锶,硼和氟联合作用的亚急性毒理实验及环境意义

本文以自由饮水给药方式进行了锶、硼和氟联合作用的亚急性实验，以探讨锶、硼对氟的拮抗作用。实验结果，给予小鼠200×l0^-6 F 六个月后，可使其骨氟含量显著升高(P<0.01)，肾碱性磷酸酶活力(ALP)显著增高(P<0.01)，4、5个月后血清碱性磷酸酶(ALP)活力亦显著增高(P<0.O1)，同时给予80×l0^-1 B3+、100×l0^-6Sr2+ 时，可以显著降低骨氟含量，抑制血清、肾碱性磷酸酶的活力，表明锶与硼对氟存在拮抗作用。     

The Origin of the Early Proterozoic Kuandian Complex: Evidence from Geochemistry

The Kuandian Complex is scarcely preserved Early Proterozoic volcanic suite, formed2.3-2.4 Ga ago. It is located in an Early Proterozoic mobile belt bounded by the ArchaeanRangrim and Ryonggang Blocks of the northeastern Sino-Korean Craton. The Complex ismainly made up of amphibolites, gneisses, leucoleptite, leptite and layered granite. Petrologicaland geochemical studies show that the protoliths of the Complex are mainly assoctations ofbimodal volcanics and anorogenic granites. The Kuandian amphibolites are depleted in Nb, Ta,P and Ti, and enriched in LILE, e.g. K, Rb and Cs, with pronounced depletion of Sr relative toNd and Pb; La/Nb ratios are higher than 1(1.75 to 5.18). The trace element patterns of theamphibolites are similar to continental flood basalts formed by the Gondwana break-up, suchas those in South Karoo and Tasmania, which shows continental contamination. ε_(Nd) valuesranging from 0.70 to 1.94 of the Kuandian amphibolites and the relationships between Nb/Yband La/Yb suggest that contamination of basaltic magma happened in the mantle, rather thanalong the conduit. Isotope ratios of ~(208)Pb/~(204)Pb, ~(207)Pb/ ~(204)Pb, ~(206)Pb/~(204)Pb, ~(143)Nd/~(144)Ndand ~(87)Sr/~(86)Sr indicate that the magma was derived from a contaminated mantle source likeDMM or a mixture of DMM and EM2. The Kuandian Complex has Dupal anomaly, as is thecase with some continental basalts in the south hemisphere, e.g. in South Karoo and Tasmania.Petrochemical modelling proposes that the Kuandian gneiss, granite, and amphibolite camefrom the same parental magma, being products of strong fractional crystallization. Protoliths ofthe Kuandian Complex were formed in extensional tectonic setting during the transition fromcontinental crust to oceanic crust. The formation of the Kuandian Complex indicates that 2.3or 2.4 Ga ago tectonic evolution of the Sino-Korean craton was different from that of otherwell-studied Precambrian cratons, e.g. the North American shield, European platform andAustralian continent in that strong volcanic eruption resulted in its accretion. Besides, the con-taminated magma source with a Dupal anomaly for the Complex indicates that crust-mantleconvection whose scale was similar to that of the present plate tectonics had occurred at leastbefore the formation of the Kuandian Complex (2.3-2.4 Ga B.P).     

Geochronology, geochemistry and tectonic implications of Xiongshan diabasic dike swarm, northern Fujian

Sm/Nd isotopic age determination showed that Xiongshan dike swarm was at 585.7 Ma ± 30 Ma. The trace element geochemistry and Sr/Nd/Pb isotope gemhemistry studies indicate that the dike swarm was products of back-arc basin spreading ridge and the magma originated from the depleted mantle region which was metasomatized by LILE-rich liquids/melts derived from subduction slab. Project supported by the National Natural Science Foundation of China.     

我国最大古岩溶型铀矿床成因的同位素地球化学研究

据对某大型古岩溶型铀矿床中铀－铅同位素体系及硫、碳、氧、氢同位素组成的研究结果，表明该矿床成矿物质源自矿区众多地层，成矿流体的变质水和古岩溶水（古大气降水）的混合水；成矿经历了古岩溶铀淋积富集，燕山早、晚期构造运动促使两次含铀热水溶液改造、叠加成矿（１３５～１１９。６５Ｍａ），成矿作用与古岩溶和区域地质构造演化密切相关，属古岩溶型热造铀矿床。     

Migration Fractionation of Neutral Nitrogen Compounds of Crude Oils from Tabei Oilfield in the Tarim Basin, China

The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.     

Pedogenic factors affecting magnetic susceptibility of the last interglacial palaeosol S1 in the Chinese Loess Plateau

The magnetic susceptibility has been used as a quantitative or semi‐quantitative proxy for reconstructing the summer monsoon intensity in the Chinese Loess Plateau based on extensive studies on climatic or/and environmental mechanisms producing the magnetic susceptibility signatures. However, the precise nature of the link between past climates and the susceptibility signatures has remained uncertain primarily due to lack of our understanding in the ?nalizing and preserving processes of the signatures. This paper attempts to examine the reliability or acceptability of this summer monsoon proxy from non‐magnetic perspectives of soil‐forming processes. We chose nine sections along two transects: one across the western part of the Chinese Loess Plateau and another across the eastern part. Several conclusions can be drawn from our analytical data. First, clay translocation within the S1 palaeosol pro?les, as indicated by ?eld‐observed clay coatings on ped faces in Bt and Bk horizons and demonstrated by laboratory‐analysed clay contents, must have moved some of the magnetic minerals downward so that the susceptibility re?ects only the post‐translocation distribution of the magnetic‐susceptibility‐producing minerals. Second, the best‐developed palaeosol S1S3 at most of the sections studied is not expressed by the magnetic susceptibility because this palaeosol developed in underlying coarse loess (L2) and coarse textures tend to lower the susceptibility. Third, carbonate concentration is normally negatively correlated with the magnetic susceptibility or simply suppresses the magnetic susceptibility peak when the susceptibility enhancement exceeds the carbonate dilution effect. To conclude, extreme caution must be observed when using magnetic susceptibility signatures to retrieve high‐resolution records of the last interglacial palaeoclimate in the Chinese Loess Plateau. Copyright © 2004 John Wiley & Sons, Ltd.     

Optimal design of viscoelastic dampers using eigenvalue assignment

In this study a procedure for determining the optimum size and location of viscoelastic dampers is proposed using the eigenvalue assignment technique. Natural frequencies and modal damping ratios, required to realize a given target response, are determined first by the convex model. Then the desired dynamic structural properties are realized by optimally distributing the damping and stiffness coefficients of viscoelastic dampers using non‐linear programming based on the gradient of eigenvalues. This optimization method provides information on the optimal location as well as the magnitude of the damper parameters. The proposed procedure is applied to the retrofit of a 10‐story shear frame, and to a three‐dimensional structure with an asymmetric plan. The analysis results confirm that the responses of model structures retrofitted by the proposed method correspond well with the given target response. Copyright © 2003 John Wiley & Sons, Ltd.     

Seismic structural control using an electric servomotor active mass driver system

This study investigates an electric‐type active mass driver (AMD) system for structural vibration control. Composed primarily of an electric servomotor and a ball screw, the electrical AMD system is free from noise problems, oil leakage, and labor‐intensive maintenance that commonly are associated with hydraulic AMD systems. The desired stroke amplification of the mass and the power demand of the servomotor can be adjusted via the ball screw pitch, which in turn affects the effectiveness and efficiency of the system. Meanwhile, an instantaneous optimal direct output feedback control algorithm is adopted. Numerical simulation is performed using a five‐story steel frame as the object structure under the conditions of the 1940 El Centro earthquake. The AMD system proves to be effective and efficient within a certain range of the ball screw pitch. The reductions of the peak responses can reach as high as 70% if properly designed. Requiring only the velocity measurement of the top floor for on‐line feedback control, the proposed control algorithm is recommended for practical implementation. Copyright © 2004 John Wiley & Sons, Ltd.     

Determination and application of the weights for landslide susceptibility mapping using an artificial neural network

The purpose of this study is the development, application, and assessment of probability and artificial neural network methods for assessing landslide susceptibility in a chosen study area. As the basic analysis tool, a Geographic Information System (GIS) was used for spatial data management and manipulation. Landslide locations and landslide-related factors such as slope, curvature, soil texture, soil drainage, effective thickness, wood type, and wood diameter were used for analyzing landslide susceptibility. A probability method was used for calculating the rating of the relative importance of each factor class to landslide occurrence. For calculating the weight of the relative importance of each factor to landslide occurrence, an artificial neural network method was developed. Using these methods, the landslide susceptibility index (LSI) was calculated using the rating and weight, and a landslide susceptibility map was produced using the index. The results of the landslide susceptibility analysis, with and without weights, were confirmed from comparison with the landslide location data. The comparison result with weighting was better than the results without weighting. The calculated weight and rating can be used to landslide susceptibility mapping.