kendall方法分析了27个台站年降水量显著增加趋势发生的时间突变点。结果表明,新疆近50 a来年降水量显著增加,北疆和南疆趋势最为明显;其中冬半年(1、2、11月和12月)这4个月的降水量增加趋势显著,对新疆年降水量的贡献较大;新疆大部分台站年降水量趋势发生突变的时间点在20世纪80年代以后。     

荒漠生态系统C、N、P生态化学计量研究进展

生态化学计量学是通过研究生物有机体主要元素含量及其比值的变化关系,揭示生态系统各组分间元素循环规律的一门学科,生态化学计量也是荒漠生态系统研究的重要内容。因此,综合掌握水分和养分限制环境下C、N、P生态化学计量的关系对揭示荒漠生态系统植物的限制性元素、土壤营养的供给能力、养分的有效性等都具有重要的意义。基于此,回顾和分析了国内外荒漠生态系统C、N、P生态化学计量最新研究和动态,分别从植物、凋落物、土壤、土壤微生物、土壤酶进行较为系统的评述,讨论了植物-土壤-微生物-酶四者的关系,提出了荒漠生态系统C、N、P生态化学计量的未来研究方向,期望为全面理解固沙植被的演变过程、稳定性维持机制及其科学管理提供理论指导。     

Influence of m-cresol purple indicator additions on the pH of seawater samples: correction factors evaluated from a chemical speciation model

The perturbation of the indicator m-cresol purple on the pH in seawater is illustrated in diagrams, representing measurements in 1-cm and 5-cm cells. The diagrams apply to a measured pH interval of 7.4–8.4 using a 2-mM stock solution of m-cresol purple sodium salt dissolved in seawater. The magnitude of the perturbation is described as correction values, i.e., the change in seawater pH caused by the indicator. The diagrams are based on calculations made by using the equilibrium speciation programme, MARINHALT. From these calculations, and least squares fitting methods, pH correction values are described in terms of the pH difference between each seawater sample and the pH of an indicator stock solution. Calculations are performed for a typical high latitude water and a north Pacific deep water. Diagrams are presented for a salinity of 35 and a temperature of 15°C. Responses to salinities between 32 and 36 and temperatures 15–25°C are illustrated as well. A ±0.05 pH difference between a seawater sample and an indicator stock solution gives a correction of less than 0.001 pH unit for a 1-cm cell. For a 5-cm cell, pH differences between the indicator stock solution and a seawater sample as large as ±0.3 cause corrections smaller than ±0.001 pH unit. Calculations demonstrate that the five-fold lower indicator concentration used with 5-cm cells decreases the perturbation effect by approximately a factor of five relative to 1-cm cells.     

A Holocene record of climate change,fire ecology and human activity from montane Flat Top Bog,Maui

A sediment core from a high-elevation bog on Maui in the Hawaiian Islands contains evidence for drier conditions between 9.4–5.8 kyr BP, followed by a wetter interval between 5.8–2.2 kyr BP, and a variable late Holocene. These precipitation changes may be a reflection of vertical displacements of the upper boundary of the mid-Pacific Trade Wind Inversion (TWI) cloud layer. Fires, probably volcanically ignited, occurred in the forests prior to human arrival. Polynesian activity in this high-elevation, remote site was apparently limited, with no pollen, charcoal, or sedimentological evidence for local anthropogenic disturbance. After European contact, grass fires increased and introduced plant species invaded the site. Values for Cd, Cu, Pb, and Zn in sediments throughout the Holocene indicate low trace-metal deposition from atmospheric particulates at the site, even in the twentieth century.This paper is one of a series of papers guest edited by Dr. Mark Brenner on tropical paleolimnology     

Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

Relationships between Holocene sea-level variations,trophic development,and climatic change in Negra Lagoon,Southern Uruguay

Paleolimnological data are presented on trophic development, climatic change and sea level variations in Negra Lagoon, a 142 km² coastal lagoon in southern Uruguay. Using a sediment core that extended to the early Holocene, analyses of organic matter, carbonate, diatoms and opal phytoliths allowed us to track changes in trophic state and paleosalinity levels, which were closely related to Holocene sea level variation, temperature and humidity. Diatom Association Zones (DAZ) corresponding to transgressive events were dominated by marine/brackish taxa and relatively low organic matter values, while those DAZ corresponding to regressive events showed increases in brackish/freshwater diatoms and organic matter. Opal Phytoliths Association Zones (OPAZ) also were identified, temperature and humidity indices were calculated, and climatic trends were inferred. During the middle Holocene (i.e., ~5000–4000 yr BP), cool–dry climatic conditions were established. After ~4000 yr BP, a transition from cool to warm–humid conditions was observed, but fully warm humid conditions established only after ~1700 yr BP. Such climatic amelioration led to increases in trophic state.