EPR and magnetism of the nanostructured natural carbonaceous material shungite

The X-band EPR and magnetic susceptibility in the temperature range 4.2–300 K study of the shungite-I, natural nanostructured material from the deposit of Shunga are reported. Obtained results allow us to assign the EPR signal to conduction electrons, estimate their number, N _P, and evaluate the Pauli paramagnetism contribution to shungite susceptibility. A small occupation (~5%) of the localized nonbonding π states in the zigzag edges of the open-ended graphene-like layers and/or on σ (sp ^2+x ) orbitals in the curved parts of the shungite globules has been also revealed. The observed temperature dependence of the EPR linewidth can be explained by the earlier considered interaction of conduction π electrons with local phonon modes associated with the vibration of peripheral carbon atoms of the open zigzag-type edges and with peripheral carbon atoms cross-linking different nanostructures. The relaxation time T ₂ and diffusion time T _D are found to have comparable values (2.84 × 10⁻⁸ and 1.73 × 10⁻⁸ s at 5.2 K, respectively), and similar dependence on temperature. The magnetic measurements have revealed the suppression of orbital diamagnetism due to small amount of large enough fragments of the graphene layers.     

Uplift and late orogenic deformation of the Central European Variscan belt as revealed by sediment provenance and structural record in the Carboniferous foreland basin of western Poland

The Carboniferous foreland basin of western Poland contains a coherent succession of late Viséan through Westphalian turbidites derived from a uniform group of sources located within a continental magmatic arc. Detrital zircon geochronology indicates that two main crustal components were present in the source area of Namurian A sediments. They represent Late Devonian and Early Carboniferous ages, respectively. The detritus from Westphalian D beds is much more diversified and contains admixture of Late Carboniferous zircons suggesting rapid unroofing of Variscan igneous intrusions in the hinterland between Namurian A and Westphalian D times. Tectonic repetitions of tens of metres thick fault-bounded stratigraphic intervals, recorded in several wells, provide evidence for compressional regime that occurred in the SW part of the Carboniferous basin not earlier than during the Westphalian C and produced NW–SE trending folds, concordant with the structural grain of the adjacent, NE part of the Bohemian Massif.     

Ecosystem Functions of Tidal Fresh, Brackish, and Salt Marshes on the Georgia Coast

We examined patterns of habitat function (plant species richness), productivity (plant aboveground biomass and total C), and nutrient stocks (N and P in aboveground plant biomass and soil) in tidal marshes of the Satilla, Altamaha, and Ogeechee Estuaries in Georgia, USA. We worked at two sites within each salinity zone (fresh, brackish, and saline) in each estuary, sampling a transect from the creekbank to the marsh platform. In total, 110 plant species were found. Site-scale and plot-scale species richness decreased from fresh to saline sites. Standing crop biomass and total carbon stocks were greatest at brackish sites, followed by freshwater then saline sites. Nitrogen stocks in plants and soil decreased across sites as salinity increased, while phosphorus stocks did not differ between fresh and brackish sites but were lowest at salty sites. These results generally support past speculation about ecosystem change across the estuarine gradient, emphasizing that ecosystem function in tidal wetlands changes sharply across the relatively short horizontal distance of the estuary. Changes in plant distribution patterns driven by global changes such as sea level rise, changing climates, or fresh water withdrawal are likely to have strong impacts on a variety of wetland functions and services.     

Experimental metasomatism of monazite and xenotime: mineral stability, REE mobility and fluid composition

In this study a Th-bearing monazite from a Brazil beach sand, a low Th monazite from a Malawi carbonatite, and a xenotime from a pegmatite in northern Pakistan were experimentally metasomatised in a series of common metamorphic and igneous fluids at 600°C/500 MPa and 900°C/1000 MPa. Fluids included H₂O, NaCl, and KCl brines, CaF₂?+?H₂O, 1m and 2m HCl, 1m and 2m H₂SO₄, 1m NaOH, and Na₂Si₂O₅?+?H₂O. The monazite show a variety of responses to the fluids ranging from no reaction (KCl?+?H₂O) to small compositional changes and partial replacement of the monazite grain rim by Th-enriched monazite in the NaOH and (Na₂Si₂O₅?+?H₂O) experiments respectively. The other acid and brine fluids induced varying degrees of partial dissolution in the monazite and xenotime, but no compositional alteration. Partial replacement of monazite grain rims by Th-enriched monazite occurred only in the alkaline fluids as the result of a coupled dissolution-reprecipitation process.     

Polymetallic sulfide ores hosted in Late Permian carbonate at the Alanish locality,northern Iraq: petrography and mineral chemistry

Polymetallic sulfide ores (Zn, Pb, Fe, Cu, Ag, and Cd) found in the Alanish locality of northern Iraq are hosted by dolostone in the Late Permian Chia Zairi Formation. The Alanish locality is one of several Zn–Pb deposits that are widespread in northern Iraq, situated along the northern passive margin of the Arabian plate. This paper describes the ore deposit classification, mineral chemistry, and paragenetic sequence of the area and proposes an ore formation model. We report the presence of acanthite and greenockite for the first time in Iraq. A brine solution derived from the sedimentary basin formed the primary sulfide ore minerals (sphalerite, galena, acanthite, pyrite, chalcopyrite, greenockite, and marcasite). The pre-tectonic mineralization is characterized by replacement textures including (1) high-Fe, low-Zn, dark-colored, coarse-grained sphalerite; (2) deformed anisotropic coarse-grained galena; and, (3) idiomorphic cubes of crushed pyrite. Conversely, the post-tectonic mineralization is characterized by open-space filling textures, including (1) low-Fe, high-Zn, light-colored, fine aggregated sphalerite; (2) fine-grained galena; and, (3) the existence of acanthite and marcasite. Although galena is an Ag carrier, both mineralization phases contained non-argentiferous galena. Non-sulfides (smithsonite, cerussite, and goethite) have replaced older sulfides in many areas due to supergene process. Gangue minerals present are dolomite, calcite, barite, and siderite. Open spaces and cavity filling of small paleo-karsts, replacement, veins, and veinlets are common features of the ore body. Metals were sourced from brines generated in the sedimentary basin, whereas sulfur was derived from nearby evaporates. Sediment compaction and tectonic activity, probably during Late Cretaceous, were the driving forces that squeezed and moved ore-bearing fluids derived from the sedimentary basin. Multiple stages of ore-bearing fluids were epigenetically intruded into the Late Paleozoic dolostone, forming an epigenetic strata-bound Mississippi Valley-type deposit precipitated under a temperature of 120 °C, as indicated by the cadmium fractionation in sphalerite and galena. Dolomitization and tectonic activity provided the necessary permeability for accumulating ores. The main ore body is directly connected to a fault plane and to adjacent dolostone that is frequently fractured and brecciated.     

Groundwater nitrate pollution in the recharge zone of a regional Quaternary flow system (Wielkopolska region, Poland)

The present study examines the behaviour of nitrate in the recharge zone of a regional Quaternary flow system. The presence of contaminated groundwater with high nitrate content in the shallow part of the flow system was documented. Tritium analyses confirmed that these contaminants can migrate downward. A high downward gradient exists in the study area, extending into the regions of groundwater extraction. In the unconfined part of the flow system, which is the most vulnerable to pollution, a high concentration of nitrate was found to occur at great depth. However, denitrification processes limit nitrate migration. As a result, in the deeper parts of the flow system in regions under confined conditions, an absence of nitrate was observed, and a higher sulphate concentration and total hardness were evident. The denitrification was also confirmed by the existence of a high gaseous N₂ concentration. It was documented that denitrification occurs in both the confined and unconfined parts of the flow system, but the potential for denitrification is higher in the confined parts (leading to the disappearance of nitrate in deep aquifers). Autotrophic denitrification supported by sulphide compounds was indicated as the dominant denitrification process.     

Site formation processes in loess areas: A case study from moravany-žakovska,western slovakia

The site of Moravany-Žakovska in western Slovakia is situated in a loessic terrain and is dated to the end of the Late Glacial Maximum. This article shows the importance of analyzing the 0.01-0.1 mm fraction to interpret the sedimentological environment and a number of measured anthropogenic indices, such as burnt quartz grains, charcoal, radiolarite chips, microflakes, and microfragments of bone. Analysis of the profile of the site through time reveals the relationship between occupational levels and phases of slope wash that occurred during wetter climatic episodes; these are separated by phases of aeolian sedimentation. At the same time, analysis of anthropogenic indices in this size fraction permitted the identification of occupational levels, including those not recorded by macrofinds. Analysis of anthropogenic indices in horizontal exposures enabled the identification of latent settlement structures such as hearths, areas of radiolarite processing, zones where mineral dyes were prepared, and other structures not recorded by macrofinds.     

Balanced cross-section restoration in a complicated folded hinterland structure: Shilbilisaj profile,Talas ridge,Caledonian Tien Shan

Conventional cross-section balancing techniques based on layer length measuring can be applied only for foreland structures. To analyse complicated hinterland structure with numerous small-scale folds, this balancing technique requires the reliable and detailed tracing of the morphology of any layer throughout the cross-section, which is unattainable. We present a special kinematic method of balancing cross sections based “on the geometry of the folded domain” which enables the structural restoration of hinterland regions. We apply the method to restore the detailed structural section along the Shilbilisaj River, having a length of 26 km. We divided this section into 40–60 so-called “domains” each including 2–7 folds. Our method uses the fold's morphology to determine the strain ellipsoid, which describes the deformation of each domain and is used to restore its pre-folded state. By combining the pre-folded states of the domains, we reconstruct the entire profile, and calculate shortening values as K = L₀/L₁ (initial to final length). The overall shortening value for the profile is 4.49, incrementally varying along the section from 3.79 to 5.53. The comparable results of two independently performed reconstructions emphasize the reliability of the applied balancing method.