Holocene alluvial stratigraphy in the upper Susquehanna River Basin, New York

Two alluvial terraces and the present flood plain were studied at two locations along the Susquehanna and Unadilla Rivers in south-central New York state. They have formed since deglaciation and incision of the stream channels into the valley train deposits. The higher terrace has noncumulative soil profiles with well-developed color B horizons predominantly of silt loam and very fine sandy loam. The terrace is weathered to a degree similar to nearby glacial outwash terraces that have caps of similarly textured sediments. Incision that produced the terrace occurred before 9705 ± 130 yr B.P. The lower terrace is characterized by relatively thick, vertical-accretion deposits of silt loam that contain sequences of thin, buried A, color B, and C horizons. They were formed between about 3240 ± 110 (¹⁴C data of soil humin) and 235 ± 80 yr B.P. Deposits above the 235 ± 80 yr B.P. stratum are unweathered. The soil stratigraphy and ¹⁴C dates of soil humin from buried A horizons are surprisingly well correlated between sites. Most sediments of the present flood plain have been deposited since 1120 ± 80 yr B.P. Incipient A horizons and oxidation of inherited organic matter in the subsoil are the only evidence of pedogenesis in the flood-plain deposits that are older than 275 ± 80 yr B.P. The most recent flood-plain fill deposited since then is unaltered. These youngest sediments of the flood plain along with the youngest veneer of vertical-accretion deposits on the lowest terrace are associated with an increased rate of deposition largely attributable to clearing of the forests by settlers, beginning in the late 1700s. Comparison of the alluvial stratigraphy with the radiocarbon-dated pollen stratigraphy of southwestern New York (Miller 1973) reveals some apparent time correlations between alluvial events and vegetation changes. This gives reason to speculate that climatic change or forest catastrophes such as disease or drought are causes of some of the alluvial events.     

Cosmic-ray-produced36Cl and53Mn in Allan Hills-77 meteorites

Cosmic-ray-produced⁵³Mn (t_1/2 = 3.7 × 10⁶years) has been determined by neutron activation in nine Allan Hills-77 meteorites. Additionally,³⁶Cl (_1/2 = 3.0 × 10⁵years) has been measured in seven of these objects using tandem accelerator mass spectrometry. These results, along with¹⁴C (t_1/2 = 5740years) and²⁶Al (7.2 × 10⁵ years) concentrations determined elsewhere, yield terrestrial ages ranging from 0.1 × 10⁵ to 7 × 10⁵ years. Weathering was not found to result in⁵³Mn loss.     

Hallimond tube flotation of scheelite and calcite with amines

Hallimond tube flotation experiments have been carried out on the two calcium minerals scheelite and calcite using dodecylammonium chloride as collector. The main variables studied were the calcium ion concentration and the pH.In the case of scheelite, addition of calcium chloride markedly lowered the flotation recovery. Recovery was also lowered when the pH was reduced below about 10. Since it is known that the zeta potential of scheelite is almost independent of pH this confirms that co-adsorption of un-ionized amine is necessary for good flotation. Other un-ionized long-chain molecules can replace the amine; thus it was shown that excellent flotation can be obtained event at about pH 7 by adding dodecanol together with dodecylammonium chloride. With the completely ionic trimethyldodecylammonium chloride recoveries were poor and were independent of pH.In the case of calcite, calcium chloride had no immediate effect on flotation recovery, but at low collector concentrations marked depression occurred after many hours standing in the presence of calcium ions. The effect of pH on flotation of calcite was anomalous and there appear to be two pH regions in which recoveries are high.The results are discussed and attention is drawn to the need for more thorough studies of the calcium carbonate/water interface.     

Schwefel-Isotope und die Genese von Erzlagerstätten

Zusammenfassung Die Möglichkeiten und Probleme der genetischen Ausdeutung von Schwefel-Isotopen-Verhältnissen in Erzmineralien werden an Beispielen (vorwiegend nach Messungen verschiedener Autoren im Göttinger Zentrallabor) diskutiert. Es ergeben sich z. B. Anhaltspunkte, ob eine Lagerstätte von basaltischen Magmen aus dem Erdmantel abzuleiten sein kann oder nicht. Die Meßdaten von Meggen und vom Rammeisberg sind mit einer Ableitung aus dem Erdmantel höchstens bei wesentlichen Zusatzannahmen (sehr starke Assimilation von ungewöhnlichem Krustenmaterial oder extreme Fraktionierung in einem Sekundärherd) vereinbar. Aus der Kruste abzuleitende hydrothermale Lagerstätten können schwankende (Harz) oder auch ziemlich einheitliche S-Isotopen-Verhältnisse zeigen (Freiberg/ Sa.; Süddeutschland). Extreme Unterschiede innerhalb der Lagerstätte Wiesloch bei Heidelberg werden durch bakterielle Fraktionierung eines begrenzten Sulfat-Vorrates gedeutet. — In Abb. 6 sind außerdem Blei-Isotopen-Verhältnisse aus Süddeutschland dargestellt.

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The possibilities and problems of the genetical interpretation of sulfur isotope ratios in ore minerals are discussed using mainly results from the Göttingen isotope laboratory. For example, criteria are obtained regarding the question whether a certain deposit can be derived from basaltic magmas from the Earth's mantle, or not. The sulfur isotope data for minerals from the deposits of Meggen and Rammelsberg (Germany) are only consistent with a derivation from the mantle if substantial additional assumptions are made (very strong assimilation of unusual crustal material or extreme fractionation in a secondary magma chamber). Hydrothermal deposits derived from the Earth's crust can show variable (Harz mountains) or also rather uniform isotope ratios (Freiberg/Saxony; Southern Germany). Extreme variations within the deposit of Wiesloch near Heidelberg are interpreted as caused by bacterial fractionation of a limited amount of sulfate. - Fig. 6 shows lead isotope ratios from Southern Germany.

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Résumé La composition isotopique du soufre dans les minéraux des gîtes métallifères: données et problèmes pour une interprétation génétique.

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(Meggen, Rammelsberg, Freiberg, Wiesloch) . .

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Der Deutschen Forschungsgemeinschaft sei auch an dieser Stelle für die Ermöglichung der Schwefel-Isotopen-Messungen in Göttingen gedankt.     

Beobachtungen über das Phytoplankton klarer Hochgebirgsseen

Ohne Zusammenfassung     

Die Diabasvorkommen des Amazonasgebietes und das Problem des Intrusionsmechanismus

Zusammenfassung Unter Bezug auf die beobachteten großräumigen Diabasvorkommen im Gebiet des Amazonasbeckens wird der Versuch unternommen, den Intrusionsmechanismus basaltischer Schmelzen prinzipiell zu erklären. Es läßt sich zeigen, daß das Problem der Magmenbewegung von dem der Magmaentstehung nicht zu trennen ist. Beide bedürfen der Anwendung sowohl hydrostatischer als auch hydrodynamischer Gesetzmäßigkeiten.Die Beachtung der hydrostatischen Gesichtspunkte erfordert einerseits eine Herdlage in den oberen Teilen des Erdmantels, wo aber andererseits die Entstehung der Schmelze aus thermischen Gründen nicht ohne Konvektionsströmungen denkbar ist.Die Annahme eines konvektiven Zirkulationssystems im Mantel, dessen Auswirkung gelegentlich durch Schweremessungen beobachtbar sein können, beantwortet viele wichtige offene Fragen im Problemkreis des Intrusionsmechanismus basischer Gesteine.

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Basing on huge occurrence of diabase in the Amazon basin, a limited distribution of which is dealt with in this paper, an outline of the principal mechanism of intrusions of basaltic magma is attempted. Apparently, the problem of movement of magma is not allowed to be regarded without that of its origin. Both, movement and origin, are subjected to hydrostatical and hydrodynamical laws.The application of the hydrostatics demands the source of magma to be in the upper parts of the earth's mantle. In this location, however, temperature seems to be insufficient to originate melted basaltic rocks unless thermical convection takes place.The postulation of a vertical system of circulation in the mantle, the effects of which sometimes may be recognized by gravity measurements, solves some important problems of the mechanism of intrusion. In this way, among other things, the deep lying mass of higher density along the center of the Amazon basin may be determined as to triassic-jurassic age.

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Résumé Considérant la présence de diabases en grande quantité dans le bassin de l'Amazone, l'auteur tente d'interpréter dans son principe le mécanisme d'intrusion des liquides basaltiques. Il semble que le problème du mouvement du magma ne peut pas être séparé de celui de son origine. Tous deux doivent être soumis à des lois hydrostatiques et hydrodynamiques.La considération du point de vue hydrostatique donne à penser que la source du magma se trouve dans la partie supérieure du manteau terrestre où cependant, pour des raisons thermiques, on ne peut penser à la formation de liquides magmatiques sans courants de convection.L'hypothèse d'un système de circulation convective dans le manteau, dont les effets ont parfois été observés par des mesures de gravité, apporte une solution à quelques problèmes concernant le mécanisme d'intrusion. Dans cet ordre d'idées, la masse profonde de forte densité située dans le centre du bassin de l'Amazone peut être rapportée au Triasique-Jurassige.

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Die Veröffentlichung der vorliegenden Arbeit erfolgt mit freundlicher Genehmigung der Petróleo Brasileiro, S. A. (Petrobrás) sowie der Gesellschaft für praktische Lagerstättenforschung GmbH (Prakla). Beiden Gesellschaften sei dafür an dieser Stelle aufrichtig gedankt!     

Die Darstellung des geomagnetischen Potentials zur Epoche 1945,0 durch eine Entwicklung nach Kugelfunktionen bis zur 15. Ordnung

Zusammenfassung Es werden die Ergebnisse einer Berechnung des geomagnetischen Potentials in Form einer Reihenentwicklung nach Kugelfunktionen bis zur 15. Ordnung auf Grund der magnetischen Weltkarten für die Epoche 1945,0 vonE. H. Vestine und andern vorgelegt. Bei der Ableitung des Potentialausdrucks nach der Methode der kleinsten Quadrate wurden die Orthogonalitätseigenschaften der Kugelflächenfunktionen vollständig ausgenutzt.

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Summary The results of the analysis of the main geomagnetic field for the epoch 1945.0 in a series of spherical harmonics to the 15th degree are presented. The analysis is based on the world magnetic charts derived byVestine et al. The coefficients of the potential are calculated by least-squares approximation taking advantage of the orthogonality of the spherical harmonics over discrete ranges.

     

Rare gases and fossil particle tracks in the Kenna ureilite

Fossil particle tracks and spallation-produced He and Ne in the Kenna ureilite indicate that it existed in space as a small object for 23 m.y. In our study of Kenna, we found no evidence of trapped He or Ne. Large amounts of heavy rare gases occur in Kenna in concentrations typical of ureilites. In a step-wise release of gases, the isotopic compositions of Kr and Xe were found to be constant above 600°C, revealing the presence of a single retentively sited component. The Xe isotopic abundances are characterized by 124:126:128:129:130:131:132:134:136 = 0.471:0.414:8.280:103.61: 16.296:81.92:100:37.70:31.23. This isotopic composition is distinct from AVCC (average carbonaceous chondritic), but similar to compositions known for some time in certain temperature fractions of Renazzo, Murray and Murchison. Kenna-type Xe appears to be one of the several components found in carbonaceous chondrites.

Binz et al. (Geochim. Cosmochim. Acta 39, 1576–1579, 1975) have recently found that many volatile trace elements are strongly depleted in ureilites. Thus, the relatively large amounts of heavy rare gases present in ureilites did not result from a mixture of a volatile-rich component with the ureilite host. It appears that some material rich in carbon and heavy rare gases was incorporated into a differentiated ureilite host. All current hypotheses which purport to explain the origin of trapped gases in meteorites encounter difficulty in accounting for trapped gases in ureilites in a straightforward manner.