Hydroxy acids in Antarctic lake sediments and their geochemical significance

Hydroxy acids in sediments of Lakes Bonney, Fryxell, Joyce and Vanda, and unnamed ponds (B2, NF1, NF2 and L4) as well as in cyanobacterial mats from the McMurdo Sound region of southern Victoria Land in Antarctica have been studied to clarify their features and elucidate their source organisms. Normal and branched (iso and anteiso) 2-hydroxy acids were found in all the samples studied with the predominance of even- and odd-carbon numbers, respectively. The most dominant 2-hydroxy acids in the sediments were mainly short-chain components (<C₂₀). Normal and branched 3-hydroxy acids were detectewith the predominance of even- and odd-carbon numbers, respectively, in total concentrations between 0.48 and 53 μg/g of dry sediment. (ω-1)-Hydroxy acids were all long-chains (C₂₂, C₂₄, C₂₆, C₂₈ and C₃₀). 9,10-Dihydroxyhexadecanoic and/or 9,10-dihydroxyoctadecanoic acids were identified in all the sediments and a cyanobacterial mat. The composition of hydroxy acids differ considerably among the lakes and ponds, suggesting the difference of source organisms. These 2-, 3- and (ω-1)-hydroxy, and 9,10-dihydroxy acids may be derived from cyanobacteria and microalgae, in addition to non-photosynthetic microorganisms. Cyanobacteria and microalgae which are widely distributed in the world, may be important sources of hydroxy acids in the natural environments.     

琵琶湖中浊度的季节变化

Seasonal variation of the turbidity (suspended substance) has been investigated in Lake Biwa. During the last five years, vertical and horizontal distributions of water temperature, turbidity, electric conductivity and chlorophyll-a have been obtained both in the south basin and the southern part of the north basin of Lake Biwa. The benthic nepheloid layer (BNL) developed in the seasons of thermal stratification, and is not detectable in the non-stratification period (winter). The BNL is mainly maintained by the organic matter such as phytoplankton under decomposition. However, the turbidity in the nepheloid layer was much affected by the turbid water from rivers after heavy rainfall. In this case, the major component of the suspended substance (SS) in the nepheloid layer was inorganic soil. The particulate P concentration, which is originated from phytoplankton, also increased after a rain fall. This suggests that phytoplankton in the surface layer sinks with clay and silt coming through rivers. From summer to the end of the stratification period, another kind of turbidity appeared in the bottom layer. This is caused by the chemical reaction of manganese under the anoxic condition. The resuspension of bottom sediment by strong currents also occurred, but it is not a major process for maintaining the BNL.     

The nature of the CM parent asteroid regolith based on cosmic ray exposure ages

Cosmic ray exposure (CRE) ages of CM chondrites have been found to have multiple peaks (as many as four), in stark contrast to other groups of chondrites (Nishiizumi and Caffee 2012; Herzog and Caffee 2014). In this study, we sought correlations between the CRE ages and petrography of CM chondrites, and we conclude that the degree of aqueous alteration does appear to vary with the CRE ages—the CMs displaying the most aqueous alteration all have relatively short exposure ages. However, some CMs with low degrees of alteration also have short exposure ages—thus, this apparent correlation is not exclusive. We also found a definite inverse relation between the number of distinctive lithologies in a CM and its exposure age, which could indicate different responses of homogeneous and heterogeneous meteoroids to the space environment between their onset of exposure (exhumation and ejection from the parent body) and arrival at Earth. Breccias have more internal surfaces of lithologic discontinuity, possibly resulting in weaker meteoroids that disintegrate more readily than their more homogeneous counterparts. Our results suggest that CM chondrite regoliths consist of numerous genomict lithologies in a breccia with millimeter‐ to decimeter‐scale clasts, with varying degree of heating/metamorphism.     

Using sulfur isotopes to determine the sources of vermillion in ancient burial mounds in Japan

This study represents an attempt to determine the sources of vermillion found in ancient Japanese burial mounds of the 1st–6th centuries A.D., by comparing their ratios of sulfur isotopes with those of cinnabar ore samples collected in Japan and China. Cinnabar ore samples were taken from three mines in central Japan (Niu in Mie, Yamato in Nara, and Sui in Tokushima prefectures), and from Wanshan in China, where mining activity has been recorded back to the 6th century A.D. and earlier. When the ratios of a ³⁴S and ³²S were compared with the Canyon Diablo meteorite standard, a high δ³⁴S value of +22.6 ± 3.6‰ was found for the Wanshan mine, as opposed to low values ranging from −7.3 ± 1.9 to −2.1 ± 1.6‰ for the Japanese mines. The ratios of sulfur isotopes in vermillion collected from ancient Japanese burial mounds also divided into two groups. High ratios (+11.1 to +22.8‰) were found in 1st‐ and 2nd‐ century burials in the western regions of northern Kyushu and San'in, suggesting that local, powerful chiefs obtained vermillion through relations with China. Lower ratios (−8.4 to −2.0‰) were found in burials of the 2nd through 6th centuries in central Japan, where the ancient Yamato dynasty emerged as the first unified polity around the end of the 2nd century A.D. We, therefore, conclude that the Yamato dynasty exploited local sources of vermillion, rather than depending solely on China. The present study demonstrates the feasibility of determining sources of vermillion using sulfur isotope ratios, and the relevance of such findings for archaeological research. © 2005 Wiley Periodicals, Inc.     

Be andCl depth profiles in an Apollo 15 drill core

Cosmic-ray-produced¹⁰Be (t_1/2 = 1.6 × 10⁶ years) and³⁶Cl (t_1/2 = 3.0 × 10⁵ years) have been measured in the Apollo 15 long core for study of galactic cosmic ray production profiles using tandem accelerator mass spectrometry. From these experiments, the half-attenuation length for¹⁰Be production and³⁶Cl production were calculated to be 120 g/cm² and 132 g/cm² (150–400 g/cm² region). The measured half-attenuation length for¹⁰Be is slightly longer than that predicted by the Reedy-Arnold theoretical model. The flatter and somewhat deeper maximum seen in the³⁶Cl profile compared to the¹⁰Be,²⁶Al and⁵³Mn profiles can be explained by production from secondary thermal neutrons on³⁵Cl.     

Detection of Aseismic Slip on an Inland Fault by Crustal Movement and Groundwater Observations: A Case Study on the Yamasaki Fault, Japan

To understand the detailed process of fault activity, aseismic slip may play a crucial role. Aseismic slip of inland faults in Japan is not well known, except for that related to the Atotsugawa fault. To know whether aseismic slip does not occur, or is merely not detected, is an important question. The National Institute of Advanced Industrial Science and Technology constructed an observation site near Yasutomi fault, a part of the Yamasaki fault system, and has collected data on the crustal strain field, groundwater pressures, and crustal movement using GPS. In a departure from the long-term trend, a transient change of the crustal strain field lasting a few months was recorded. It indicated the possibility of an aseismic slip event. Furthermore, analyses of data from the extensometers at Yasutomi and Osawa observation vaults of Kyoto University, as well as GPS data from the Geographical Survey Institute (GEONET), revealed unsteady crustal strain changes. All data could be explained by local, left-lateral, aseismic slip of the order of 1 mm in the shallow part of the Yasutomi fault.     

Nemuro-Oki earthquake of June 17, 1973: A lithospheric rebound at the upper half of the interface

P-wave first motions, radiation patterns and amplitudes of long-period surface waves, relocated aftershock distributions, leveling and tsunami data indicate that the 1973 Nemuro-Oki earthquake is caused by a low-angle thrust-faulting, representing a rebound at the upper 50 km of the interface between the continental and oceanic lithospheres. Rebound, most likely aseismic, at depths below 50 km, is suggested to take place in the near future from a comparison of recent geologic crustal deformation with pre-seismic and co-seismic data. The estimated seismic moment is about $\text{1}\text{3}\text{–}\text{1}\text{4}$ of that for the neighboring great earthquakes. The macro-seismic data suggest that the 1973 earthquake is smaller than the 1894 Nemuro-Oki earthquake, the last great earthquake in this region.The 1973 earthquake had been predicted on the basis of a seismic gap. Although the prediction was successful as to the location and nature of the faulting and partly as to the occurrence time, it is smaller than the predicted one. A part of the seismic gap may still remain. The difference between the observed seismic slip (1.6 m) and that predicted on the basis of the pre-seismic crustal deformation (3.0 m) indicates either (1) the 1973 earthquake relieved only a part of the strain accumulated in the upper 50 km, or (2) a significant amount of aseismic slip took place on the seismic fault and completely relieved the accumulated strain in the focal region of the 1973 earthquake. If the former is the case, the remaining strain, not only in the focal region, but also in the remaining seismic gap adjoining it, may be relieved in a larger earthquake in the future.The source parameters obtained are as follows: fault plane, dip direction = N40°W, dip angle = 27°; seismic moment = 6.7 · 10²⁷ dyn cm; average slip dislocation, 1.6 m in N63°W direction; stress drop = 35 bars. In these calculations, the fault dimension and the rigidity are assumed to be 100 · 60 km² and 7.0 · 10¹¹ dyn/cm², respectively.     

Beryllium-10 and aluminum-26 in individual cosmic spherules from Antarctica

Abstract— We present data for the cosmogenic nuclides ¹⁰Be and ²⁶Al in a suite of 24 extraterrestrial spherules, collected from Antarctic moraines and deep sea sediments. All of the 10 large spherules collected in glacial till at Lewis Cliff are extraterrestrial. As in earlier work, the great majority of particles show prominent solar cosmic-ray (SCR) production of ²⁶Al, indicating bombardment ages on the order of 10⁶ years or even longer. These long ages are in direct contradiction to model ages for small particles in the inner Solar System and may require reconsideration of models of small particle lifetimes. A small fraction of the particles so far measured (6/42) possess cosmogenic radionuclide patterns consistent with predictions for meteoroid spall droplets. We believe that most of the spherules were bombarded in space primarily as bodies not much larger than their present size. The content of in situ produced ¹⁰Be and ²⁶Al in quartz pebbles in the same moraine suggests that these spherules may have on average a significant terrestrial age.     

A noble gas and cosmogenic radionuclide analysis of two ordinary chondrites from Almahata Sitta

Abstract– We present the results of a noble gas (He, Ne, Ar) and cosmogenic radionuclide (¹⁰Be, ²⁶Al, ³⁶Cl) analysis of two chondritic fragments (#A100, L4 and #25, H5) found in the Almahata Sitta strewn field in Sudan. We confirm their earlier attribution to the same fall as the ureilites dominating the strewn field, based on the following findings: (1) both chondrite samples indicate a preatmospheric radius of approximately 300 g cm^?2, consistent with the preatmospheric size of asteroid 2008 TC₃ that produced the Almahata Sitta strewn field; (2) both have, within error, a ²¹Ne/²⁶Al‐based cosmic ray exposure age of approximately 20 Ma, identical to the reported ages of Almahata Sitta ureilites; (3) both exhibit hints of ureilitic Ar in the trapped component. We discuss a possible earlier irradiation phase for the two fragments of approximately 10–20 Ma, visible only in cosmogenic ³⁸Ar. We also discuss the approximately 3.8 Ga (⁴He) and approximately 4.6 Ga (⁴⁰Ar) gas retention ages, measured in both chondritic fragments. These imply that the two chondrite fragments were incorporated into the ureilite host early in solar system evolution, and that the parent asteroid from which 2008 TC₃ is derived has not experienced a large break‐up event in the last 3.8 Ga.