Infiltration pattern in a regolith–fractured bedrock profile: field observation of a dye stain pattern

We examined the infiltration pattern of water in a regolith–bedrock profile consisting of two overburdens (OB1 and OB2), a buried rice paddy soil (PS), two texturally distinctive weathered materials (WM1 and WM2) and a fractured sedimentary rock (BR), using a Brilliant Blue FCF dye tracer. A black‐coloured coating in conducting fractures in WM1, WM2 and BR was analysed by X‐ray diffraction and scanning electron microscopy. The dye tracer penetrated to greater than 2 m depth in the profile. The macropore flow and saturated interflow were the major infiltration patterns in the profile. Macropore flow and saturated interflow were observed along fractures in WM1, WM2 and BR and at the dipping interfaces of PS–WM1, PS–WM2 and PS–BR respectively. Heterogeneous matrix flow occurred in upper overburden (OB1) and PS. Compared with OB1, the coarser textured OB2 acted as a physical barrier for vertical flow of water. The PS with low bulk density and many fine roots was another major conducting route of water in the profile. Manganese oxide and iron oxide were positively identified in the black coating material and had low crystallinity and high surface area, indicating their high reactivity with conducting contaminants. Copyright © 2006 John Wiley & Sons, Ltd.     

Instrumentation and Numerical Analysis of Cylindrical Diaphragm Wall Movement During Deep Excavation at Coastal Area

ABSTRACT

The lateral deflection of a cylindrical diaphragm wall and the associated ground movement induced by deep excavation are analyzed by performing site instrumentations and numerical analyses in the coastal area of Korea. Wall lateral deflection, rebar stress, and pore water pressure were measured and analyzed in eight directions. Variations of soil properties with the decrease of confining pressure are compared by performing various in situ tests before ad after excavation. To calculate the wall lateral deflection accurately, the effects of small strain nonlinearity, confining pressure, and the hysteresis loading/unloading loop developed during excavation are considered in the proposed numerical analysis. By comparing numerical results with measured ones, the importances of considering small strain nonlinearity and confining pressure reduction in the nonlinear (FEM) are emphasized. Also, the effects of wall stiffness on the performance of cylindrical diaphragm walls are studied for future similar excavation in the coastal area.     

Ripples in intertidal mud—a conceptual explanation

On protected mudflats and along sheltered tidal channel margins, wave- and current-generated ripples are frequently observed on surficial and subsurface mud beds, although such bedforms are generally not thought to occur in cohesive sediments. In this paper, examples of such ripple marks in the German Wadden Sea (back-barrier tidal flats of Spiekeroog island) and also along the west coast of Korea (Baeksu tidal flats) are documented and analyzed. The mud ripples are 5–8 cm in spacing and 0.3–0.8 cm in height, and are composed of slightly sandy to virtually pure mud (80–98% mud content). For the Spiekeroog study area, a comparison of in situ particle-size measurements of suspended matter and of dispersed mud collected from the ripples shows that the former consists of low-density flocs which are considerably larger than the constituent grains of the latter. To assess local wave effects, near-bed orbital velocities and orbital diameters were calculated on the basis of standard wave theory using estimated wave parameters at the time of the study (June 2004) as well as wave data recorded nearby within the back-barrier tidal basin. The relationships between grain size, morphometric ripple parameters, and the near-bed orbital diameter show the wave-generated mud ripples to be of the orbital post-vortex type. It is demonstrated that only short-period shoaling (intermediate water depth) waves with periods of 1.5–2.5 s and heights of 0.1–0.5 m are able to generate and maintain such ripples. Corresponding near-bed orbital velocities range from 8–32 cm s^–1 and near-bed orbital diameters from 6.25–10 cm. It can be anticipated that increased current shear and turbulence associated with higher and longer waves prevent ripple formation due to the resuspension of settled mud, and the breakdown of suspended flocs and aggregates into smaller particles which then tend to remain in suspension. The most plausible explanation for the formation of the mud ripples is that mud flocs and aggregates deposited from suspension around high-water slack tide under moderate weather conditions initially respond as single (non-cohesive) particles which are hydraulically equivalent to ambient very fine sands. During exposure at low tide, gradual loss of water transforms the rippled mud into increasingly more cohesive mud drapes which are more resistant to erosion. Unless destroyed during high-energy events, the mud ripples may remain intact long enough to become buried and thereby preserved. Indeed, occasional but persistent observations of ripples in sub-Recent to ancient mudrocks document their preservation potential.     

Investigation of the accelerated carbonation of a MgO-based binder used to treat contaminated sediment

A MgO-based binder developed to simultaneously solidify/stabilize contaminated sediment and store CO₂ has been described previously. The objectives of the study presented here were to investigate the kinetics of the carbonation reactions of the binder and the extent to which carbonation occurred and to identify the optimal conditions for using the binder. The carbonation reaction was clearly faster and the degree of carbonation higher at CO₂ concentrations of 50 and 100% than in the ambient atmosphere (which contains 0.04% CO₂). A modified unreactive core model adequately described the kinetics. The rate constants were 0.0217–0.319 h^?1 and were proportional to the degree of carbonation. A high degree of carbonation, 93.8%, was achieved at a CO₂ concentration of 100%. The water to sediment ratio strongly affected carbonation, the optimal ratio being around 0.7. The relative humidity did not strongly affect the carbonation performance. The carbonation products were magnesite (MgCO₃) and nesquehonite (MgCO₃·3H₂O). X-ray diffraction analysis showed that brucite (Mg(OH)₂) was not present, suggesting that brucite was very quickly transformed into magnesium carbonates, the presence of which was confirmed by thermal gravimetric analysis. The results indicated that, in 7 d, 1 kg of binder could sequester up to 0.507 kg of CO₂ in a 100% CO₂ atmosphere. The results indicate that the MgO-based binder has great potential to be used to sequester CO₂ under accelerated carbonation conditions.     

集合同化方法在黄海海域海表面温度同化中的应用

The effects of sea surface temperature(SST) data assimilation in two regional ocean modeling systems were examined for the Yellow Sea(YS). The SST data from the Operational Sea Surface Temperature and Sea Ice Analysis(OSTIA) were assimilated. The National Marine Environmental Forecasting Center(NMEFC) modeling system uses the ensemble optimal interpolation method for ocean data assimilation and the Kunsan National University(KNU) modeling system uses the ensemble Kalman filter. Without data assimilation, the NMEFC modeling system was better in simulating the subsurface temperature while the KNU modeling system was better in simulating SST. The disparity between both modeling systems might be related to differences in calculating the surface heat flux, horizontal grid spacing, and atmospheric forcing data. The data assimilation reduced the root mean square error(RMSE) of the SST from 1.78°C(1.46°C) to 1.30°C(1.21°C) for the NMEFC(KNU) modeling system when the simulated temperature was compared to Optimum Interpolation Sea Surface Temperature(OISST) SST dataset. A comparison with the buoy SST data indicated a 41%(31%) decrease in the SST error for the NMEFC(KNU) modeling system by the data assimilation. In both data assimilative systems, the RMSE of the temperature was less than 1.5°C in the upper 20 m and approximately 3.1°C in the lower layer in October. In contrast, it was less than 1.0°C throughout the water column in February. This study suggests that assimilations of the observed temperature profiles are necessary in order to correct the lower layer temperature during the stratified season and an ocean modeling system with small grid spacing and optimal data assimilation method is preferable to ensure accurate predictions of the coastal ocean in the YS.     

Arsenic levels in human hair,Kandal Province,Cambodia: The influences of groundwater arsenic,consumption period,age and gender

This study focused on the analysis of As levels in human hair samples collected from six villages in the Kandal Province of Cambodia. Of interest were the influence of, and interactions among, certain factors affecting As intake into the human body: As concentrations in groundwater, period of groundwater consumption, age and gender. The results revealed As levels in human hair ranging from 0.06 to 30 μg g⁻¹ with median and arithmetic mean values of 0.61 and 3.20 μg g⁻¹ (n = 68), respectively. Furthermore, a linear relationship was found between As concentrations in human hair and in the local groundwater. Arsenic (III) is the dominant species in Kandal groundwater, constituting in most cases at least 60% of the total As. Arsenic concentration ranged from 5 to 1543 μg L⁻¹, with the median value 348 μg L⁻¹ and arithmetic mean 454 μg L⁻¹. In large rural, poor areas holding most of Kandal’s 1.1 million people, up to 2 in 1000 people are believed to be at risk of cancer through the As-enriched water they drink. A toxicity risk assessment provides a hazard quotient (HQ) equaling 5.12, also a clear indication of non-carcinogenic exposure risk. On the authors’ visit to Kampong Kong commune, Kandal Province, cases of arsenicosis were diagnosed in patients as a result of drinking As-enriched groundwater.     

Ship measurements of submicron aerosol size distributions over the Yellow Sea and the East China Sea

During the spring of 2005, the total particle concentrations and the submicron aerosol size distributions were measured on board the research vessel over the south sea of Korea and the Korean sector of the Yellow Sea. Similar measurements were made over the East China Sea in autumn 2005. The aerosol properties varied dynamically according to the meteorological conditions, the proximity to the land masses and the air mass back trajectories. The average total particle concentration was the lowest over the East China Sea, 4335 ± 2736 cm^− 3, but the instantaneous minimum, 837 cm^− 3, for the entire ship measurement was recorded during the Yellow Sea cruise. There was also a long (more than 6 h) stretch of low total particle concentrations that fell as low as 1025 cm^− 3 during the East China Sea cruise when the ship was the farthest from the shores and the air mass back trajectories resided long hours over the sea. These observations lead to the suggestion of ~ 1000 cm^− 3 as the background total particle concentration over the marine boundary layer in the studied region of the Yellow Sea and the East China Sea, implying significant anthropogenic influence even for the background value. In the mean time, average aerosol size distributions were unimodal and the mode diameter ranged between 52 and 86 nm, excluding the fog periods, which suggests that the aerosols measured in this study experienced relatively less aging processes within the marine boundary layer.     

UBVVI Surface Photometry of the Spiral Galaxy NGC 300 in the Sculptor Group

We present UBVI surface photometry over a 20.5' × 20.5' area of the late-type spiral galaxy NGC 300. We have derived isophotal maps, surface brightness profiles, ellipticity profiles, position angle profiles, and color profiles. By merging our I-band measurements with those of Boker et al. based on Hubble Space Telescope observations, we have obtained combined I-band surface brightness profiles for the region 0.02" < r < 500" and have decomposed the profiles into three components: a nucleus, a bulge, and an exponential disk.     

On the variation of frequency-based rainfall amounts: a case study for evaluating recent extreme rainfalls in Korea

Extreme rainfall events recently occurring in Korea have been shown to change frequency-based rainfall amounts quite significantly. Regardless of the reason for these extremes, the general concern of most hydrologists is how to handle these events for practical applications in Hydrology. Our study aim is to evaluate these extremes with their effect on frequency-based rainfall amounts, especially if they can be assumed to be within normal levels. As there is no commonly accepted methodology to be applied to this kind of study, we follow simplified steps such as: (1) estimation of the climatological variance of frequency-based rainfall amounts, (2) estimation of confidence intervals of frequency-based rainfall amounts (lower and upper bounds for the 5 and 1% significance levels estimated using the climatological variance), and (3) evaluation of the effect of extra rainfall events on the frequency-based rainfall amounts. Twelve stations on the Korean peninsula are selected as they have relatively longer data length. The annual maximum rainfall data collected from 1954 to 1998 are used. From this study we concluded that (1) at least 30 years of data length should be used for the frequency analysis in order to assure the stability of the variance of frequency-based rainfall amounts, (2) the climatological variances estimated all range from 5 to 8% of the frequency-based rainfall amounts, and (3) even though the frequency-based rainfall amount seems to become extreme with seemingly abnormal events, it still remains under its upper bound for the 5 or 1% significance levels estimated using the climatological variance, as well as it decays exponentially to the normal level as extra events are added. Thus, we conclude that we do not need to panic over seemingly abnormal events occurring so far, but just need to consider the variability inherent in frequency-based rainfall amounts.