Derivation of Structure Parameters of Temperature and Humidity in the Convective Boundary Layer from Large-Eddy Simulations and Implications for the Interpretation of Scintillometer Observations

We derive the turbulent structure parameters of temperature $C_{T}^2$ and humidity $C_q^2$ from high-resolution large-eddy simulations (LES) of a homogeneously-heated convective boundary layer. Boundary conditions and model forcing were derived from measurements at Cabauw in The Netherlands. Three different methods to obtain the structure-parameters from LES are investigated. The shape of the vertical structure-parameter profiles from all three methods compare well with former experimental and LES results. Depending on the method, deviations in the magnitude up to a factor of two are found and traced back to the effects of discretization and numerical dissipation of the advection scheme. Furthermore, we validate the LES data with airborne and large-aperture scintillometer (LAS) measurements at Cabauw. Virtual path measurements are used to study the variability of $C_{T}^2$ in the mixed layer and surface layer and its implications for airborne and LAS measurements. A high variability of $C_{T}^2$ along a given horizontal path in the LES data is associated with plumes (high values) and downdrafts (low values). The path average of $C_{T}^2$ varies rapidly in time due to the limited path length. The LES results suggest that measured path averages require sufficient temporal averaging and an adequate ratio of path length to height above the ground for the LAS in order to approach the domain average of $C_{T}^2$ .     

The last Scandinavian Ice Sheet in northwestern Russia: ice flow patterns and decay dynamics

Advance of the Late Weichselian (Valdaian) Scandinavian Ice Sheet (SIS) in northwestern Russia took place after a period of periglacial conditions. Till of the last SIS, Bobrovo till, overlies glacial deposits from the previous Barents and Kara Sea ice sheets and marine deposits of the Last Interglacial. The till is identified by its contents of Scandinavian erratics and it has directional properties of westerly provenance. Above the deglaciation sediments, and extra marginally, it is replaced by glaciofluvial and glaciolacustrine deposits. At its maximum extent, the last SIS was more restricted in Russia than previously outlined and the time of termination at 18-16 cal. kyr BP was almost 10 kyr delayed compared to the southwestern part of the ice sheet. We argue that the lithology of the ice sheets' substrate, and especially the location of former proglacial lake basins, influenced the dynamics of the ice sheet and guided the direction of flow. We advocate that, while reaching the maximum extent, lobe-shaped glaciers protruded eastward from SIS and moved along the path of water-filled lowland basins. Ice-sheet collapse and deglaciation in the region commenced when ice lobes were detached from the main ice sheet. During the Lateglacial warming, disintegration and melting took place in a 200-600 km wide zone along the northeastern rim of SIS associated with thick Quaternary accumulations. Deglaciation occurred through aerial downwasting within large fields of dead ice developed during successively detached ice lobes. Deglaciation led to the development of hummocky moraine landscapes with scattered periglacial and ice-dammed lakes, while a sub-arctic flora invaded the region.     

First composition measurements of positive ions in the upper troposphere

First mass-spectrometric composition measurements of atmospheric ions between 3250 and 11700 m altitude are reported. They reveal the presence of very massive cluster ions, the majority of which cannot be attributed to a single hydrated ion family like, for example H⁺(H₂O)_n. The observed fraction of very massive ions increases with decreasing altitude. Masses as large as about 540 amu were observed at 8200 m altitude. Implications of the observations for ion and nucleation processes are discussed.     

Silicon negative ion chemistry in the atmosphere-in situ and laboratory measurements

The results of a rocket-borne mass spectrometer measurement indicate that large concentrations of negative ions exist above the bottom of the atmospheric atomic oxygen layer. A large majority of these ions have a mass greater than 100 amu. In addition, an ion at mass 76 was observed with concentrations too large to be CO₄^?. In order to explain these features, a number of reactions involving silicon oxide negative ions have been measured in a flowing afterglow system. The ion SiO₃^? is produced by reaction of O₃^?, and CO₃^?, with SiO. The SiO₃^? ion is extremely stable and does not react measurably with NO, NO₂, CO, CO₂, O₃ or O. Since meteoroid ablation produces a large silicon input into the atmosphere, it appears possible that the ions observed at mass 76 may be SiO₃^?. Possible production mechanisms for this ion as well as the heavy ions are discussed.     

The Earth's rotation and atmospheric circulation, from 1963 to 1973

Summary. The zonal angular momentum of the atmospheric circulation has been evaluated month-by-month and compared with astronomical observations of the length-of-day for the 10 years from 1963 May to 1973 April. The reason for undertaking this study is to enable the astronomical observations to be 'corrected' for the zonal wind effect and to investigate the residual excitation function for solid-Earth contributions. The principal conclusions reached are the following: (i) The annual change in length-of-day is almost entirely due to the seasonal changes in the zonal circulation with tidal, oceanographic and hydrologic phenomena contributing together at most 10 per cent of the total excitation, (ii) The semi-annual term is predominantly due to the zonal wind and the body tide, with oceanic and hydrologic terms contributing about 10 per cent, (iii) The atmospheric circulation plays a dominant role in length-of-day changes in the period range from 1 to about 4 yr. This is partly associated with the quasi-biennial oscillation and its harmonics. Both the period and amplitude of these fluctuations are very variable, (iv) At longer periods the atmosphere may still contribute to the total excitation but other excitation functions begin to rise above the spectrum of the meteorological excitation, (v) At periods less than about 1 yr the atmospheric excitation is dominant, and while the presence of other excitation functions cannot be excluded, they cannot exceed 20 per cent of the wind excitation. On the basis of these results the astronomical record from 1962 to 1978 has been 'corrected' for the meteorological 'noise'. The residual excitation exhibits only fluctuations on a time-scale of about 5 yr and longer and it is this result that must be attributed to core-mantle interactions or to other solid-Earth excitation functions.