Removal of bisphenol A (BPA) from biologically treated wastewater by microfiltration and nanofiltration

Bisphenol A (BPA) is an endocrine disruptor that is difficult to completely remove from wastewater by conventional biological methods. Increased post-treatment BPA removal with ceramic membranes is worth investigating because of these membranes’ mechanical and chemical stability and lifespan. To determine the effectiveness of ceramic membranes for post-treatment of biologically treated BPA-contaminated wastewater, microfiltration (MF) and nanofiltration (NF) were conducted. Both processes removed BPA completely at an initial BPA concentration of 0.3 ± 0.14 mg/L. Increased concentration of 0.7 ± 0.29 mg/L decreased BPA removal. MF removed at least 24 % of BPA, presumably because BPA was adsorbed on particulate matter, which was retained by the membrane, or adsorbed on its surface. NF removed up to thrice more BPA. MF and NF completely removed suspended solids and 40–60 % COD. Filtration capacity decreased with time due to fouling but did not depend on initial BPA concentration. BPA concentrations in municipal wastewater are typically lower than the lowest concentration tested, where MF completely removed BPA. Hence, MF ceramic membranes appear a promising solution for post-treatment of BPA-containing wastewater. MF can be used at a much lower transmembrane pressure than NF, requiring less energy to pump wastewater through the membrane, thus reducing costs.     

Changing patterns of residential and workplace segregation in the Stockholm metropolitan area

Immigrant–native segregation is present in the spaces in which individuals from different ethnic/racial groups practice their everyday lives; interact with others and develop their ethnic, social and spatial networks. The overwhelming majority of academic research on immigrant segregation has focused on the residential domain, thus largely overlooking other arenas of daily interaction. The present study contributes to the emerging literature on immigrant residential and workplace segregation by examining changes in patterns of residential and workplace segregation over time. We draw our data from the Stockholm metropolitan region, Sweden’s main port of entry for immigrants. The results suggest a close association between residential and workplace segregation. Immigrant groups that are more segregated at home are also more segregated in workplace neighborhoods. More importantly, we found that a changing segregation level in one domain tends to involve a similar trend in the other domain.     

Fossil fuel compounds from fly dust in recent organic matter of southern Poland peats

Several samples of peat from 6 bogs located in southern Poland were investigated for occurrence and distribution types of biomarkers present in their extractable organic matter fraction. It was found that there are inputs from two different sources of organic compounds differing in their characteristics and origin: (1) recent immature peat organic matter deposited in situ which is the source of all polar functionalized compounds, most of n-alkanes, and acyclic isoprenoids, and (2) mature fossil fuels, most probably bituminous coals from the Upper Silesia Coal Basin of vitrinite reflectance equivalent values of 0.9–1.1%. The latter compounds were most probably transported with fly ash to bogs from nearby settlements utilizing such fuel in domestic ovens. This group includes pentacyclic triterpenoids (hopanes and moretanes), minor amounts of n-alkanes, and numerous alkyl naphthalenes and alkyl phenanthrenes. All these compounds show distributions and values of geochemical ratios characteristic for mature organic matter confirming there ex situ origin.     

Anomalous induction in the Carpathians

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A substantial part of this paper was presented at the IAGA symposium Relations between External and Internal Magnetic Variations, XVI. IUGG General Assembly, August–September 1975, Grenoble.     

The strength and width of Fe Kα lines in Seyferts and their correlations with the X-ray slope

We study properties of Fe K lines of a large sample of Seyfert 1s observed by ASCA . Fits with power laws and Gaussian lines yield the average linewidth and equivalent width of 0.22±0.03 keV and 0.13±0.01 keV, respectively. Thus, the typical lines are weak and narrow. We then obtain the average line profile of all our spectra, and find it to consist of a narrow core and blue and red wings, with the red wing being much weaker than that of e.g. MCG −6-30-15. We obtain three average spectra of Seyferts grouped according to the hardness, and find the equivalent width of the core (originating in a remote medium) to be ≃50 eV in all three cases. The wings are well fitted by a broad line from a disc with strong relativistic effects. Its equivalent width correlates with the slope, increasing from ∼70 eV for the hardest spectrum to ∼120 eV for the softest one. The inner disc radius decreases correspondingly from ∼40 to ∼10 gravitational radii, and the fitted disc inclination is ∼45°. The obtained correlation between the slope and the strength of the broad Fe K line is found to be consistent with the previously found correlation of the slope and Compton reflection.     

Organic matter from the Callovian (Middle Jurassic) deposits of Lithuania: Compositions,sources and depositional environments

This study presents the first organic geochemical and petrographical investigation of the Callovian deposits of the eastern part of the Central European Basin. It is shown that in both the terrigenous Papil? Formation (Lower Callovian) and shallow- to deeper-marine facies of the Papartin? and Skinija formations (Middle and Upper Callovian, respectively), terrestrial organic matter predominates. This is reflected by the carbon preference index values higher than 1.2 for all samples and in some cases higher than 2, as well as the occurrence of characteristic higher plant biomarkers like cadalene, dehydroabietane, simonellite and retene. Moreover, in the case of the Papil? Formation, sugiol – a natural product terpenoid produced by distinct conifer families, has been detected in clay sediments. The occurrence of such a biomolecule in the Middle Jurassic clays is reported for the first time. Its occurrence is probably connected with the presence of small wood debris in the clay sediments. In samples of the Papil? Formation, charcoal fragments co-occurring with unsubstituted polycyclic aromatic hydrocarbons were detected, indicating that wildfires took place during the Early Callovian of Lithuania and/or neighbouring areas. In the Middle and Upper marine Callovian sediments of Lithuania there is no evidence of anoxic conditions occurring in the water column. However, periodic anoxic or strongly dysoxic episodes may have occurred, most probably below the photic zone, during the deepest phase of the Late Callovian transgression, as is evidenced from pyrite framboid diameter distribution and general impoverishment of benthic fauna. Huminite reflectance (R_r) values for the investigated area are in the range of 0.21–0.31%, suggesting the occurrence of immature organic matter. Such values indicate that these investigated deposits were close to the surface during their whole diagenetic history, and the thickness of younger cover did not exceed ca. 500 m. This is also supported by a biomarker analysis in which less thermally stable ββ-hopanes and hopenes significantly dominated.     

Modelling the pre-failure instabilities of sand

A simple incremental model describing the pre-failure behaviour of granular soils is presented. The model describes both the dry/fully drained and undrained response. It takes into account an initial anisotropy of soil and an initial state defined as either contractive or dilative. A physically sound definition of loading/unloading is assumed, which differs from elasto-plastic approaches. The model is based on extensive empirical data and gives predictions conformable with experimental results. It also describes pre-failure instabilities of granular soils, both dry/fully drained and undrained. The Hill’s criterion was used to examine stability. It was shown that this condition can be formulated either in terms of the effective stresses or by the total stresses. In the extreme cases of either dry/fully drained or undrained conditions, these alternative formulations are equivalent. This is not so in the case of partial drainage of pore water and associated volumetric deformations as well as pore pressure changes. The model describes the pre-failure instabilities well, and additionally allows for analytical derivation of the instability line. It was shown that the second order work, appearing in the Hill’s condition, is equivalent to the entropy source.     

A Model to Predict Granular Activated Carbon Backwash Curves

A mathematical model that produces curves for predicting the expansion of granular activated carbon (GAC) filter beds has been developed and applied to several widely used commercial GAC products. Initially, the hydraulic load required to produce a given bed expansion was assumed to be inversely proportional to the viscosity. This assumption was then modified by assuming a power law for the dependence on viscosity. The errors were sufficiently small to allow practical application of the formulae presented in this paper. The potential for application of the method was tested and is illustrated by an example.     

Background Concentrations of Nickel in the Sediments of the Carpathian Dam Reservoirs (Southern Poland)

The background nickel (Ni) concentrations in the sediments of two sub‐mountain reservoirs (Dobczyce and Czorsztyn) situated in the Carpathian Flysh (southern Poland) were evaluated. Ni concentrations (15.6–83.1 µg g^?1 dry wt.) in both reservoir sediments were affected mainly by the high background content of Ni in the surrounding watershed. Distribution of elevated Ni concentrations mostly revealed an impact of long‐range transport influenced by the flow of the main tributary. Ni spatial pattern was mainly influenced by mineral compounds of Fe, Mn, and Al, and to a lesser degree by organic matter content and silt and clay fractions of the sediments of both investigated reservoirs. Spatial distribution was additionally modified by hydrological conditions (flood events and course of the old river‐bed). In both reservoirs, substantial portions of Ni were bound to potentially immobile phases, i.e., moderately reducible and residual phases (64–82% in total). Laboratory experiments showed that changes in pH affected Ni leaching from the sediment to a small degree (at pH ～3 up to 19.9%). Our results indicated that Ni in these reservoirs has low mobility and, therefore, poses a low toxicological risk to aquatic organisms.