美国罗德河流域地下水中铝形成动力学

In the Rhode River estuarine/watershed area, increased acidity of precipitation from atmospheric acidic deposition has deleterious effects on the freshwater ecosystems. One of the characteristics of an acidic watershed is the mobilization of aluminum from soils to aquatic environment. Increased concentrations of aluminum in surface waters are toxic to living organisms. Detection of long-term changes of acidity and elevated Al concentrations in surface and soil waters is a central issue. In this present paper, the dynamics ofAl speciation in the shallow ground waters from Rhode River watershed 110 (la) were investigated. This research provides a unique, regional analysis of important controls on the transport of Al speciation through the rural watershed of the Chesapeake Bay.     

Tectonic and climatic controls on late Quaternary bajada sedimentation along Narmada-Son Fault(NSF),Gujarat,Western India

An alluvial bajada has been recognized along a part of the active Narmada-Son Fault(NSF) and confined by the Karjan River on the eastern side and by the Madhumati River on western side.The bajada sequence exposed along the incised cliffs of various north flowing parallel streams has been studied in their proximal,medial and distal part. The sediments are characterized on the basis of grain size,fabric,sedimentary structures,bed geometry and sorting, and lithologs prepared from the mapped cliff sections.Detailed study of sedimentary characteristics,lithofacies analysis and facies associations indicate that sediments are mainly of three types-sediments that were deposited by debris flows and sediment gravity flows,and as extensive bar deposits.Three major aggredational sequences are recognized.Each sequence is composed of coarsening-upward sequence of proximal facies overlain by fining-upward sequence of distal facies.Coarsening upward sequence record periods of tectonic activity related to uplift along the NSF and fan progradation,whereas fining-upward sequence results from tectonic quiescence periods.The presence of rhizocretions,calcium carbonate nodules and calcite sheets within the basal debris flow and sediment gravity flow indicate semi-arid climate,whereas the formation of pedoginized paleosol indicate relatively wetter climate prevailing in the study area.Tectonic activity along the NSF has played dominant role by controlling the geometry and volume of bajada sediments.Climate is found to be responsible for compositional and temporal distribution of bajada sediments.OSL dating suggests that the bajada sediments were deposited during the later part of late Pleistocene.The incision of the sediments is attributed to uplift due to inversion of the lower Narmada basin during the early Holocene.     

Holocene slip rate and paleoearthquake records of the Salt Lake segment of the Northern Zhongtiaoshan Fault,Shanxi Province

The Northern Zhongtiaoshan Fault is a major deep fault at the southern margin of the Yuncheng Basin. There have been few studies on the fault, and the historical earthquakes are few and weak. However, the intensity of activity on the fault should never be underestimated. Through interpretations of aerial images, topography measurements and excavation of trenches, this paper studied the fault distribution, the surface deformation and the activity of the normal fault south of Salt Lake near the city of Yuncheng. By tracing faults in the three trenches, it was found that there had been at least three large paleoseismic events, at 1–3.5, 3.6–4.4 and 7.4–8.8 ka BP. Employing 14 C dating, we determined the same gravel layers in the uplifted side and downthrown side. Making differential Global Positioning System measurements of the vertical difference and topographic profile, we obtained the mean slip rate of the Northern Zhongtiaoshan Fault since 24.7 ka BP(0.75±0.05 mm/a). Using the results of relevant studies, we calculated the possible vertical fault displacement of one earthquake(2.35 m) and obtained the recurrence interval of characteristic earthquakes as 2940–3360 a after dividing the displacement by the mean slip rate.     

Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area,Sichuan Province,China

Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolution, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios(δ13C = 2.14‰, δ18O = -5.77‰), and was precipitated early. It was precipitated directly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid(δ18O = -3‰), which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios(δ13C = -2.36‰, δ18O = -15.68‰). This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2+, Fe3+ and Mg2+ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the burial process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite cements in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone(δ13C = 1.93‰, δ18O = -6.11‰), demonstrating that the two are from the same source that had a heavier oxygen isotope ratio(δ18O of about 2.2‰). The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different water-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles(lithic quartz sandstone) has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.     

南海共轭大陆边缘的构造对比及差异伸展模式

南海陆缘的伸展模式虽被广泛研究,但目前为止仍存在争议.本文基于最新的高质量多道地震数据、水深数据及其他地球物理资料,开展南海共轭陆缘构造不对称性的对比研究,并在此基础上探讨南海陆缘的伸展模式.揭示了南海陆缘在地形地貌、基底构造和陆缘断裂发育等方面具有空间差异性.在南北方向,北部陆缘基底呈现向海方向的阶梯状下降,而南部陆缘主要发育宽阔的掀斜断块基底,深度变化不大.两侧的断裂发育也具有不同的特点,在南部陆缘识别出大型拆离断层体系;在东西方向,南海东部和西南次海盆的陆缘分别发育了不同的构造单元.提出一种差异伸展模式解释南海陆缘空间差异的成因,认为拆离断层在南海新生代演化过程中发挥了重要的作用.以拆离断层为界,古华南陆缘上地壳主要发生单剪变形,而下地壳和上地幔则以塑性纯剪变形为主,上下两部分的形变区域在横向上具有不同的偏移距离,使得位于下板块的南部陆缘发育了不同的构造单元.南海东部较大的偏移距离导致边缘高原(礼乐滩)的发育,而西部较小的偏移距离则形成外部隆起(郑和隆起).现今南海的演化过程可能受到古南海关闭不同时性的影响.     

A risk assessment model for produced water discharge from offshore petroleum platforms-development and validation

Produced water discharge accounts for the greater portion of wastes arising from offshore oil and gas production operations. Development and expansion of Canada’s offshore oil and gas reserves has led to concerns over the potential long-term impacts of produced water discharges to the ocean. To examine this emerging environmental issue at a regional scale, an integrated risk assessment approach was developed in this study based on the princeton ocean model (POM), a random walk (RW) and Monte Carlo simulation. The use of water quality standards arrayed in a Monte Carlo design in the developed approach has served to reflect uncertainties and quantify environmental risks associated with produced water discharge. The model was validated against field data from a platform operating off Canada’s east coast, demonstrating its usefulness in supporting effective management of future produced water discharge.     

由帕克菲尔德圣安德烈斯断层深部观测台钻井点主动源监测得到的震前速度变化

测量地震活跃断层区内的应力变化一直是地震学长期探寻的目标。在此我们指出,利用在圣安德烈斯断层深部观测台(SAFOD)钻孔点进行的井间主动源试验所得的地震波波速对应力的依赖性就可测量到这种应力变化。在两个多月的时间里,我们观测到沿着地下固定路径传播的S波走时变化(几微秒)与气压变化之间存在非常好的负相关性。我们还发现在走时数据中有两次很大的偏移,这两次偏移的时间与两个预计在圣安德烈斯断层深部观测台会产生最大同震应力变化的地震的时间吻合。有趣的是,这两次偏移分别在地震事件之前约10小时和2小时的时间开始,说明它们可能与早期实验室研究(Braceetal,1966;Scholz,1968)观测到的破裂前应力导致的裂纹性质改变有关。     

Histopathology alterations and histochemistry measurements in mussel, Mytilus edulis collected offshore from an aluminium smelter industry (Norway)

Histopathological characteristics of specific organs express condition, and represent time-integrated impacts on the organism stemming from alterations at lower levels of biological organisation. As integrative parameters, histochemical investigations have proved to be sensitive tools to detect effects of chemical compounds. The objective of this study was to determine changes in the tissues of mussels collected at a PAH contaminated site compared to a reference site using histopathological and histochemical parameters: lipofuscin (LF) accumulation in mussel digestive gland, and lysosomal membrane stability (LMS), and using additional information provided by body burden analysis to compare the sensitivity of these parameters. The histochemical measurements for both LF and LMS gave a clear indication of a high level of stress in animals from the PAH contaminated site. This LF accumulation in lysosomes is the result of peroxidation of autophagocytosed proteins associated with protein aggregates and oxidatively damaged organelles. These measurements were able to detect the effects of PAHs, and showed a strong relationship with the body burden results.     

Assessment of the ecological quality status of soft-bottoms in Reunion Island (tropical Southwest Indian Ocean) using AZTI marine biotic indices

The ability of the two synthetic marine biotic indices, AMBI and M-AMBI, to account for changes in the ecological quality of coastal soft bottoms of Reunion Island according to disturbances was assessed from macrobenthic samples collected in five sectors between 1994 and 2004. Samples were collected under non-perturbed conditions and at two sites subjected to heavy organic enrichment. Both indices are based on a classification of macrofauna into ecological groups (EG), and their transfer to tropical waters required some adaptations. These indices proved efficient in detecting a degradation of habitat quality. Their use resulted in the classification of all sites sampled between 1996 and 1998 as "good" or "high". M-AMBI nevertheless tended to result in the attribution of a slightly worse ecological quality status than AMBI. Together with an update of the EG species list for the Indian Ocean area, our results support the extension of both indices for the assessment of tropical soft bottoms.     

Benthic macrophytes as a tool for delineating, monitoring and assessing ecological status: the case of Slovenian coastal waters

Benthic macrophytes from 51 sites in the upper infralittoral zone along the Slovenian rocky coast were sampled (randomly stratified) in order to (1) confirm water body (WB) boundaries, (2) select sampling points for a surveillance monitoring programme, and (3) assess preliminary Ecological Status Classes (ESC) within the European Water Framework Directive (WFD). Coverage data of macrophytes were analyzed by using cluster analysis, Simper analysis and the Ecological Evaluation Index (EEI). The vegetation was rather homogenously classified into two Cystoseiretum crinitae subassociations: Halopithetosum incurvae, and Cystoseiretosum compressae, and into Cystoseiretum barbatae association. Seven monitoring sites at a kilometer scale were selected in two significant sized WBs following the mixing zone principle and the EEI successional model. The preliminary assessment of the ESC with the EEI was in agreement with existing human pressures in the area. In view of the present results, benthic macrophytes and EEI could be valuable tools for the implementation of the WFD within the Mediterranean eco-region.