Genesis of the Au–Bi–Cu–As, Cu–Mo ± W, and base–metal Au–Ag mineralization at the Mountain Freegold (Yukon, Canada): constraints from Ar–Ar and Re–Os geochronology and Pb and stable isotope compositions

The genesis of mineralized systems across the Mountain Freegold area, in the Dawson Range Cu–Au?±?Mo Belt of the Tintina Au province was constrained using Pb and stable isotope compositions and Ar–Ar and Re–Os geochronology. Pb isotope compositions of sulfides span a wide compositional range (²⁰⁶Pb/²⁰⁴Pb, 18.669–19.861; ²⁰⁸Pb/²⁰⁴Pb, 38.400–39.238) that overlaps the compositions of the spatially associated igneous rocks, thus indicating a magmatic origin for Pb and probably the other metals. Sulfur isotopic compositions of sulfide minerals are broadly similar and their δ³⁴S (Vienna-Canyon Diablo Troilite (V-CDT)) values range from ?1.4 to 3.6 ‰ consistent with the magmatic range, with the exception of stibnite from a Au–Sb–quartz vein, which has δ³⁴S values between ?8.1 and ?3.1 ‰. The δ³⁴S values of sulfates coexisting with sulfide are between 11.2 and 14.2 ‰; whereas, those from the weathering zone range from 3.7 to 4.3 ‰, indicating supergene sulfates derived from oxidation of hypogene sulfides. The δ¹³C (Vienna Peedee Belemnite (VPDB)) values of carbonate range from ?4.9 to 1.1 ‰ and are higher than magmatic values. The δ¹⁸O (V-SMOW) values of magmatic quartz phenocrysts and magmatic least-altered rocks vary between 6.2 and 10.1 ‰ and between 5.0 and 10.1 ‰, respectively, whereas altered magmatic rocks and hydrothermal minerals (quartz and magnetite) are relatively ¹⁸O-depleted (4.2 to 7.9 ‰ and ?6.3 to 1.5 ‰, respectively). Hydrogen isotope compositions of both least-altered and altered igneous rock samples are D-depleted (from ?133 to ?161 ‰ Vienna-Standard Mean Ocean Water (V-SMOW)), consistent with differential magma degassing and/or post-crystallization exchange between the rocks and meteoric ground water. Zircon from a chlorite-altered dike has a U–Pb crystallization age of 108.7?±?0.4 Ma; whereas, the same sample yielded a whole-rock Ar–Ar plateau age of 76.25?±?0.53 Ma. Likewise, molybdenite Re–Os model ages range from 75.8 to 78.2 Ma, indicating the mineralizing events are genetically related to Late Cretaceous volcano-plutonic intrusions in the area. The molybdenite Re–Os ages difference between the nearby Nucleus (75.9?±?0.3 to 76.2?±?0.3 Ma) and Revenue (77.9?±?0.3 to 78.2?±?0.3 Ma) mineral occurrences suggests an episodic mineralized system with two pulses of hydrothermal fluids separated by at least 2 Ma. This, in combination with geological features suggest the Nucleus deposit represents the apical and younger portion of the Revenue–Nucleus magmatic-hydrothermal system and may suggest an evolution from the porphyry to the epithermal environments.     

Ground-penetrating radar for monitoring the distribution of near-surface soil water content in the Gurbantünggüt Desert

In the Gurbantünggüt Desert, snowmelt-induced high soil water contents briefly create favorable conditions for the germination and growth of plants every spring. Monitoring the rapidly changing conditions in this time period demands fast and efficient methods for measuring soil water contents at the field scale. For this study, a series of ground-penetrating radar (GPR) measurements were carried out on sites characterized by semi-vegetated dunes both in April 2010 and 2011. We compare water contents calculated from the GPR direct ground wave signal to both point scale validation measurements by time-domain reflectometry (TDR) and gravimetric sampling. Our results show that GPR is an effective method to rapidly obtain a detailed image of the field scale soil water content distribution in the Gurbantünggüt Desert with an accuracy similar to TDR. Observed large scale soil water content variations are dominated by dune topography: During snow melting, melt water was found to trickle slowly from the dune ridges to interdune valleys, increasing the soil water content there while the dune ridges quickly started to dry down. In dune valleys, smaller scale near-surface soil water content changes were dominated by variations in the vegetation coverage, leading to snowmelt funnels at distinct locations: The snowmelt initially occurred around the stems and branches of plants, forming funnel-shaped melt water induced holes through the snow cover and leading to an increasing amount of melt water collected around these plant roots. Our comparison of data from 2010 to 2011 furthermore suggests a temporally stable distribution of near-surface soil water content. This has important ecological significance for controlling desertification and for restoring and reconstructing vegetation in the Gurbantünggüt Desert.     

New records of Dorcatherium guntianum (Tragulidae), stratigraphical framework, and diphyletic origin of Miocene European tragulids

Seven hitherto unpublished Dorcatherium guntianum teeth from the Early Miocene of Germany are described. Morphology and size of the teeth are documented in detail and taxonomic affiliation is assessed based on comparisons to type materials of European tragulids. The fossils represent one of the earliest European Dorcatherium records and the oldest unequivocal evidence of D. guntianum from Germany. A review of the European Dorcatherium occurrence pattern suggests that a bunoselenodont and a selenodont lineage immigrated into Europe simultaneously from the East or Southeast, and corroborates the interpretation of the genus as being diphyletic. Moreover, our data add support to immigration scenarios that have been linked with the emerging freshwater wetlands, which formed as a result of the regression in the Western Paratethys.     

H2O–CO2 solubility in mafic alkaline magma: applications to volatile sources and degassing behavior at Erebus volcano, Antarctica

We present new equilibrium mixed-volatile (H₂O–CO₂) solubility data for a phonotephrite from Erebus volcano, Antarctica. H₂O–CO₂-saturated experiments were conducted at 400–700 MPa, 1,190 °C, and ~NNO + 1 in non-end-loaded piston cylinders. Equilibrium H₂O–CO₂ fluid compositions were determined using low-temperature vacuum manometry, and the volatile and major element compositions of the glassy run products were determined by Fourier transform infrared spectroscopy and electron microprobe. Results show that the phonotephrite used in this study will dissolve ~0.8 wt% CO₂ at 700 MPa and a fluid composition of $ X_{{{\text{H}}_{ 2} {\text{O}}}} $ ~0.4, in agreement with previous experimental studies on mafic alkaline rocks. Furthermore, the dissolution of CO₂ at moderate to high $ X_{{{\text{H}}_{ 2} {\text{O}}}}^{\text{fluid}} $ in our experiments exceeds that predicted using lower-pressure experiments on similar melts from the literature, suggesting a departure from Henrian behavior of volatiles in the melt at pressures above 400 MPa. With these data, we place new constraints on the modeling of Erebus melt inclusion and gas emission data and thus the interpretation of its magma plumbing system and the contributions of primitive magmas to passive and explosive degassing from the Erebus phonolite lava lake.     

Description and crystal structure of albrechtschraufite, MgCa4F2[UO2(CO3)3]2⋅17-18H2O

Albrechtschraufite, MgCa₄F₂[UO₂(CO₃)₃]₂?17-18H₂O, triclinic, space group Pī, a?=?13.569(2), b?=?13.419(2), c?=?11.622(2) Å, α?=?115.82(1), β?=?107.61(1), γ?=?92.84(1)° (structural unit cell, not reduced), V?=?1774.6(5) ų, Z?=?2, D _c?=?2.69 g/cm³ (for 17.5 H₂O), is a mineral that was found in small amounts with schröckingerite, NaCa₃F[UO₂(CO₃)₃](SO₄)?10H₂O, on a museum specimen of uranium ore from Joachimsthal (Jáchymov), Czech Republic. The mineral forms small grain-like subhedral crystals (≤ 0.2 mm) that resemble in appearance liebigite, Ca₂[UO₂(CO₃)₃]??~?11H₂O. Colour pale yellow-green, luster vitreous, transparent, pale bluish green fluorescence under ultraviolet light. Optical data: Biaxial negative, nX?=?1.511(2), nY?=?1.550(2), nZ?=?1.566(2), 2?V?=?65(1)° (λ?=?589 nm), r < v weak. After qualitative tests had shown the presence of Ca, U, Mg, CO₂ and H₂O, the chemical formula was determined by a crystal structure analysis based on X-ray four-circle diffractometer data. The structure was later on refined with data from a CCD diffractometer to R1?=?0.0206 and wR2?=?0.0429 for 9,236 independent observed reflections. The crystal structure contains two independent [UO₂(CO₃)₃]^4? anions of which one is bonded to two Mg and six Ca while the second is bonded to only one Mg and three Ca. Magnesium forms a MgF₂(O_carbonate)₃(H₂O) octahedron that is linked via the F atoms with three Ca atoms so as to provide each F atom with a flat pyramidal coordination by one Mg and two Ca. Calcium is 7- and 8-coordinate forming CaFO₆, CaF₂O₂(H₂O)₄, CaFO₃(H₂O)₄ and CaO₂(H₂O)₆ coordination polyhedra. The crystal structure is built up from MgCa₃F₂[UO₂(CO₃)₃]?8H₂O layers parallel to (001) which are linked by Ca[UO₂(CO₃)₃]?5H₂O moieties into a framework of the composition MgCa₄F₂[UO₂(CO₃)₃]?13H₂O. Five additional water molecules are located in voids of the framework and show large displacement parameters. One of the water positions is partly vacant, leading to a total water content of 17-18H₂O per formula unit. The MgCa₃F₂[UO₂(CO₃)₃]?8H₂O layers are pseudosymmetric according to plane group symmetry cmm. The remaining constituents do not sustain this pseudosymmetry and make the entire structure truly triclinic. A characteristic paddle-wheel motif Ca[UO₂(CO₃)₃]₄Ca relates the structure of albrechtschraufite partly to that of andersonite and two synthetic alkali calcium uranyl tricarbonates.     

Geodetic monitoring of tectonic deformation in the Australian region

A number of geodetic techniques exist for measuring instantaneous crustal motions and deformations. Over distances of a few hundred kilometres, conventional terrestrial methods can achieve accuracies of about 1–2 parts in 10⁶ for horizontal positions, but most existing triangulation networks in Australia are of lower accuracies. Geodetic levelling can provide height‐difference measurements with an accuracy of a few mm for points separated by about 100 km, but actual accuracies are often much lower than this. For points separated by longer distances, from a few 100 km to several 1000 km, space techniques can provide precisions of 5–10 cm. Two experiments carried out in Australia confirm that these precisions can be reached. A laser ranging experiment between sites near Canberra and Perth produced a baseline that is precise to better than 10 cm, and a radio‐interferometry experiment between Canberra, Parkes and Sydney produced baselines with precisions of 10 cm. Further evaluation of both systems is required, but the present results indicate that crustal deformations of the order of 10 cm can be measured with repeat surveys.     

Landscape ‘Contagion’ in Raster and Vector Environments

Abstract

Raster land cover data has been used to construct adjacency matrices by scanning the pixel edges and calculating proportions according to the land cover types joined. Like joins (e.g., forest to forest) are most common because pixel size is typically much smaller than the average patch size. The dominance of like joins (the matrix diagonal) of the adjacency matrix has led to one interpretation of the matrix as landscape contagion (the tendency of land cover to cluster into a few, large patches). Construction of the adjacency matrix in a vector environment results in a different measurement. In a vector environment, land cover patches are not sub–divided into pixels. Therefore, the main diagonal of the adjacency matrix is zero. Construction of an adjacency matrix in a vector environment estimates the evenness of distribution of edge types, not contagion. The same edge type evenness metric is estimated in a raster environment by ignoring the matrix diagonal and re-scaling the off-diagonal elements so that they sum to one (1).     

Economic Efficiency of Residential Water Conservation Programs in a Pennsylvania Public Water Utility

This study examines the economic efficiency of implementing a residential water conservation program in a small Pennsylvania public water utility. Local demographic data and results from similar programs elsewhere were used to estimate potential water conservation for three programs: rebates for low-flow toilets, rebates for high-efficiency washing machines, and in-home water audits. Future water supply and wastewater treatment demand were estimated. The net present value of constructing, operating, and maintaining new capacity infrastructure (water supply, water storage tanks, and wastewater treatment plant capacity), as well as the costs of the conservation programs, was calculated for a range of scenarios that included future demand growth, construction costs, interest rates, and levels of participation in the conservation programs. Results indicate that investing in residential water conservation would be cost-effective for a small number of scenarios that generally combine higher growth rates, higher interest rates, higher construction costs, and relatively modest public participation in conservation. The results are affected by the timing of necessary supply-side investments relative to the most significant water conservation gains, the relatively inexpensive local water supply costs, and the relatively high local wastewater treatment costs. Water conservation might be cost-effective for a wider range of conditions in communities facing scarce and expensive water supply options.