The study of atmospheric optical parameters according to multiyear photometric observations of the sun in crimea

We describe the construction of an SF-1 automatic sun photometer designed for determining the atmospheric optical parameters in the region of 372–1005 nm during year-round observations (monitoring), as well as an improved method of automatic data processing. Observations in Crimea (in Simferopol with an SF-1 photometer since 2001 and in Karadag with an M-83 standard sun photometer since 1972) are presented. Observation data are analyzed to demonstrate the intra-annual and interannual time dependences of the aerosol optical depths and Angstrom exponents for the atmosphere over Simferopol and Karadag. The considerable decrease in the aerosol optical depth (i.e., an increase in atmospheric transparency over Crimea) since 1993 due to an abrupt decrease in the anthropogenic load on the atmosphere as a result of the suspension of main industrial plants is an important finding.     

Spectral and thermodynamic constraints on the existence of gypsum at the Juventae Chasma on Mars

The spectral imaging of the Mars obtained with the Mars Express/OMEGA experiment demonstrates that a majority of the sulfates-rich regions are associated with the interior light-toned layered deposits within the canyon system in the equatorial zone of the planet. While all sulfates-rich deposits inside the canyons are characterized by the presence of the kieserite and hydrated magnesium sulfates, the spectral features of gypsum were detected only in the Juventae Chasma and the Iani Chaos. The detection of gypsum in the upper part of the layered deposits, stacking the erosional remnant on the floor of the Juventae Chasma (above the spectral signature of the kieserite and polyhydrated sulfates detected on the flanks of the remnant) represents a more intriguing case. To clarify the question of the presence of gypsum in the Juventae Chasma, we present reanalyzed OMEGA spectra within that area and performed the chemical equilibrium modelling of sulfates precipitation sequence at the freezing and the evaporation of a hypothetical aqueous solution which could have existed within the Chasma in the past. Our results did not confirm the presence of distinct spectral signatures of gypsum. The results of equilibrium modelling also exclude significant precipitation of gypsum during the latest stage of the aqueous sedimentation, responsible for the formation of the upper part of the erosional remnant.     

Petrology of the parental melts and mantle sources of Siberian trap magmatism

Based on the investigation of olivine phenocrysts and melt and spinel inclusions in them from the picrites of the Gudchikhinsky Formation and olivine phenocrysts and the whole-rock geochemistry from the Tuklonsky and Nadezhdinsky formations of the Noril’sk region, the compositions and conditions of formation and evolution of the parental melts and mantle sources of Siberian trap magmatism were evaluated. Olivine phenocrysts from the samples studied are enriched in Ni and depleted in Mn compared with olivines equilibrated with the products of peridotite melting, which suggests a considerable role of a nonperidotitic component (olivine-free pyroxenite) in their mantle source. The onset of Siberian trap magmatism (Gudchikhinsky Formation) was related to the melting of pyroxenite produced by the interaction of ancient recycled oceanic crust with mantle peridotite. During the subsequent evolution of the magmatic system (development of the Tuklonsky and Nadezhdinsky formations), the fraction of the pyroxenite component in the source region decreased rapidly (to 40 and 60%, respectively) owing to the entrainment of peridotite material into the melting zone. The formation of magmas was significantly affected by the contamination by continental crustal material. The primitive magmas of the Gudchikhinsky Formation crystallized under near-surface conditions at temperatures of 1250–1170°C and oxygen fugacities 2.5–3.0 orders of magnitude below the Ni-NiO buffer. Simultaneously, the magmas were contaminated by continental silicic rocks and evaporites. The parental magmas of the Gudchikhinsky rocks corresponded to tholeiitic picrites with 11–14 wt % MgO. They were strongly undersaturated in sulfur, contained less than 0.25 wt % water and carbon dioxide, and were chemically similar to the Hawaiian tholeiites. They were produced by melting of a pyroxenite source at depths of 130–180 km in a mantle plume with a potential temperature of 1500–1580°C. The presence of low melting temperature pyroxenite material in the source of Siberian trap magmas promoted the formation of considerable volumes of melt under the thick continental lithosphere, which could trigger its catastrophic collapse. The contribution of pyroxenite-derived melt to the magmas of the Siberian trap province was no less than 40–50%. This component, whose solid residue was free of sulfides and olivine, played a key role in the origin of high contents of Ni, Cu, and Pt-group elements and low sulfur contents in the parental trap magmas and prevented the early dispersion of these elements at the expense of sulfide melt fractionation. The high contents of Cl in the magmas resulted in considerable HCl emission into the atmosphere and could be responsible for the mass extinction at the Paleozoic-Mesozoic boundary.     

Productivity cycles in Lake Hovsgol, NW Mongolia, during the last 1 Ma and the age model of the HDP-04 drill core record

Repetitive patterns in the records of total organic carbon (TOC), total nitrogen (TN) and δ¹³C_org observed in the Lake Hovsgol sediment section from HDP-04 drill core reflect past changes in productivity of Lake Hovsgol and in the isotopic composition of the lake's carbon pool. Lake Hovsgol productivity proxy signals are interpreted to represent the response of the Hovsgol lacustrine system to glacial–interglacial cycles of the Pleistocene. This interpretation is supported by the apparent orbitally-forced pattern in the TOC, TN and δ¹³C_org records of the past 250 ka in the BDP-96-2 drill core from neighboring Lake Baikal.The intervals with independent age control, such as the radiocarbon-dated last glacial–interglacial transition and the paleomagnetic reversals, make it evident that productivity proxy signals are reliable indicators of past cold-to-warm and warm-to-cold climate transitions, as seen from the agreement with the pattern of global climate change in marine δ¹⁸O records. The Brunhes/Matuyama reversal during the MIS 19 interglacial coincides with a distinct peak of TOC and TN in the Hovsgol record, similar to the signal during the Holocene interglacial. By contrast, the upper Jaramillo reversal in the Lake Hovsgol record occurs in a diatom-free calcareous interval characterized by minima in TOC, TN and by a ‘glacial’-type range of δ¹³C_org values. In both Lake Baikal and Lake Hovsgol records, peaks in TOC and TN contents help distinguishing past interglacials and interstadials, and isotopically-heaviest δ¹³C_org values help identify past glacial intervals.An age model for the HDP-04 drill core section is proposed based on recognizing the repetitive patterns in Lake Hovsgol productivity and lithologic records as regional paleoclimate cycles of middle to late Pleistocene. Absolute dates and diatom biostratigraphic correlation ties to the Lake Baikal record are used as key controls. In the proposed age model, the interval 81–24 m in the HDP-04 sediment section below the major unconformity is correlated to MIS 27 through late MIS 13, whereas the upper 24 m of the HDP-04 section is suggested to have recovered the sedimentary record of late MIS 7 to MIS 1.     

The first Sm–Nd isotope–geochemical data on the Paleoproterozoic age of metamorphic rocks from the crystalline basement of the Yurovsk rise (Okhotsk massif)

Rocks with Paleoproterozoic Sm–Nd model ages (T _Nd(DM) = 2096–2350 Ma) are the sources of protoliths with gneiss, amphibolite, marble, and calciphyre of Yurovsk rise. This fact makes possible estimation of the lower age boundary of the formation of the crystalline basement of Yurovsk rise as Paleoproterozoic. According to the results of Sm–Nd, U–Pb (SHRIMP), and Pb–Pb geochronological studies, two isotope provinces are distinguished within the crystalline basement of the Okhotsk massif. The Paleoarchean province occupies the territory of Kukhtui rise, in which crust-forming processes played a key role (3250–3650 Ma). The Paleoproterozoic province includes Yurovsk rise, in which the major stages of crust formation have an age of 1900–2350 Ma.     

Analysis and characterization of ash-free coals from the Pechora coal basin obtained by organic solvent extraction

Doklady Earth Sciences - The probability of obtaining of ash-free coal extracts, so-called “hyper-coals,” has been shown for coals of the Pechora basin for the first time. The ash...     

Isotope compositions of C and O of magmatic calcites from the Udachnaya–East pipe kimberlite,Yakutia

It has been demonstrated for the first time that the isotopic compositions of carbon (δ¹³C) in magmatic calcites from the Udachnaya–East pipe kimberlite groundmass varies from–2.5 to–1.0‰ (V-PDB), while those of oxygen (δ¹⁸O) range from 15.0 to 18.2‰ (V-SMOW). The obtained results imply that during the terminal late magmatic and postmagmatic stages of the kimberlite pipe formation, the carbonates in the kimberlite groundmass became successively heavier isotopically, which indicates the hybrid nature of the carbonate component of the kimberlite: it was formed with contributions from mantle and sedimentary marine sources.

     

Primary melt and fluid inclusions in regenerated crystals and phenocrysts of olivine from kimberlites of the Udachnaya-East Pipe,Yakutia: The problem of the kimberlite melt

The primary melt and fluid inclusions in regenerated zonal crystals of olivine and homogeneous phenocrysts of olivine from kimberlites of the Udachnaya-East pipe, were first studied by means of microthermometry, optic and scanning electron microscopy, electron and ion microprobe analysis (SIMS), inductively coupled plasma mass-spectrometry (ICP MSC), and Raman spectroscopy. It was established that olivine crystals were regenerated from silicate–carbonate melts at a temperature of ~1100°C.

     

Authigenic Carbonates from Holocene Sediments of Lake Itkul (South of West Siberia) as Indicators of Climate Changes

Doklady Earth Sciences - The results of this study on carbonate-containing bottom sediments of the shallow brackish Lake Itkul, West Siberia, are presented. The study methods applied included X-ray...     

Water in Parental Basaltic Magmas of Menshyi Brat Volcano (Iturup Island,Kurile Islands)

Doklady Earth Sciences - Data from the study of minerals of the liquidus association (olivine and spinel) from high-Mg basalts (up to 10 wt % MgO) of Menshyi Brat Volcano (Iturup Island) are...