The thermal decomposition studies of three Polish bituminous coking coals and their blends

The objective of this work was to investigate the thermal decomposition of various bituminous coal blends. Three Polish coals of varying rank (82.7, 86.2 and 88.7 wt.% carbon content) and caking ability (weak, moderate and strong) were collected from the Krupiński, Szczygłowice and Zofiówka mines, respectively. These coals were used to prepare binary and ternary blends. Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) were used. The weight loss and heat flow during pyrolysis, and storage/loss elastic modulus measured as a function of increasing temperature were related to the caking ability of coals. Parameters determined with the TGA and the DSC methods in the binary and ternary blends were correlated with the proportion of strongly-caking-coal concentration in the blend. The weight loss of coal blends was found to be additive parameter. The DSC thermograms of binary blends were found to be different from those of the ternary blends, which suggests a different course for this blend pyrolysis.     

A complex asteroseismic study of the hybrid B-type pulsator ν Eridani

We present results of comprehensive seismic modelling of the B-type main-sequence pulsator ν Eridani, which consists in parallel fitting of the pulsational frequencies and corresponding values of the complex, nonadiabatic parameter f, defined by the bolometric flux perturbation. This kind of studies, which we call complex asteroseismology, provides a unique test of stellar opacities. Our results indicate a preference for the OPAL data.     

Modelling the pre-failure instabilities of sand

A simple incremental model describing the pre-failure behaviour of granular soils is presented. The model describes both the dry/fully drained and undrained response. It takes into account an initial anisotropy of soil and an initial state defined as either contractive or dilative. A physically sound definition of loading/unloading is assumed, which differs from elasto-plastic approaches. The model is based on extensive empirical data and gives predictions conformable with experimental results. It also describes pre-failure instabilities of granular soils, both dry/fully drained and undrained. The Hill’s criterion was used to examine stability. It was shown that this condition can be formulated either in terms of the effective stresses or by the total stresses. In the extreme cases of either dry/fully drained or undrained conditions, these alternative formulations are equivalent. This is not so in the case of partial drainage of pore water and associated volumetric deformations as well as pore pressure changes. The model describes the pre-failure instabilities well, and additionally allows for analytical derivation of the instability line. It was shown that the second order work, appearing in the Hill’s condition, is equivalent to the entropy source.     

Organic matter from the Callovian (Middle Jurassic) deposits of Lithuania: Compositions,sources and depositional environments

This study presents the first organic geochemical and petrographical investigation of the Callovian deposits of the eastern part of the Central European Basin. It is shown that in both the terrigenous Papil? Formation (Lower Callovian) and shallow- to deeper-marine facies of the Papartin? and Skinija formations (Middle and Upper Callovian, respectively), terrestrial organic matter predominates. This is reflected by the carbon preference index values higher than 1.2 for all samples and in some cases higher than 2, as well as the occurrence of characteristic higher plant biomarkers like cadalene, dehydroabietane, simonellite and retene. Moreover, in the case of the Papil? Formation, sugiol – a natural product terpenoid produced by distinct conifer families, has been detected in clay sediments. The occurrence of such a biomolecule in the Middle Jurassic clays is reported for the first time. Its occurrence is probably connected with the presence of small wood debris in the clay sediments. In samples of the Papil? Formation, charcoal fragments co-occurring with unsubstituted polycyclic aromatic hydrocarbons were detected, indicating that wildfires took place during the Early Callovian of Lithuania and/or neighbouring areas. In the Middle and Upper marine Callovian sediments of Lithuania there is no evidence of anoxic conditions occurring in the water column. However, periodic anoxic or strongly dysoxic episodes may have occurred, most probably below the photic zone, during the deepest phase of the Late Callovian transgression, as is evidenced from pyrite framboid diameter distribution and general impoverishment of benthic fauna. Huminite reflectance (R_r) values for the investigated area are in the range of 0.21–0.31%, suggesting the occurrence of immature organic matter. Such values indicate that these investigated deposits were close to the surface during their whole diagenetic history, and the thickness of younger cover did not exceed ca. 500 m. This is also supported by a biomarker analysis in which less thermally stable ββ-hopanes and hopenes significantly dominated.     

An Ontology‐Driven Framework and Web Portal for Spatial Decision Support1

Numerous systems and tools have been developed for spatial decision support (SDS), but they generally suffer from a lack of re‐usability, inconsistent terminology, and weak conceptualization. We introduce a collaborative effort by the SDS Consortium to build a SDS knowledge portal. We present the formal representation of knowledge about SDS, the various ontologies captured and made accessible by the portal, and the processes used to create them. We describe the portal in action, and the ways in which users can search, browse, and make use of its content. Finally, we discuss the lessons learned from this effort, and future development directions. Our work demonstrates how ontologies and semantic technologies can support the documentation and retrieval of dynamic knowledge in GIScience by offering flexible schemata instead of fixed data structures.     

A secular theory of coplanar, non-resonant planetary system

We present the secular theory of coplanar N -planet system, in the absence of mean motion resonances between the planets. This theory relies on the averaging of a perturbation to the two-body problem over the mean longitudes. We expand the perturbing Hamiltonian in Taylor series with respect to the ratios of semimajor axes which are considered as small parameters, without direct restrictions on the eccentricities. Next, we average out the resulting series term by term. This is possible thanks to a particular but in fact quite elementary choice of the integration variables. It makes it possible to avoid Fourier expansions of the perturbing Hamiltonian. We derive high-order expansions of the averaged secular Hamiltonian (here, up to the order of 24) with respect to the semimajor axes ratio. The resulting secular theory is a generalization of the octupole theory. The analytical results are compared with the results of numerical (i.e. practically exact) averaging. We estimate the convergence radius of the derived expansions, and we propose a further improvement of the algorithm. As a particular application of the method, we consider the secular dynamics of three-planet coplanar system. We focus on stationary solutions in the HD 37124 planetary system.     

Searching for the Parent of the Tunguska Cosmic Body

We present the results of an extensive study of the Tunguska Cosmic Body (TCB) origin on dynamical grounds. To identify the TCB parent, or a plausible candidate, we applied the well-known concept of dynamical similarity whereby we have compared the geocentric and heliocentric dynamical parameters of a selected set of the Near Earth Objects (NEOs) and TCB particles. First, we made use the idea of Kresak by comparing geocentric coordinates of the TCB radiant with those of the NEOs. Second, we studied the long-term dynamical evolution of all NEOs and TCB particles searching for similarities between their heliocentric orbits. As a general result, we observed many more similar cases and a different pattern of the high orbital similarity among the TCB particles and the asteroid orbits than we did for comets.     

A dynamical analysis of the 14 Herculis planetary system

Precision radial velocity measurements of the Sun-like dwarf 14 Herculis published by Naef et al., Butler et al. and Wittenmyer, Endl & Cochran reveal a Jovian planet in a 1760-d orbit and a trend indicating the second distant object. On the grounds of dynamical considerations, we test a hypothesis that the trend can be explained by the presence of an additional giant planet. We derive dynamical limits to the orbital parameters of the putative outer Jovian companion in an orbit within ∼13 au. In this case, the mutual interactions between the Jovian planets are important for the long-term stability of the system. The best self-consistent and stable Newtonian fit to an edge-on configuration of Jovian planets has the outer planet in 9-au orbit with a moderate eccentricity of ∼0.2 and confined to a zone spanned by the low-order mean motion resonances 5:1 and 6:1. This solution lies in a shallow minimum of (χ²_ν)^1/2 and persists over a wide range of the system inclination. Other stable configurations within 1σ confidence interval of the best fit are possible for the semimajor axis of the outer planet in the range of (6,13) au and the eccentricity in the range of (0, 0.3). The orbital inclination cannot yet be determined but when it decreases, both planetary masses approach ∼10 m _J and for i ∼ 30° the hierarchy of the masses is reversed.     

Geology,stratigraphy and palaeoenvironmental evolution of the Stephanorhinus kirchbergensis-bearing Quaternary palaeolake(s) of Gorzów Wielkopolski (NW Poland,Central Europe)

The sedimentary succession exposed in the Gorzów Wielkopolski area includes Eemian Interglacial (MIS 5e) or Early Weichselian (MIS 5d–e) deposits. The sedimentary sequence has been the object of intense interdisciplinary study, which has resulted in the identification of at least two palaeolake horizons. Both yielded fossil remains of large mammals, alongside pollen and plant macrofossils. All these proxies have been used to reconstruct the environmental conditions prevailing at the time of deposition, as well as to define the geological context and the biochronological position of the fauna. Optically stimulated luminescence dating of the glaciofluvial layers of the GS3 succession to 123.6 ± 10.1 (below the lower palaeolake) and 72.0 ± 5.2 ka (above the upper palaeolake) indicate that the site formed during the Middle–Late Pleistocene (MIS 6 – MIS 5). Radiocarbon-dating of the lacustrine organic matter revealed a tight cluster of Middle Pleniglacial Period (MIS 3) ages in the range of ~41–32 ka cal bp (Hengelo – Denekamp Interstadials). Holocene organic layers have also been found, with ¹⁴C ages within a range of 4330–4280 cal bp (Neolithic). Pollen and plant macrofossil records, together with sedimentological and geochemical data, confirm the dating to the Eemian Interglacial.     

Blueschist facies metamorphism in Nordenskiöld Land of west‐central Svalbard

Recent fieldwork in Nordenskiöld Land, Svalbard's Southwestern Basement Province, has established the presence of high‐pressure (HP) lithologies. They are strongly retrogressed blueschists consisting mainly of garnet and Ca‐amphibole with remnants of ferroglaucophane and phengite. The pressure–temperature (P–T) conditions were estimated using phase equilibrium modelling in the NCKFMMnASHTO system. P–T estimates based on the garnet, phengite and ferroglaucophane compositional isopleths and modelled paragenetic assemblage indicate peak metamorphism at 470–490 °C and 14–18 kbar. These data fall close to the 7–8 °C km^?1 geotherm, which is similar to that from Motalafjella, the only previously known occurrence of blueschists in Svalbard's Caledonides. The newly discovered blueschists could have formed during the early stage of the Caledonian Orogeny and may represent a vestige of missing marginal basins of the western Iapetus developed at the onset of subduction. The likely counterpart to Svalbard's blueschists is the ophiolitic sequence in the Pearya Terrane of northern Ellesmere Island.