The heat goes on—changes in indices of hot extremes in Poland

Theoretical and Applied Climatology - On the basis of temperature observations at 60 meteorological stations in Poland, changes in the indices associated with the presence of extremely high air...     

Impulse approximation improved

Improved formulas of impulse approximation method for stellar perturbations are derived. The method proposed involves a deflection of the stellar path. It is also applicable to an arbitrary time interval. A comparison of the classical vs improved method is presented both in qualitative discussion and numerical results for Oort cloud cometary orbits.     

A model of the gravitational field of Amalthea

Utilizing the topographic model of Jovian moon Amalthea (Stooke, 1994) and supposing that its mass density is constant we derived its basic geometrical and dynamical characteristics. For calculations the harmonic model of topography of the degree and order 18 was selected. The model appears to fit the entire surface to a mean accuracy of a few hundred meters, except in the regions localized around longitudes 0° and 180°. On the basis of the harmonic expansion of the topography we estimated the volume (V = 2.43 ± 0.02 km³) and the mean radius of topographyr ₀ = (79.7 ± 0.2) km. Generalized moments of inertia up to the order 2, principal moments of inertia and orientation of the principal axes with respect to the original reference frame were also calculated. The results show that although Amalthea has extremely irregular shape it may be treated dynamically as an almost symmetric body (B C). Finally, the set of the Stokes coefficients up to the degree and order 9 was evaluated. The results are verified by direct numerical integration.     

Seasonal deposition of authigenic calcite out of isotopic equilibrium with DIC and water,and implications for paleolimnological studies

Journal of Paleolimnology - We conducted year-round, monthly monitoring of the stable isotope composition of DIC and water in hypereutrophic Lake Kierskie, western Poland, along with isotope...     

Evaluating transition-metal catalysis in gas generation from the Permian Kupferschiefer by hydrous pyrolysis

Transition metals in source rocks have been advocated as catalysts in determining extent, composition, and timing of natural gas generation (Mango, F. D. (1996) Transition metal catalysis in the generation of natural gas. Org. Geochem.24, 977-984). This controversial hypothesis may have important implications concerning gas generation in unconventional shale-gas accumulations. Although experiments have been conducted to test the metal-catalysis hypothesis, their approach and results remain equivocal in evaluating natural assemblages of transition metals and organic matter in shale. The Permian Kupferschiefer of Poland offers an excellent opportunity to test the hypothesis with immature to marginally mature shale rich in both transition metals and organic matter. Twelve subsurface samples containing similar Type-II kerogen with different amounts and types of transition metals were subjected to hydrous pyrolysis at 330° and 355 °C for 72 h. The gases generated in these experiments were quantitatively collected and analyzed for molecular composition and stable isotopes. Expelled immiscible oils, reacted waters, and spent rock were also quantitatively collected. The results show that transition metals have no effect on methane yields or enrichment. δ¹³C values of generated methane, ethane, propane and butanes show no systematic changes with increasing transition metals. The potential for transition metals to enhance gas generation and oil cracking was examined by looking at the ratio of the generated hydrocarbon gases to generated expelled immiscible oil (i.e., GOR), which showed no systematic change with increasing transition metals. Assuming maximum yields at 355 °C for 72 h and first-order reaction rates, pseudo-rate constants for methane generation at 330 °C were calculated. These rate constants showed no increase with increasing transition metals. The lack of a significant catalytic effect of transition metals on the extent, composition, and timing of natural gas generation in these experiments is attributed to the metals not occurring in the proper form or the poisoning of potential catalytic microcosms by polar-rich bitumen, which impregnates the rock matrix during the early stages of petroleum formation.     

Plumbotectonic aspects of polymetallic vein mineralization in Paleozoic sediments and Proterozoic basement of Moravia (Czech Republic)

A regional isotopic study of Pb and S in hydrothermal galenas and U–Pb and S in potential source rocks was carried out for part of Moravia, Czech Republic. Two major generations of veins, (syn-) Variscan and post-Variscan, are defined based on the Pb-isotope system together with structural constraints (local structures and regional trends). The Pb-isotopic compositions of galena plot in two distinct populations with outliers in ²⁰⁶Pb/²⁰⁴Pb–²⁰⁷Pb/²⁰⁴Pb space. Galena from veins hosted in greywackes provides a cluster with the lowest Pb–Pb ratios: ²⁰⁶Pb/²⁰⁴Pb = 18.15–18.27, ²⁰⁷Pb/²⁰⁴Pb = 15.59–15.61, ²⁰⁸Pb/²⁰⁴Pb = 38.11–38.23. Those hosted in both limestones and greywackes provide the second cluster: ²⁰⁶Pb/²⁰⁴Pb = 18.37–18.44, ²⁰⁷Pb/²⁰⁴Pb = 15.60–15.63, ²⁰⁸Pb/²⁰⁴Pb = 38.14–38.32. These clusters suggest model Pb ages as Early Carboniferous and Triassic–Jurassic, the latter associated with MVT-like deposits. Two samples from veins hosted in Proterozoic rocks lie outside the two clusters: in metagranitoid (²⁰⁶Pb/²⁰⁴Pb = 18.55, ²⁰⁷Pb/²⁰⁴Pb = 15.64, ²⁰⁸Pb/²⁰⁴Pb = 38.29) and in orthogneiss (²⁰⁶Pb/²⁰⁴Pb = 18.79, ²⁰⁷Pb/²⁰⁴Pb = 15.73, ²⁰⁸Pb/²⁰⁴Pb = 38.54). The results from these two samples suggest an interaction of mineralizing fluids with the radiogenic Pb-rich source (basement?). The values of δ³⁴S suggest the Paleozoic host rocks (mostly ?6.7 to +5.2‰ CDT) as the source of S for hydrothermal sulfides (mostly ?4.8 to +2.5‰ CDT). U–Pb data and Pb isotope evolutionary curves indicate that Late Devonian and Early Carboniferous sediments, especially siliciclastics, are the general dominant contributor of Pb for galena mineralization developed in sedimentary rocks. Plumbotectonic mixing occurred, it is deduced, only between the lower and the upper crust (the latter involving Proterozoic basement containing heterogeneous radiogenic Pb), without any significant input from the mantle. It is concluded that in the Moravo–Silesian and Rhenohercynian zones (including proximal districts in Poland) lead and sulfur have been mobilized from the adjacent rocks during multiple hydrothermal events in processes that are remarkably comparable in timing, geochemistry of fluids and nature of sources.     

Life cycle of chokka-squid Loligo reynaudii in South African waters

This short note summarises past and current knowledge of the life cycle of chokka-squid Loligo reynaudii d’Orbigny, 1845, in South African waters. Prior to approximately 2010, the chokka-squid stock was considered simple and uniform, with one paralarval pool, the drift of paralarvae westwards, one main nursery area and one main, long spawning migration of adult squid eastwards, back to the main spawning grounds. Based on new information, this life-history scheme has been revised. Genetically, the stock is uniform; however, morphologically, it comprises three main geographic groups. It is proposed that the differences between the groups originate from many different paralarval events and that short (not long) migrations dominate the life cycle.     

Geo‐questionnaire: A Method and Tool for Public Preference Elicitation in Land Use Planning

Geo‐questionnaire involves an integration of sketchable maps with questions, aimed at eliciting public preferences and attitudes about land allocation and services. Respondents can link their answers with corresponding locations on a map by marking points or sketching polygon features. Geo‐questionnaires have been used to learn about perceptions and preferences of city residents for specific types of land use, place‐based services, and development projects. This article reports on results of an empirical study, in which an online geo‐questionnaire was designed and implemented to elicit preferences of residents in guiding an urban development plan. Preferences collected in the form of polygon sketches were processed using GIS operations and mapped for visual interpretation. The article focuses on aggregation and analysis of respondent preferences including the analysis of positional and attribute uncertainty. Results of the study show that geo‐questionnaire is a scalable method for eliciting public preferences with a potential for meaningfully informing land use planning.