Geochronology of the Xihuashan Tungsten Deposit in Southeastern China: Constraints from Re–Os and U–Pb Dating

Xihuashan tungsten deposit is one of the earliest explored tungsten deposits in southeastern China. It is a vein type deposit genetically associated with the Xihuashan granite pluton. Here we report new dating and zircon geochemistry results. Re–Os isotopic dating for molybdenite intergrowth with wolframite in the oldest generation of the Xihuashan pluton yielded an isochron age of 157.0 ± 2.5 Ma (2σ). Zircon U–Pb laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) dating shows that the pluton crystallized at 155.7 ± 2.2 Ma (2σ). This age is similar to the molybdenite Re–Os age for the ore deposit within error. This, together with published data, suggests that the major W(Mo)‐Sn mineralization occurred between 160–150 Ma in southeastern China. These deposits constitute a major part of the magmatic‐metallogenic belt of eastern Nanlin. The lower Re content in molybdenite of the Xihuashan tungsten deposit shows crustal origin for the ore‐forming material. The limited direct contributions from the subducting slab for the tungsten mineralization in the Nanling region suggest a change of the style of the paleo‐Pacific plate beneath southeastern China.     

Virtual wave gauges based upon stereo imaging for measuring surface wave characteristics

A virtual wave gauge (VWG) technique based on stereo imaging is developed to remotely measure water wave height, period, and direction. VWG minimizes computational costs by directly tracking the elevation of the water surface at selected points of interest using a Eulerian based dynamic searching algorithm. Results show that the VWG technique developed in this paper dramatically improves efficiency by two orders of magnitude compared to the traditional Lagrangian–Eulerian based point cloud method of stereo image processing. VWG is tested against traditional wave wire gauges to within 98% accuracy for significant wave height. Furthermore, the flexibility of the VWG is demonstrated in two field applications. First in an offshore breaking wave case, an array of VWGs is used to efficiently measure wave directionality. Second to investigate the reflection coefficient of a rock-mounted structure interacting with nearshore waves, linear and spatial VWG arrays are designed and implemented based on a priori information of the wave field from a preliminary VWG measurement. Overall, we demonstrate that the flexible and computational efficient VWG technique has the potential to make real-time remote stereo imaging wave measurements a reality.     

Appraisal of storm beach buffer width for cyclonic waves

The loss of beach sand from berm and dune due to high waves and surge is a universal phenomenon associated with sporadic storm activities. To protect the development in a coastal hazard zone, hard structures or coastal setback have been established in many countries around the world. In this paper, the requirement of a storm beach buffer, being a lesser extent landward comparing with the coastal setback to ensure the safety of infrastructures, is numerically assessed using the SBEACH model for three categories of wave conditions in terms of storm return period, median sand grain size, berm width, and design water level. Two of the key outputs from the numerical calculations, berm retreat and bar formation offshore, are then analysed, as well as beach profile change. After having performed a series of numerical studies on selected large wave tank (LWT) test results with monochromatic waves using SBEACH, we may conclude that: (1) Berm erosion increases and submerged bar develops further offshore as the storm return period increases for beach with a specific sand grain size, or as the sand grain reduces on a beach under the action of identical wave condition; (2) Higher storm waves yield a large bar to form quicker and subsequently cause wave breaking on the bar crest, which can reduce the wave energy and limit the extent of the eroding berm; (3) A larger buffer width is required for a beach comprising small sand grain, in order to effectively absorb storm wave energy; and (4) Empirical relationships can be tentatively proposed to estimate the storm beach buffer width, from the input of wave conditions and sediment grain size. These results would benefit a beach nourishment project for shore protection or design of a recreational beach.     

The domestic divide: Access to the Internet in New Zealand

We use unit records of the 2006 census to show that access to the Internet in the home varies geographically in New Zealand primarily as a result of demographic and socio‐economic differences among individuals. Of particular significance is the much lower rates of domestic access experienced by Māori and Pacific Island individuals even after controlling for differences in their age, gender, education, income, occupation and settlement type. While differences in Internet access by ethnicity has been noted before, it is the magnitude and persistence of this difference in New Zealand after controlling for correlated factors that renders this study unique. Our results have important implications in an education environment increasingly reliant on Web access, but they also raise questions about the extent of access to the Internet outside the home.     

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.     

Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).     

An empirical model of subcritical bedform migration

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.