Interannual salinity variations in the Tsushima Strait and its relation to the Changjiang discharge

Interannual salinity variations in the Tsushima Strait are investigated on the basis of historical hydrographic data. The EOF analysis revealed that the most dominant mode is the in-phase salinity variation between the eastern and western channels. The time coefficients of the EOF first mode in summer show a negative correlation with the Changjiang discharge, which indicates that salinity in the Tsushima Strait tends to decrease over summer, related to a large discharge of the Changjiang. The eigenvectors of the first mode are larger in the eastern channel than those in the western channel, though the low salinity water mainly flows through the western channel. This is because the low salinity water spreads into the eastern channel as well as the western channel over summers with a large discharge of the Changjiang. The out-of-phase salinity variation between the channels is extracted as the EOF second mode; this is the predominant variation in the western channel. The time coefficients of the second mode in summer show no significant correlations to the volume transports through the western channel and the transport differences between channels. A relationship between the EOF second mode and variations in the wind stress over the East China Sea is suggested.     

Synthesis of γ-Mg2SiO4

Magnesium orthosilicate with spinel structure (γ-Mg₂SiO₄) was synthesized at about 250 kbar and 1000°C. Unit cell dimension was established to be 8.076 ± 0.001Å. X-ray powder diffraction pattern revealed a significant difference between γ-Mg₂SiO₄ and other γ-M₂SiO₄ spinels (M = Fe, Co, and Ni) in the intensities of (111) and (331) reflections, both of which are virtually absent in the Mg₂SiO₄ spinel. This feature could be thoroughly understood by the calculation of the intensities for several silicate spinels.     

Subhorizontal tectonic framework of the Horoman peridotite complex and enveloping crustal rocks,south‐central Hokkaido,Japan

Geological observations in the Horoman area, south‐central Hokkaido, show that the Horoman peridotite complex of the Hidaka metamorphic belt is a tectonic slice about 1200 m thick. The peridotite slab is intercalated into a gently east‐dipping structure. The underlying unit is a Cretaceous–Paleogene accretionary complex. Riedel shear planes in the sedimentary layers of the accretionary complex near the structural bottom of the peridotite slab indicate top‐to‐the‐west (thrust) displacement. The overlying unit is composed of felsic–pelitic gneisses and mafic–felsic intrusive rocks (the Hidaka metamorphic rocks). The boundary surface between the peridotite complex and metamorphic rocks forms a domal structure. Microstructures of sheared metamorphic rocks near the structural top of the peridotite slab indicate top‐to‐the‐east (normal) displacement. The results combined with previous studies suggest that the Horoman peridotite complex was emplaced onto the Asian margin (Northeast Japan) during the collision between the Asian margin and the Hidaka crustal block.     

Computational model of the structural and elastic properties of the ilmenite and perovskite phases of MgSiO3

The structural and elastic properties of the ilmenite and perovskite phases of MgSiO₃ are investigated with a computational model based on energy minimization. The potential energies of these two crystals are approximated by the sum of Coulomb, van der Waals, and repulsion terms between atoms. Required energy parameters are derived by fitting the parameters to the observed crystal structures of these two phases as well as to the measured elastic constants of the ilmenite phase. The resulting potential model is applied to predicting the elastic constants of the perovskite phase. The calculated bulk modulus of the perovskite phase compares favorably with the data obtained from volume-compression experiments as well as the values estimated from empirical elasticity systematics of perovskite type compounds. The predicted shear modulus of the perovskite phase is also in reasonable agreement with the values proposed from similar empirical elasticity systematics. Subsequently, the model is used to simulate the high pressure behaviors of the crystal structures and elastic constants of these two phases.     

High-temperature Raman spectroscopy and quasi-harmonic lattice dynamic simulation of diopside

We investigated the lattice vibrational properties and lattice dynamical behaviour of diopside by combining laser micro-Raman spectroscopic measurements with quasi-harmonic lattice dynamic simulation using a transferable interatomic potential. We obtained polarized Raman spectra from a Fe-poor natural diopside and the temperature dependencies of the Raman modes to 1125?K from high-temperature Raman spectra of a Fe-poor and a Fe-rich natural diopside. The various modes display different temperature dependencies: from ?0.021?cm^?1/K to ?0.004?cm^?1/K. The temperature shift of low frequency modes is generally higher. A comparison of experimentally determined frequencies and symmetries of vibrational modes of the optical type (Raman and infrared) obtained in this and earlier studies with those calculated by us suggests that a consistent characterization of the vibrational properties was achieved. The good agreement between the experimental and simulated data on the temperature-dpendencies of the Raman modes (within 5%), crystal structure (2%), bulk modulus (5%), volume thermal expansivity (6%), and constant volume heat capacity (0.2%) testifies to the applicability of the transferable interatomic potential and the lattice dynamic model to predicting the vibrational, physical, and thermodynamic properties. The simulated properties from the lattice dynamic calculations are very similar to those obtained by molecular dynamic calculations with the same potential model.     

Thermal expansion of single-crystal forsterite to 1023 K by Fizeau interferometry

Using a Fizeau interferometry technique, we have measured the coefficients of linear thermal expansion of single-crystal forsterite (Mg₂SiO₄) along three axial directions to 1023 K during heating and cooling cycles. Overall, the present data are consistent in magnitude (within 1 to 2%) with those previously reported but have less scatter. We used the Grüneisen statistical mechanical approach in analzying the data. The least-squares method was applied to evaluate thermal parameters (?, Q ₀, k and a) in two cases. The expansion coefficients in wider temperature ranges were extrapolated by using the parameters of solution 2 (i.e., solution by fixing ? and k). In contrast to earlier findings, our results show that for forsterite the Grüneisen parameter decreases with temperature, implying that it does not behave too differently from fayalite (Fe₂SiO₄) and periclase (MgO).     

Periodic response of a rigid block resting on a footing subjected to harmonic excitation

This study presents the dynamic behaviour of a rigid block which rests on a footing supported by a spring and a dashpot on a rigid base. The response of the rigid body is examined carefully when the base is excited by a harmonic force. It is found that a periodic motion appears in three different modes: stick-stick, stick-slip and slip-slip. The conditions that initiate the stick-stick and slip-slip modes are derived in explicit forms and the maximum sliding displacement is also obtained analytically. Useful dimensionless parameters are proposed for the presentation of the dynamic behaviour. The accuracy of results is confirmed by the response history computed by the Nigam-Jennings method.     

Experimental and Numerical Investigations of Ground Deformation Using Chemical Grouting for Pipeline Foundation

Based on experimental and numerical investigations, the present paper focuses on under ground scope (UGS) chemical grouting method that can actually improve the pipeline surrounding foundation to solve pipeline saggy damage. According to the experimental results, a solution-type injection material could make lager soil deformation, using less total slurry amount than suspension-type injection material. Therefore, a suspension-type injection material with shorter gel time is more suitable for the UGS method, making it more effective to reinforce the pipeline foundation and restore pipelines. The results of some patterns of injection tests revealed relationship between the behavior of the grouting material and the deformation of the soil. It is found that the material can be injected into a foundation by fracture grouting if the permeation coefficient is lower than 1.00 × 10⁻³ mm/s. The situation was analyzed by using 2-D finite element method analysis software Phase2, and the analysis result proposes that the real data and simulation data are nearly the same in impermeable soil. Furthermore, even if the construction object is permeable soil, it can also be become impermeable soil by two phases grouting: soil improvement grouting and restoration grouting.     

Molecular dynamics study of the crystal structure and phase relation of the GeO2 polymorphs

A two-body interatomic potential model for GeO₂ polymorphs has been determined to simulate the structure change of them by semi-empirical procedure, total lattice energy minimization of GeO₂ polymorphs. Based on this potential, two polymorphs of GeO₂; α-quartz-type and rutile-type, have been reproduced using the molecular dynamics (MD) simulation techniques. Crystal structures, bulk moduli, volume thermal expansion coefficients and enthalpies of these polymorphs of GeO₂ were simulated. In spite of the simple form of the potential, these simulated structural values, bulk moduli and thermal expansivities are in excellent agreement with the reliable experimental data in respect to both polymorphs. Using this potential, MD simulation was further used to study the structural changes of GeO₂ under high pressure. We have investigated the pressure-induced amorphization. As reported in previous experimental studies, quartz-type GeO₂ undergoes pressure-induced crystalline-to-amorphous transformation at room temperature, the same as other quartz compounds; SiO₂, AlPO₄. Under hydrostatic compression, in this study, α-quartz-type GeO₂ transformed to a denser amorphous state at 7.4 GPa with change of the packing of oxygen ions and increase of germanium coordination. At higher pressure still, rutile-type GeO₂ transformed to a new phase of CaCl₂-type structure as a post-rutile candidate. Received: 29 July 1996 / Revised, accepted: 30 April 1997