A threshold in soil formation at Earth’s arid-hyperarid transition

The soils of the Atacama Desert in northern Chile have long been known to contain large quantities of unusual salts, yet the processes that form these soils are not yet fully understood. We examined the morphology and geochemistry of soils on post-Miocene fans and stream terraces along a south-to-north (27° to 24° S) rainfall transect that spans the arid to hyperarid transition (21 to ∼2 mm rain y⁻¹). Landform ages are ? 2 My based on cosmogenic radionuclide concentrations in surface boulders, and Ar isotopes in interbedded volcanic ash deposits near the driest site indicate a maximum age of 2.1 My. A chemical mass balance analysis that explicitly accounts for atmospheric additions was used to quantify net changes in mass and volume as a function of rainfall. In the arid (21 mm rain y⁻¹) soil, total mass loss to weathering of silicate alluvium and dust (−1030 kg m⁻²) is offset by net addition of salts (+170 kg m⁻²). The most hyperarid soil has accumulated 830 kg m⁻² of atmospheric salts (including 260 kg sulfate m⁻² and 90 kg chloride m⁻²), resulting in unusually high volumetric expansion (120%) for a soil of this age. The composition of both airborne particles and atmospheric deposition in passive traps indicates that the geochemistry of the driest soil reflects accumulated atmospheric influxes coupled with limited in-soil chemical transformation and loss. Long-term rates of atmospheric solute addition were derived from the ion inventories in the driest soil, divided by the landform age, and compared to measured contemporary rates. With decreasing rainfall, the soil salt inventories increase, and the retained salts are both more soluble and present at shallower depths. All soils generally exhibit vertical variation in their chemistry, suggesting slow and stochastic downward water movement, and greater climate variability over the past 2 My than is reflected in recent (∼100 y) rainfall averages. The geochemistry of these soils shows that the transition from arid to hyperarid rainfall levels marks a fundamental geochemical threshold: in wetter soils, the rate and character of chemical weathering results in net mass loss and associated volumetric collapse after 10⁵ to 10⁶ years, while continuous accumulation of atmospheric solutes in hyperarid soils over similar timescales results in dramatic volumetric expansion. The specific geochemistry of hyperarid soils is a function of atmospheric sources, and is expected to vary accordingly at other hyperarid sites. This work identifies key processes in hyperarid soil formation that are likely to be independent of location, and suggests that analogous processes may occur on Mars.     

1200a来洪湖演变的环境磁学记录

对取自洪湖的 140cm沉积物样芯进行了环境磁学测量,分析了所获得的环境磁学参数随深度变化的曲线,结果表明,沉积物磁性特征由稳定单畴(SSD)和细粘滞性 (FV)亚铁磁性矿物所主导,磁性矿物颗粒由下至上粒径逐渐减小。结合AMS测年和地球化学分析,可以推断出洪湖在 1200a来经历了沼泽沉积和湖相沉积。并且磁性特征的变化与气候的变化大致对应:磁性参数较大值对应着冷干的气候条件;水热条件增强时,磁性参数值下降。较好记录了湖泊随气候的扩张和缩小过程,同时也反映了人类活动的影响。     

Mineralogy and geochemistry of the Au-Ag ore deposits of the South Korean Peninsula

Pyrite and arsenopyrite are the predominant ore minerals in the Korean Au-Ag deposits of this study. The X _Ni ^py , X _Co ^py , X _Ni ^apy , and X _Co ^apy values range between 100 and 3,000 ppm, 200 and 6,000 ppm, 200 and 8,200 ppm, and 100 and 10,200 ppm, respectively. Most X _Ni ^py /X _Co ^py values fall in the field lower than values varying 0.16–1.30. Arsenopyrite also tends to prefer cobalt rather than nickel showing X _Ni ^apy /X _Co ^apy values between 0.20 and 1.40. The concentrations of minor elements in ores and gangue minerals vary 1–55 ppm Au and 1–1,120 ppm Ag for the former and 4–57 ppm Ni and 2–45 ppm Co for the latter. The Au/Ag ratio in ore has a good correlation to the Ni/Co ratio of arsenopyrite to gangue. The (Ni/Co)_py-(Ni/Co)_gangue and (Ni/Co)_apy-(Ni/Co)_gangue diagrams revealed that the values from the Korean Au-Ag deposits plot in the field lower than 900 °C which is the lowermost temperature determined by previous partitioning experiments.     

Late quaternary uplift in eastern Indonesia

Radiocarbon dates of fifteen samples representing raised shorelines on various islands of the tectonically mobile region of eastern Indonesia suggest rates of tectonic uplift ranging up to 12.5 mm/year. Low rates of 0.35–1.2 mm/year are from Biak Island and are averages for the last 31,000–36,000 years. The low rates may be explained to indicate subsidence alternating with uplift, both of which occurring under influence of the large Irian fault zone that passes to the immediate south of the island. Very young elevated strandlines (250 years BP) indicate rates of uplift between 8 and 12.5 mm/year which seem to demonstrate the episodic character of vertical diastrophic movements. Intermediate rates of uplift are in the order of 5 mm/year and may represent averages for eastern Indonesia.     

Biomass estimation of Sonneratia caseolaris (l.) Engler at a coastal area of Hai Phong city (Vietnam) using ALOS-2 PALSAR imagery and GIS-based multi-layer perceptron neural networks

This study tested the use of machine learning techniques for the estimation of above-ground biomass (AGB) of Sonneratia caseolaris in a coastal area of Hai Phong city, Vietnam. We employed a GIS database and multi-layer perceptron neural networks (MLPNN) to build and verify an AGB model, drawing upon data from a survey of 1508 mangrove trees in 18 sampling plots and ALOS-2 PALSAR imagery. We assessed the model’s performance using root-mean-square error, mean absolute error, coefficient of determination (R²), and leave-one-out cross-validation. We also compared the model’s usability with four machine learning techniques: support vector regression, radial basis function neural networks, Gaussian process, and random forest. The MLPNN model performed well and outperformed the machine learning techniques. The MLPNN model-estimated AGB ranged between 2.78 and 298.95 Mg ha^?1 (average = 55.8 Mg ha^?1); below-ground biomass ranged between 4.06 and 436.47 Mg ha^?1 (average = 81.47 Mg ha^?1), and total carbon stock ranged between 3.22 and 345.65 Mg C ha^?1 (average = 64.52 Mg C ha^?1). We conclude that ALOS-2 PALSAR data can be accurately used with MLPNN models for estimating mangrove forest biomass in tropical areas.     

Seismicity changes related to a water injection experiment in the Nojima Fault Zone

Abstract A water injection experiment was carried out by the scientific drilling program named the 'Nojima Fault Zone Probe' during the two periods 9–13 February and 16–25 March 1997. The pumping pressure at the surface was approximately 4 MPa. The total amount of injected water was 258 m³. The injection was made between depths of 1480 m and 1670 m in the Disaster Prevention Research Institute, Kyoto University (DPRI) 1800 m borehole drilled into the Nojima Fault zone. A seismic observation network was deployed to monitor seismic activity related to the water injections. Seismicity suddenly increased in the region not far from the injection hole 4 or 5 days after the beginning of each water injection. These earthquakes were likely to be induced by the water injections. Most of the earthquakes had magnitudes ranging from −2 to +1. Numerous earthquakes occurred during the first injection, but only one could be reliably located and it was approximately 2 km north of the injection site. Between the two injection periods, earthquakes concentrated in the region approximately 1 km northwest of the injection site. During and after the second injection experiment, earthquakes were located approximately 1.5 km west of the injection site. Those earthquakes were located approximately 3 km or 4 km from the injection point and between 2 km and 4 km in depth. Values of intrinsic permeability of 10⁻¹⁴–10⁻¹⁵ m² were estimated from the time lapse of the induced seismic activity. The coefficient of friction in the area where the induced earthquakes occurred was estimated to be less than 0.3.     

Oxygen isotope study of the Kamioka Zn-Pb skarn deposits,Central Japan

The Kamioka Zn-Pb deposits consist of clinopyroxene-rich skarns replacing limestone lenses in Hida gneissose rocks. Paleozoic metabasite, early Jurassic Funatsu granitic rocks and late Cretaceous porphyritic dikes and stocks, are the known igneous rocks in the mining area. Oxygen isotopic compositions of eight separates each of clinopyroxene and quartz from the deposits (Table 1), and some minerals and rocks from the major rock units around the deposits (Table 2), have been analyzed. The estimated oxygen isotopic ratios of the fluids responsible for the formation of the deposits, range as low as -4 to +3 (SMOW). These values are considerably lower than expected from magmatic waters, and demonstrate that none of the igneous rocks in the area could be a direct source of the skarn- and ore-forming fluids. The data instead show that the deposits are formed by a huge convective circulation of solutions of meteoric water origin, promoted by a hidden batholithic intrusion at the time of the late Cretaceous.     

Carbon storage in desertified lands: A case study from North China

Based on the organic and carbonate carbon levels of the top 1 m of soil from desertified soils of Northern People's Republic of China, climatic and vegetative cover zones have been derived for some 334000 km² of desertification-prone lands. Regional accumulations of pedogenic carbonates were examined relative to precipitation, altitude, and temperature. The largest accumulations of pedogenic carbonates were found in Calcic soils in warm, arid areas. Accumulated organic carbon predominated in soils under Betula platyphylla. In the naturally desertified lands of China, for example, the top 1.0-m soil layer contains some 7.84 Pg of organic carbon and 14.9 Pg of carbonate carbon. Total stored carbon, including carbonate carbon, is 1.8-fold more than organic carbon alone. The carbon released through land desertification in China may be an important factor affecting changes in concentrations of greenhouse gases worldwide.     

Sulfur Isotope Study on Hg and Sb Deposits in Japan

Abstract. Sulfur isotope ratios of cinnabar from Hg deposits and stibnite, jamesonite and berthierite from Sb deposits in Japan are examined in order to understand metallogeneses of Hg and Sb deposits in Japanese island arcs. The studied Hg and Sb deposits include the Hg deposit at Yamato‐suigin (Honshu) and the Sb deposit at Ichinokawa (Shikoku) in the Southwest Japan arc. In addition, Hg deposits including Itomuka and Ryushoden in central Hokkaido and Hg and Sb mineralizations in Northeast Japan arc are examined. The δ³⁴S values of cinnabar from the Hidaka‐Kitami district, central Hokkaido, including the Itomuka and Ryushoden deposits range widely, from ‐10 to +16 %o, the highest values encountered at the Samani deposit. The δ³⁴S values of cinnabar from other areas in Japan range from ‐12 to +5 %o, having δ³⁴S values higher than +2 %o from southwestern Hokkaido (Meiji deposit), Shikoku (Suii deposit) and Kyushu (Hasami and Yamagano deposits). On the other hand, the δ³⁴S values of stibnite from all areas in Japan range from ‐14 to +5 %o, having positive δ³⁴S values higher than +2 %o up to +5 %o from southwestern Hokkaido (Yakumo, Toyotomi and Teine deposits) and eastern‐central Honshu (Hachiman and Daikoku deposits). The variation in δ³⁴S values of Hg and Sb deposits may reflect the variation in δ³⁴S values of country rocks or variation in mixing ratio of sulfur extracted from the country rocks, sulfur derived from seawater sulfate, and sulfur derived from magmatic emanations. The relatively high δ³⁴S values of cinnabar and stibnite higher than +2 %o from southwestern Hokkaido, eastern‐central Honshu and Kyushu are probably caused by contribution of volcanic emanation from arc magmas having positive σδ³⁴S values, whereas the positive δ³⁴S values of cinnabar higher than +2 %o from Suii deposit in Shikoku may be attributed to structurally substituted sulfate in limestone country rocks and/or sulfur derived from seawater sulfate. However, the wide range of the δ³⁴S values of cinnabar from the Hidaka‐Kitami district, central Hokkaido, is difficult to explain at this moment. Other relatively low, negative δ³⁴S values of cinnabar and stibnite, berthierite from other areas in Japan may be attributed to 1) incorporation of isotopically light sedimentary sulfur or sulfur derived from ilmenite‐series silicic magma, or 2) less contribution of volcanic emanation from arc magmas having positive σδ³⁴S values.     

Intra-plate seismicity gap along the Median Tectonic Line and oblique plate convergence in southwest Japan

The intra-plate seismicity map for southwest Japan, based on fairly complete historical data for the past four hundred years, reveals an inverse correlation between the seismic activity along the island arc and the slip-rate along the Median Tectonic Line during the Late Quaternary. In the eastern part, the tectonic line is geologically inactive but regional historic seismicity has been high. The intra-plate seismic activity is probably related with the well developed mosaic-like conjugate system of strike-slip faults there. Conversely, the historic seismicity has been low in the western part, especially low in an area along the most geologically active segment of the Median Tectonic Line. Since no creep movement has been found there, energy greater than that of the Mino-Owari earthquake of 1891 (M = 8.0) seems to be stored in this seismicity gap. The difference in seismic released energy between the two regions for the last four hundred years would be balanced by the strain energy accumulated in the seismic gap. The fairly uniform strain release is conformable to the idea, proposed on the basis of the trend of maximum compression axes, that the Philippine Sea plate is dragging southwest Japan southwestward along the Nankai trough.