Gas accumulation from oil cracking in the eastern Tarim Basin: A case study of the YN2 gas field

Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C₂₊ alkanes. The δ¹³C₁ (−38.6‰ to −36.2‰) and δ¹³C₂ values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs.     

北京石花洞地区奥陶纪灰岩36Cl侵蚀速率初探

本文根据理论上灰岩中36Cl的5个来源，论述了36Cl在灰岩深度剖面上的4个分布特征，描述了36Cl的采样方法和AMS的分析技术。计算出北京石花洞地区奥陶纪（O2）灰岩的表面侵蚀速度（ε=17.40μm/a）。     

沙漠沙丘污水处理系统:原理、方法和效果

“沙漠沙丘系统(DDS)”是以地球化学工程学原理为指导的特殊水处理系统,它利用沙漠沙作为滤料,通过“机械过滤”、“化学作用”和“生物作用”净化污染水,一方面可使沙丘变得湿润而不再移动,以固定移动沙漠;另一方面又能净化污染水,最终起到“以害克害、固沙治水、一举多得”的良好综合生态环境效应。DDS是绿色的水处理系统,所需的原料和生成物都属于自然界存在的物质,无二次污染的发生。在DDS设计中,要注意的主要因素应包括:滤料的种类、湿干时间比、微生物培养方式、滤料层厚度、进水水质、时间、温度和pH等。DDS可以把官厅水库水由V类和超V类处理成2~3类水,从而恢复官厅水库的饮用水功能。     

福建省水氡观测资料变化规律与质量分析

本文对福建省水氡观测资料变化规律进行分析,并试图利用相对均方差、拟合噪声水平和相对年变幅等三项指标,对福建省8个水氡点的观测资料质量进行初步探索。     

浅析福建地倾斜潮汐因子γ及其组合动态特征

本文计算了福建自1992年至2004年以来的地倾斜EW和NS两分量的固体潮潮汐因子,并进行动态组合,绘制组合动态三种特征量:ΔγEW ΔγNS(表征扩容)、ΔγEW-ΔγNS(表征剪切应变)、ΔγEW/ΔγNS(表征介质各向异性)的时序曲线图,并进行固体潮特征分析,寻找中、强地震发生前远场块体和近场块体地倾斜突变性形变异常与之对应关系。结果表明:在福建沿海,海潮是决定倾斜固体潮特征的主要因素;福建发生5级上的中强地震、台湾发生7级以上强烈地震时,福建地倾斜固体潮潮汐因子及其动态组合特征存在明显的渐进式突变性形变异常现象,异常量和异常持续时间与震级和震中距有较好的对应关系。     

地质微生物地球化学作用的意义与展望

概要论述了地质微生物学、地下水微生态学、微生物地球化学作用的基本概念、研究内容、研究现状、科学意义、关键问题、发展前景和在地下水环境保护中的作用。该研究领域不仅拓宽了整个地质科学的研究范畴,而且推动了地质科学的发展,具有一定的创新性。     

北黄海盆地构造几何学研究新进展

北黄海盆地是发育于隆起背景之上的中、新生代沉积盆地。新一轮资源调查研究表明，北黄海中、新生代沉积盆地的基底由古生界沉积岩层和前寒武纪变质岩系等组成，盆地不同程度地发育下构造层（J3-K1）、中构造层（E2-E3）和上构造层（N）；从油气资源和中、新生代地层发育情况出发，将北黄海海域划分为辽东-海洋岛隆起区、北黄海盆地和胶北．刘公岛隆起区等3个一级构造单元，其中北黄海盆地包括6个二级构造单元和24个三级构造单元；盆地褶皱、断裂构造十分发育，褶皱构造可划分为区域挤压型、局部伴生型和披盖型等三类，断裂构造主要可见近EW—NE向、NW向和NNE向三组，其中近EW—NE向和NNE向断裂比较发育，控制着盆地隆、坳分布格局和沉积特征。     

Geochemistry and occurrence of inorganic gas accumulations in Chinese sedimentary basins

Inorganic gases are commonly seen in eastern China and occasionally in southern China from the shallow water columns above hot and cold springs. The gases contain 68% to nearly 100% CO₂, with δ¹³C_CO2 and δ¹³C₁ values in the range of −1.18‰ to −6.00‰ and −19.48‰ to −24.94‰, respectively. All of the 34 large inorganic CO₂ and one inorganic methane accumulations discovered in China are distributed in eastern parts of the country, from both onshore and continental shelf basins. No commercial inorganic gas accumulation has been found in central and western China. This is a review of the occurrence and geochemical characteristics of inorganic gas accumulations in Chinese sedimentary basins. A detailed study of gas samples collected from four representative inorganic CO₂ pools and one possible inorganic methane pool indicates that inorganic alkane gases typically show δ¹³C₁ values greater than −10‰ versus PDB (mostly −30‰), with a positive stable carbon isotope sequence of δ¹³C₁ < δ ¹³C₂ < δ¹³C₃ < δ ¹³C₄. In contrast, the δ¹³C₁ values of biogenic alkane gases are lighter than −30‰, with a negative isotope sequence (i.e. δ¹³C₁ > δ¹³C₂ > δ ¹³C₃ > δ¹³C₄). Inorganic gases also tend to show less negative δ¹³C_CO2 values (−10‰) than biogenic gases (<−10‰).     

Analysis of rock structure stability in coal mines

In this paper, the theory of limit point instability is used to analyse the stability of rock structures in coal mines. A general method of analysing stability of rock structures is put forward and a uniform instability condition of rock structures is set up. Some instability phenomena, such as rock bursts in circular roadways, pillars and long walls, and the outburst of coal and gas from circular roadways, are discussed analytically. At a later stage, the critical point of rock structure instability is determined. The influence of relative parameters (such as the mechanical properties of rock, coal, and the geometric sizes) on the stability of the rock structures is carefully analysed. Copyright © 2005 John Wiley & Sons, Ltd.     

Water soluble components of PM10 Chongqing, China

The concentrations of water soluble ions (Na⁺, NH₄ ⁺, K⁺, Mg²⁺, Ca²⁺, NO₃ ^-, Cl^-, and SO ₄ ^2- ) in PM₁₀ samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual average values of PM₁₀ are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m³), even that the value of the control site is still 20% higher than American standard (0.05 mg/m³). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM₁₀ were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO ₄ ^2- ] > [NO³ _-] > [Cl^-] > [F^-], and [Ca²⁺] > [NH₄ ⁺] > [K⁺] > [Na⁺] > [Mg²⁺]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As for NH_{4 +}, K⁺, Ca²⁺, NO₃ ^- and SO ₄ ^2- , their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those in summer and winter. The seasonal average concentrations of [Cl^-], [F^-], [Na⁺] and [Mg²⁺] are much lower than those of other ions. However, the concentrations of [Na⁺] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken into consideration as well.