A review of the Nimbus-7 ERB solar dataset

Fourteen years (November 16, 1978 through January 24, 1993) of Nimbus-7 total solar irradiance measurements have been made. The measured mean annual solar energy just outside of the Earth's atmosphere was about 0.1% (1.4 W/m²) higher in the peak years of 1979 (cycle 21) and 1991 (cycle 22) than in the quiet Sun years of 1985/86. Comparison with shorter, independent solar measurement sets and with empirical models qualitatively confirms the Nimbus-7 results. But these comparisons also raise questions of detail for future studies: in which years did the peaks actually occur and just how accurate are the models and the measurements?     

Characterizing the phosphorus forms extracted from soil by the Mehlich III soil test

Phosphorus (P) can limit crop production in many soils, and soil testing is used to guide fertilizer recommendations. The Mehlich III (M3) soil test is widely used in North America, followed by colorimetric analysis for P, or by inductively coupled plasma-based spectrometry (ICP) for P and cations. However, differences have been observed in M3 P concentrations measured by these methods. Using ³¹P nuclear magnetic resonance (P-NMR) and mass spectrometry (MS), we characterized P forms in M3 extracts. In addition to the orthophosphate that would be detected during colorimetric analysis, several organic P forms were present in M3 extracts that would be unreactive colorimetrically but measured by ICP (molybdate unreactive P, MUP). Extraction of these P forms by M3 was confirmed by P-NMR and MS in NaOH-ethylenediaminetetraacetic acid extracts of whole soils and residues after M3 extraction. The most abundant P form in M3 extracts was myo-inositol hexaphosphate (myo-IHP, phytate), a compound that may not contribute to plant-available P if tightly sorbed in soil. Concentrations of myo-IHP and other organic P forms varied among soils, and even among treatment plots on the same soil. Extraction of myo-IHP in M3 appeared to be linked to cations, with substantially more myo-IHP extracted from soils fertilized with alum-treated poultry litter than untreated litter. These results suggest that ICP analysis may substantially over-estimate plant-available P in samples with high MUP concentrations, but there is no way at present to determine MUP concentrations without analysis by both colorimetry and ICP. This study also tested procedures that will improve future soil P-NMR studies, such as treatment of acid extracts, and demonstrated that techniques such as P-NMR and MS are complimentary, each yielding additional information that analysis by a single technique may not provide.

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Late Holocene environmental change in Celestun Lagoon,Yucatan, Mexico

Journal of Paleolimnology - Epikarst estuary response to hydroclimate change remains poorly understood, despite the well-studied link between climate and karst groundwater aquifers. The influence...     

Seasonal variability in the Macroinvertebrate Community Index: Are seasonal correction factors required?

Freshwater macroinvertebrate data collected from streams in Taranaki, New Zealand (1981–2006) were used to examine seasonality of biological indices including taxon richness, %EPT (Ephemeroptera, Plecoptera, and Trichoptera) richness, and the hard‐ and soft‐bottomed (‐sb) stream versions of the Macroinvertebrate Community Index (MCI). All indices tested showed modest but statistically significant seasonal variation in hard‐bottomed streams. Seasonal means for the MCI were within ±3.0% of the annual mean. The Semi‐Quantitative MCI (SQMCI) (±4.3%), %EPT richness (±7.4%) and taxon richness (±7.7%) showed greater seasonal variability than the MCI. MCI, SQMCI, and %EPT richness were significantly higher in spring and winter compared with autumn and summer. Taxon richness was lower in winter than in other seasons. In soft‐bottomed streams, SQMCI‐sb showed least seasonality (within ±3.6% of the annual mean, nonsignificant), followed by MCI‐sb and taxon richness (±4.7%), and %EPT richness (±11.2%). Spring and winter MCI‐sb and SQMCI‐sb values tended to be significantly higher than those calculated from summer or autumn samples, although most values were within 5% of the annual site means. Examination of seasonal variation in species traits and their relationships to observed seasonal patterns of biotic indices did not support the suggestion that seasonal variations in life histories of aquatic macroinvertebrates affect index values. Rather, seasons with higher biotic index values were associated with a greater frequency of flow disturbance, which is consistent with the view that the character of New Zealand's stream macroinvertebrate communities with their poorly‐synchronised life histories, has been shaped by the unpredictable physical environment. We recommend the MCI and MCI‐sb for State of Environment reporting in New Zealand for cost‐effectiveness and because data requirements and seasonal variation were less than for quantitative alternative indices. We suggest that seasonal variability is unlikely to confound interpretation, and does not need to be considered.     

Case Studies of PSDDF for Phased Placement of Dredged Soils

Use of Terzaghi's one-dimensional consolidation theory is not suitable for consolidation of highly deformable soft clays such as dredged soils. To model this condition, it is necessary to consider non-linear finite strain consolidation behavior, i.e., changes in compressibility and permeability with increasing stress. A one-dimensional non-linear finite strain numerical model, Primary Consolidation, Secondary Compression, and Desiccation of Dredged Fill (PSDDF), has been used to predict the stress-dependent settlement of fine-grained dredged materials. In this paper, two case studies of using PSDDF are discussed to illustrate the applicability and accuracy of PSDDF. The first case study involves PSDDF simulations of laboratory-phased placement of a marine clay dredged from Busan, Korea. PSDDF results are in good agreement with the corresponding results of the laboratory large strain consolidation tests. The other involves estimating the service life of the Craney Island Dredged Material Management Area near Norfolk, Virginia, in the United States. The excellent agreement between measured and calculated values shows that PSDDF is a reliable tool for predicting settlement of dredged material.     

Correlations between microbial indicators, pathogens, and environmental factors in a subtropical Estuary

The objective of this study was to evaluate whether indicator microbes and physical–chemical parameters were correlated with pathogens within a tidally influenced Estuary. Measurements included the analysis of physical–chemical parameters (pH, salinity, temperature, and turbidity), measurements of bacterial indicators (enterococci, fecal coliform, Escherichia coli, and total coliform), viral indicators (somatic and MS2 coliphage), viral pathogens (enterovirus by culture), and protozoan pathogens (Cryptosporidium and Giardia). All pathogen results were negative with the exception of one sample which tested positive for culturable reovirus (8.5 MPN/100 L). Notable physical–chemical parameters for this sample included low salinity (<1 ppt) and high water temperature (31 °C). Indicator bacteria and indicator virus levels for this sample were within average values typically measured within the study site and were low in comparison with levels observed in other freshwater environments. Overall results suggest that high levels of bacterial and viral indicators were associated with low salinity sites.     

Factors Influencing the Stream‐Aquifer Flow Exchange Coefficient

Knowledge of river gain from or loss to a hydraulically connected water table aquifer is crucial in issues of water rights and also when attempting to optimize conjunctive use of surface and ground waters. Typically in groundwater models this exchange flow is related to a difference in head between the river and some point in the aquifer, through a “coefficient.” This coefficient has been defined differently as well as the location for the head in the aquifer. This paper proposes a new coefficient, analytically derived, and a specific location for the point where the aquifer head is used in the difference. The dimensionless part of the coefficient is referred to as the SAFE (stream‐aquifer flow exchange) dimensionless conductance. The paper investigates the factors that influence the value of this new conductance. Among these factors are (1) the wetted perimeter of the cross‐section, (2) the degree of penetration of the cross‐section, and (3) the shape of the cross‐section. The study shows that these factors just listed are indeed ordered in their respective level of importance. In addition the study verifies that the analytical correct value of the coefficient is matched by finite difference simulation only if the grid system is sufficiently fine. Thus the use of the analytical value of the coefficient is an accurate and efficient alternative to ad hoc estimates for the coefficient typically used in finite difference and finite element methods.     

Calibrating multi-frequency acoustic backscatter systems for studying near-bed suspended sediment transport processes

The utilisation of sound backscattered from sediments in suspension, to measure profiles of near-bed particle size and concentration, has been gaining increasing acceptance and usage by sedimentologists and coastal engineers over the past two decades. To obtain the sediment parameters from the backscattered signal requires an inversion to be conducted on the signal and this necessitates a system calibration. The calibration can be carried out by detailed acoustic and electronic measurements, or alternatively by measuring the backscattering from suspensions with known scattering characteristics. Here, we explore the latter approach and describe in some detail the calibration of a triple frequency acoustic backscatter system. The aim is to provide coastal scientists involved in using acoustics as a tool for sediment transport research, with a clear exposition of the calibration process. Suspensions of glass spheres of varying particle size were used as the calibration scatterers. To interpret the signal backscatter from the suspension of glass spheres a simple model for sphere scattering is presented. The results show that consistent calibration results can be obtained in a relatively simple and robust manner.     

Probing the magma plumbing of Erebus volcano,Antarctica, by open-path FTIR spectroscopy of gas emissions

Gas emissions from Erebus volcano, Antarctica, were measured by open-path Fourier transform infrared spectroscopy to understand degassing of its magmatic system. Two degassing phonolite lava lakes were present in the summit crater during observation in December 2004. We report analyses of H₂O, CO₂, CO, SO₂, HF, HCl and OCS, (in order of molar abundance) in the plumes. Variations in the proportions of these species strongly reflect the dynamics of degassing, and sourcing of gas from different depths in the magmatic network. The highest observed ratios of CO₂ and H₂O are consistent with gas extracted from the melt at a depth of up to ∼ 2 km below the lava lakes. Magma degassing above this depth contributes to a higher H₂O/CO₂ proportion in the airborne plume. The ratio therefore reflects the balance of deeper vs. shallower contributions of volatiles and, possibly, a combination of closed- and open-system degassing. We observe a strong contrast in HF content in emissions from the two lava lakes, which we attribute to differing levels of magma ascent and/or cooling and crystallization of the magma supply. Fluxes of all gas species were determined using independent SO₂ flux determinations and measured gas ratios. In the case of CO₂ and water, ∼ 1 and ∼ 0.4 m³ s^− 1, respectively, of parental basanite magma are required to sustain the calculated output. The discrepancy between the two figures is readily explained by sequestration of part of the magma supply at depth such that it only partially degasses its complement of water.