The Effect of Surface Heterogeneity on the Temperature–Humidity Correlation and the Relative Transport Efficiency

We derive a conceptual model of the flow over heterogeneous terrain consisting of patches with contrasting Bowen ratios. Upward moving eddies are assumed to carry heterogeneous properties, whereas downward moving eddies carry homogeneous properties. This results in a decorrelation of temperature and humidity as the contrast between the patches increases. We show that this model is able to reproduce the relationship developed by Lamaud and Irvine (Boundary-Layer Meteorol. 120:87–109, 2006). Some details differ from their expression but are in accordance with data obtained over African savannah. We extend the conceptual model to a combination of any scalars, not necessarily linked through the surface energy balance (as is the case for temperature and humidity). To this end we introduce a new parameter that describes the surface heterogeneity in surface fluxes. The results of the current model can be used to predict the discrepancy between similarity relationships for different scalars over heterogeneous terrain.     

Solar cosmic ray records in lunar rock 64455

Cosmic ray produced ¹⁰Be (half-life = 1.36 × 10⁶ yr), ²⁶Al (7.05 × 10⁵ yr), and ³⁶Cl (3.01 × 10⁵ yr) were measured in a depth profile of 19 carefully-ground samples from the glass-coated lunar surface rock 64455. The solar cosmic ray (SCR) produced ²⁶Al and ³⁶Cl in this rock are present in high concentrations, which in combination with the low observed erosion rate, <0.5 mm/Myr, provide well defined depth profiles characterizing the SCR component of the cosmic rays. In conjunction with new experimentally determined excitation functions, the ³⁶Cl concentrations suggest a softer solar-proton spectral shape than that derived from most previous measurements. The fact that no SCR-produced ¹⁰Be activity could be detected in 64455 is in good agreement with observations in 68815 and also indicates a softer SCR spectrum. Comparison of observed SCR profiles in 64455 with theoretical calculations indicates that the average solar-proton spectrum over the past 2 Myr (based on ²⁶Al) has an exponential rigidity parameter (R₀) of about 90 MV with a proton flux (J) of 73 protons/cm²/s·4π above 10 MeV. Over the last ∼0.5 Myr (based on ³⁶Cl) R₀ is about 70 MV with a flux of ∼196 protons/cm²/s·4π above 10 MeV. These SCR fluxes are consistent with most previous work.     

The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

Meereskundlich-chemische Untersuchungen mit Hilfe des Pulfrich-Photometers von Zeiss

Zusammenfassung Die bisherigen Methoden zur Bestimmung des Chlorophylls im Meerwasser benötigen zu ihrer Durchführung Wassermengen von einem bis zu einigen Litern. Sie sind infolgedessen zur Ausfühung serienmäßiger ozeanischer Messungen noch nicht voll geeignet. Durch Ausnutzung der intensiven Rotfluoreszenz des Chlorophylls und Benutzung kleinerer und engerer Kolorimeterröhren läßt es sich ermöglichen, den Wasserbedarf bis auf 100 ccm und weniger je Probe herabzudrücken und somit diesen Mangel zu beheben. Die für diesen Zweck geschaffene gleiche Arbeitsapparatur ermöglicht weiterhin, im Anschluß an die Chlorophyllbestimmung ohne wesentlich erhöhte Arbeitsbelastung die Bestimmung der Eigenfluoreszenz gleichfalls auf dem Wege der Mikromethodik an nur 1 ccm Meerwasser durchzuführen.

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Investigations in chemical oceanography carried out with the aid of the Pulfrich photometer

Summary The old method of determining the chlorophyll content of sea water required a comparatively great quantity of sea water (one or severel litres) and, hence, was not suitable in case of serial measurements. The utilization of the intensive red fluorescence of chlorophyll and the use of small and narrow colorimeter tubes render it possible to minimize the required quantity of water to 100 ccm and less per sample. The apparatus which was especially constructed for this purpose being fit for the determination of both the chlorophyll content and the proper fluorescence, the latter can be easily determined immediately after the determination of the chlorophyll content by means of the micro-method from only 1 ccm of sea water.

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Investigations chimiques dans le domaine océanographique à l'aide du photomètre de PulfrichVII^e communication. Les micro déterminations de la teneur en chlorophylle et de la fluorescence propre de l'eau de mer

Résumé La quantité minimale nécessaire pour déterminer la teneur en chlorophylle selon la méthode en usage jusqu' à présent se montait d'un à plusieurs litres; à cause de cela cette méthode n'était pas convenable pour des mensurations en séries. En se servant de l'intensive fluorescence rouge de la chlorophylle et en employant un petit tube étroit à colorimètre il est possible de limiter la quantité d'eau à 100 ccm et moins par échantillon. En outre, on peut se servir du même appareil pour déterminer la fluorescence propre selon la nouvelle méthode. Pour cette détermination qui peut être effectué sans peine immédiatement après celle de la chlorophylle on a besoin de seulement 1 ccm d'eau de mer.

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Die sechs vorhergehenden Mitteilungen sind in den Annalen der Hydrographie und maritimen Meteorologie erschienen, und zwar I:59, 1931, 313; II:61, 1933, 124; III:62, 1934, 65; IV:63, 1935, 58: V:63, 1935, 195; VI:65, 1937, 276.     

Polarimetric NIR reflectance measurements of regolith simulants at zero phase angle

Polarimetric reflectance measurements have been made at a wavelength of for a suite of predominantly lunar regolith simulants in support of development efforts for the BepiColombo Laser Altimeter (BELA). Measurements were made using an instrument at the University of Bern, Switzerland, that has been modified to accommodate photometric characterizations of laboratory samples down to 0^° phase angle (g) with linearly polarized illumination and a linearly polarized receiver. The data reveal opposition surges that are dominated by polarization state-conserving reflectance terms for all samples. Relative strengths of the trans-state reflectance terms are lowest for the darkest samples, suggesting that multiple scattering is responsible for state conversions. Normal albedo measurements of the lunar simulants range from 0.13 to 0.22 at zero illumination angle (i=0^°). The total reflectance of the regolith simulants at g=0^° were found to decrease with increasing i, which is inconsistent with predictions of reflectance models for Mercury. However, the g=0^° reflectance remains higher at i>0^° than would be expected for a gray Lambert surface that is scaled to the g=i=0^° reflectance value. Polarization ratios for reflectance under polarized illumination but unconstrained emission show that the samples scatter light in the in-plane polarization state more efficiently than in the transverse state at g=0^° and i>0^°. The opposite is true for g>0^° polarization ratios, which indicate that transverse polarized illumination scatters more efficiently at high g. The polarization effect appears to correlate with the sample's characteristic grain size, but the statistical basis of this trend is weak. The implications of these measurements upon the performance of the BELA instrument are discussed.     

Graph theory for analyzing pair-wise data: application to geophysical model parameters estimated from interferometric synthetic aperture radar data at Okmok volcano,Alaska

Graph theory is useful for analyzing time-dependent model parameters estimated from interferometric synthetic aperture radar (InSAR) data in the temporal domain. Plotting acquisition dates (epochs) as vertices and pair-wise interferometric combinations as edges defines an incidence graph. The edge-vertex incidence matrix and the normalized edge Laplacian matrix are factors in the covariance matrix for the pair-wise data. Using empirical measures of residual scatter in the pair-wise observations, we estimate the relative variance at each epoch by inverting the covariance of the pair-wise data. We evaluate the rank deficiency of the corresponding least-squares problem via the edge-vertex incidence matrix. We implement our method in a MATLAB software package called GraphTreeTA available on GitHub (https://github.com/feigl/gipht). We apply temporal adjustment to the data set described in Lu et al. (Geophys Res Solid Earth 110, 2005) at Okmok volcano, Alaska, which erupted most recently in 1997 and 2008. The data set contains 44 differential volumetric changes and uncertainties estimated from interferograms between 1997 and 2004. Estimates show that approximately half of the magma volume lost during the 1997 eruption was recovered by the summer of 2003. Between June 2002 and September 2003, the estimated rate of volumetric increase is \((6.2 \, \pm \, 0.6) \times 10^6~\mathrm{m}^3/\mathrm{year} \). Our preferred model provides a reasonable fit that is compatible with viscoelastic relaxation in the five years following the 1997 eruption. Although we demonstrate the approach using volumetric rates of change, our formulation in terms of incidence graphs applies to any quantity derived from pair-wise differences, such as range change, range gradient, or atmospheric delay.     

Die wirkliche Solarkonstante

Zusammenfassung Die Solarkonstante 2.4 wird begründet.

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Summary The true solar constant 2.4 is proved.

     

Erwiderung zu dem Aufsatz von Dr. Georgi: Das neue Absolut-Pyrheliometer von Prof. K. Wegener

Ohne Zusammenfassung