Carbonates calibrated against oceanographic parameters along a latitudinal transect in the Gulf of California, Mexico

Trophic resources are an important control governing carbonate production. Though this importance has long been recognized, no calibration exists to quantitatively compare biogenic assemblages within trophic resource fields. This study presents a field calibration of carbonate producers in a range of settings against high‐resolution in situ measurements of nutrients, temperature and salinity. With its latitudinal extent from 30° to 23° N, the Gulf of California, Mexico, spans the warm‐temperate realm and encompasses nutrient regimes from oligo‐mesotrophic in the south to eutrophic in the north. Accordingly, from south to north carbonates are characterized by: (i) coral‐dominated shallow carbonate factories (5–20 m water depth) with average sea‐surface temperatures of 25 °C (min. 18 °C, max. 31 °C), average salinities of 35·06‰ and average chlorophyll a levels, which are a proxy for nutrients, of 0·25 mg Chl a m^?3 (max. 0·48, min. 0·1). (ii) Red algal‐dominated subtidal to inner‐shelf carbonate formation (10–25 m) in the central Gulf of California exhibiting average temperatures of 23 °C (min. 18 °C, max. 30 °C), average salinities of 35·25‰, and average Chl a levels of 0·71 Chl a m^?3 (max. 5·62, min. 0). (iii) Molluskan bryozoan‐rich inner to outer shelf factories in the northern Gulf of California (20–50 m) with average sea surface temperatures of only 20 °C (min. 13 °C, max 29 °C), average salinities of 35·01‰, and average contents of 2·2 mg Chl a m^?3 (max. 8·38, min. 0). By calibrating sedimentological data with in situ measured oceanographic information in different environments, the response of carbonate producers to environmental parameters was established and extrapolated to carbonates on a global scale. The results demonstrate the importance of recognizing and quantifying trophic resources as a dominant control determining the biogenic composition and facies character of both modern and fossil carbonates.     

Thermal evolution of the orogenic lower crust during exhumation within a thickened Moldanubian root of the Variscan belt of Central Europe

At the eastern margin of the Bohemian Massif (Variscan belt of Central Europe), large bodies of felsic granulite preserve mineral assemblages and structures developed during the early stages of exhumation of the orogenic lower continental crust within the Moldanubian orogenic root. The development of an early steep fabric is associated with east–west-oriented compression and vertical extrusion of the high-grade rocks into higher crustal levels. The high-pressure mineral assemblage Grt-Ky-Kfs-Pl-Qtz-Liq corresponds to metamorphic pressures of ∼18 kbar at ∼850 °C, which are minimum estimates, whereas crystallization of biotite occurred at 13 kbar and ∼790 °C during decompression with slight cooling. The late stages of the granulite exhumation were associated with lateral spreading of associated high-grade rocks over a middle crustal unit at ∼4 kbar and ∼700 °C, as estimated from accompanying cordierite-bearing gneisses. The internal structure of a contemporaneously intruded syenite is coherent with late structures developed in felsic granulites and surrounding gneisses, and the magma only locally explored the early subvertical fabric of the felsic granulite during emplacement. Consequently, the emplacement age of the syenite provides an independent constraint on the timing of the final stages of exhumation and allows calculation of exhumation and cooling rates, which for this part of the Variscan orogenic root are 2.9–3.5 mm yr⁻¹ and 7–9.4 °C Myr⁻¹, respectively. The final part of the temperature evolution shows very rapid cooling, which is interpreted as the result of juxtaposition of hot high-grade rocks with a cold upper-crustal lid.     

Correlations in aftershock and seismicity patterns

Correlations in space and time play a fundamental role in earthquake processes. One direct manifestation of the effects of correlations is the occurrence of aftershocks due to the stress transfer in the vicinity of a main shock. Less obvious and more speculative changes in correlations may occur in the background seismicity before large earthquakes. Using statistical physics it is possible to introduce a measure of spatial correlations through a correlation length. This quantity characterizes how local fluctuations can influence the occurrence of earthquakes over distances comparable with the correlation length. In this work, the physical basis of spatial correlations of earthquakes is discussed in the context of critical phenomena and the percolation problem. The method of two-point correlation function is applied to the seismicity of California. Well defined variations in time of the correlation length are found for aftershock sequences and background seismicity. The scaling properties of our obtained distributions are analyzed with respect to changes in several scaling parameters such as lower magnitude cutoff of earthquakes, the maximum time interval between earthquakes, and the spatial size of the area considered. This scaling behavior can be described in a unified manner by utilizing the multifractal fit. Utilizing the percolation approach the time evolution of clusters of earthquakes is studied with the correlation length defined in terms of the radius of gyration of clusters. This method is applied to the seismicity of California.     

Modeling of the classification behavior of the diaphragms used in multi-chamber cement mills

A new approach has been developed for describing the classification that arises at the diaphragm in multi-chamber ball mills. Fourteen industrial scale cement mills have been sampled in this study and after mass balancing, model fits of the equipment were done. Successive mill product predictions for the sampled conditions were achieved, and requirements to build up an optimization capable model are discussed.     

Modified column flotation of adsorbing iron hydroxide colloidal precipitates

A promising technique for the removal of heavy metal ions from wastewater streams involved firstly the ions adsorption on a colloidal precipitate (carrier) and then the separation of the loaded flocs (coagula) by a modified column flotation. Here, the effluent feed and the carrier (ferric hydroxide) enter smoothly by the top of the column through a special diffuser, in counter current with rising bubbles (100–600 μm diameter) generated by using recycled water, surfactant and air suction through a venturi. High separation values of the column flotation of the carrier precipitates were achieved, despite the high superficial flow rate and the high Fe^+ 3 concentration utilized (> 60 mg L^− 1 Fe). No rupture of colloidal carrier aggregates was observed and a low split was ensured by monitoring the concentrate (floated product) flow rate. Results indicated that best separation was attained by controlling the medium pH (for best heavy metal ion adsorption onto the carrier), followed by sodium oleate, used as “collector” and optimizing operating parameters (conditioning, flow rates, etc.). The column throughput reached 43 m h^− 1 (m³ m^− 2 h^− 1), which is about 4 times the normal capacity of DAF-dissolved air flotation unit, the most used floater in wastewater treatment. Various metals (Cu, Ni, Pb, etc.) and molybdate ions present in synthetic and real effluent were successfully removed based on this colloidal adsorbing flotation principle. The process was also applied in a pilot scale to treat an industrial electroplating wastewater. Most of toxic metals (Cu, Ni and Zn) were reduced from initial concentrations of about of 2 to 10 mg L^− 1, to below 0.5 to 1.0 mg L^− 1, meeting local municipal discharge limits (but Cd ions). It is believed that flotation separation using medium-sized bubbles has great potential as a clean water and wastewater treatment technology.     

Middle Weichselian environments on western Yamal Peninsula, Kara Sea based on pollen records

Pollen data from two sections from a coastal cliff on the western Yamal Peninsula (69°43.27′N, 66°48.80′E) document the environmental history during the Karginsky (Middle Weichselian) interstadial. Low pollen concentrations, high amounts of redeposited pollen, and relatively high presence of Artemisia pollen characterize sediments deposited at about 33,000 ¹⁴C yr B.P. Grass-sedge plant associations with few other herbs occupied the area during the late Karginsky interstadial. Artemisia pollen may indicate rather xerophytic vegetation and disturbed soils in the area. The dominance of redeposited pollen reflects scarce (disturbed) vegetation cover and low pollen productivity. The climate was relatively cold and dry. Sediments dated to 32,400 ¹⁴C yr B.P. contain fewer redeposited pollen and concentration of non-redeposited pollen is significantly higher. Pollen contents indicate the dominance of tundra-like grass-sedge vegetation and more humid conditions. Pollen records dated between 30,100 and 25,100 ¹⁴C yr B.P. also reflect scarce tundra-like vegetation during this interval. The presence of Betula nana and Salix pollen may reflect limited presence of shrub communities. This suggests that the climate was somewhat warmer during the latter part of the interstadial. However, generally the pollen records show that harsh environmental conditions prevailed on the Yamal Peninsula during the Karginsky interstadial.     

Climate variability in the Spanish Pyrenees during the last 30,000 yr revealed by the El Portalet sequence

Palynological, sedimentological and stable isotopic analyses of carbonates and organic matter performed on the El Portalet sequence (1802 m a.s.l., 42°48′00?N, 0°23′52?W) reflect the paleoclimatic evolution and vegetation history in the central-western Spanish Pyrenees over the last 30,000 yr, and provide a high-resolution record for the late glacial period. Our results confirm previous observations that deglaciation occurred earlier in the Pyrenees than in northern European and Alpine sites and point to a glacial readvance from 22,500 to 18,000 cal yr BP, coinciding with the global last glacial maximum. The patterns shown by the new, high-resolution pollen data from this continental sequence, chronologically constrained by 13 AMS ¹⁴C dates, seem to correlate with the rapid climate changes recorded in Greenland ice cores during the last glacial-interglacial transition. Abrupt events observed in northern latitudes (Heinrich events 3 to 1, Oldest and Older Dryas stades, Intra-Allerød Cold Period, and 8200 cal yr BP event) were also identified for the first time in a lacustrine sequence from the central-western Pyrenees as cold and arid periods. The coherent response of the vegetation and the lake system to abrupt climate changes implies an efficient translation of climate variability from the North Atlantic to mid latitudes.