Phosphorus distribution in sinking oceanic particulate matter

Despite the recognition of the importance of phosphorus (P) in regulating marine productivity in some modern oceanic systems and over long timescales, the nature of particulate P within the ocean is not well understood. We analyzed P concentration in particulate matter from sediment traps and selected core tops from a wide range of oceanic regimes: open ocean environments (Equatorial Pacific, North Central Pacific), polar environments (Ross Sea, Palmer Deep), and coastal environments (Northern California Coast, Monterey Bay, Point Conception). These sites represent a range of productivity levels, temporal (seasonal to annual) distributions, and trap depths (200–4400 m). P associations were identified using an operationally defined sequential extraction procedure. We found that P in the sediment traps is typically composed of reactive P components including acid-insoluble organic P ( 40%), authigenic P ( 25%), and oxide associated and/or labile P ( 21%), with lesser proportions of non-reactive detrital P depending on location ( 13%). The concentrations and fluxes of all particulate P components except detrital P decrease or remain constant with depth between the shallowest and the deepest sediment traps, indicating some regeneration of reactive P components. Transformation from more labile forms of P to authigenic P is evident between the deepest traps and core top sediments. Although for most sites the magnitudes of reactive P fluxes are seasonally variable and productivity dependent, the fractional associations of reactive P are independent of season. We conclude that P is transported from the upper water column to the sediments in various forms previously considered unimportant. Thus, acid-insoluble organic P measurements (typically reported as particulate organic P) likely underestimate biologically related particulate P, because they do not include the labile, oxide-associated, or authigenic P fractions that often are or recently were biologically related. Organic C to reactive P ratios are typically higher than Redfield Ratio and are relatively constant with depth below 300 m suggesting that preferential regeneration of P relative to C occurs predominantly at shallow depths in the water column, but not deeper in the water column (> 300 m). The view of P cycling in the oceans should be revised (1) to include P fractions other than acid-soluble organic P as important carriers of reactive P in rapidly sinking particles, (2) to include the efficient transformation of labile forms of P to authigenic P in the water column as well as in sediments, and (3) to consider the occurrence of preferential P regeneration at very shallow depths.     

Work practice among advanced producer service firms – project work in space-time

This article is an explorative investigation of a sample of advanced producer service (APS) companies located in Stockholm (the capital and main urban centre of Sweden). The discussion is centred on aspects of work practice and how this is conditioned by space-time constraints. These space-time constraints refer to coupling, authority and capability constraints which are concepts framed in a time-geography approach. Although time-geography is primarily engaged in mapping presence and locations in time-space, its concepts of constraints embrace physical, social and cultural factors. The article presents an empirical in-depth study of project work and work practice among a selection of APS companies. A micro-approach to work practice has been pursued using a multi-method strategy and time-geography methodology including time diaries, interviews and a questionnaire. The experiences among the investigated companies of time-geography constraints make the constant negotiations for the practice of work among these organizations intelligible. To the extent these investigated companies may be considered representative of advanced services more generally, the presence of pressing constraints helps to explain the more general structure of this industry of high labour turnover and rapid company re-structuring processes.     

The impact of climate change on tribal communities in the US: displacement, relocation, and human rights

Tribal communities in the United States, particularly in coastal areas, are being forced to relocate due to accelerated rates of sea level rise, land erosion, and/or permafrost thaw brought on by climate change. Forced relocation and inadequate governance mechanisms and budgets to address climate change and support adaptation strategies may cause loss of community and culture, health impacts, and economic decline, further exacerbating tribal impoverishment and injustice. Sovereign tribal communities around the US, however, are using creative strategies to counter these losses. Taking a human rights approach, this article looks at communities’ advocacy efforts and strategies in dealing with climate change, displacement, and relocation. Case studies of Coastal Alaska and Louisiana are included to consider how communities are shaping their own relocation efforts in line with their cultural practices and values. The article concludes with recommendations on steps for moving forward toward community-led and government-supported resettlement programs.     

Determination of Total Free Sulphides in Sediment Porewater and Artefacts Related to the Mobility of Mineral Sulphides

A field and laboratory study of the accuracy of a method commonly used to determine free sulphide concentrations in the porewater of marine sediments is presented. The method uses an ion-selective electrode (ISE), sensitive to the sulphide ion (S²⁻), in sediments buffered to high pH (>12) and is commonly used in regulatory monitoring programs to assess the impacts of open net-pen finfish aquaculture on local marine habitats. Here we report that on the timescale of field measurements, the accepted protocol can lead to significant bias of free sulphide measurements, with orders of magnitude higher concentration detected in the buffered sediment–porewater slurry than in porewater samples isolated and analysed separately. Laboratory experiments with model marine sediments and analysis of sediment composition indicate that this bias is likely introduced by the dissolution of particulate sulphides and/or sulphur present in the sediments under the intense alkaline conditions of the protocol. Recommendations for the modification and continued use of this commonly applied field methodology are discussed.     

Rapid, high-precision potentiometric titration of alkalinity in ocean and sediment pore waters

A system for rapid, high precision potentiometric determination of alkalinity in sea water and sediment pore water is presented. Two titration units were used: a 40 ml unit for seawater and a small volume unit for sediment pore water. Titration time was normally less than 10 minutes per sample, including sample exchange. With a 40 ml sample volume, the relative standard deviation of the alkalinity obtained in the laboratory was 0.05% and at sea 0.1 %. The small-volume system (0.5–1.5 ml) gave a precision of 0.07%. Five titration points, in two groups after the second equivalence point, were used to evaluate the equivalence volume. Results from equilibrium calculations and computer simulated alkalinity titrations show that it was possible to use a non-modified Gran function [(V₀ +v)^*10^(E/Z)] and still achieve good accuracy and precision.     

Manoeuvring the middle ground: Social mobility and the renegotiation of gender and family obligations among Chinese Singaporeans

The article examines Singaporeans' experiences of upward social mobility and how traditional gender roles within the family are renegotiated and reinterpreted in Singapore. When the former British colony gained independence in 1965 its post-colonial government embarked on an ambitious modernization programme, under which villages were demolished and residents relocated to new high-rise estates, farmland gave way to factories, the education system was reformed, and women entered the workforce. The transformation has been accompanied by a rapid upward social mobility, whereby Singaporeans born in the midst of the transformation, in the period 1960s – 1980s, lived remarkably different lives compared with preceding generations. The article is an ethnographic analysis of how Singaporean middle-class women and men, who have experienced rapid upward social mobility, handle and negotiate changing expectations regarding gender and intergenerational support. The analytical framework is constructed around the concepts of social mobility, modernity, and spaces of contestation and negotiation. The ethnographic data illuminate how traditional family values, such as filial piety, are contested and renegotiated. The data also show how social mobility intersects with other forms of mobility, such as the spatial movement involved in urbanization. Women entering the labour force have to spend their days away from home and can no longer fully attend to their elderly family members and/or young children. However, spatial movement in the sense of increased access to transportation and communication has also enabled members of extended families to maintain their ‘urban kinship network’ without having to live together.     

Potential climate change impacts on the probability of wind damage in a south Swedish forest

We estimated how the possible changes in wind climate and state of the forest due to climate change may affect the probability of exceeding critical wind speeds expected to cause wind damage within a forest management unit located in Southern Sweden. The topography of the management unit was relatively gentle and the forests were dominated by Norway spruce (Picea abies (L.) Karst.). We incorporated a model relating the site index (SI) to the site productivity into the forest projection model FTM. Using estimated changes in the net primary production (NPP) due to climate change and assuming a relative change in NPP equal to a relative change in the site productivity, we simulated possible future states of the forest under gradual adjustment of SI in response to climate change. We estimated changes in NPP by combining the boreal-adapted BIOMASS model with four regional climate change scenarios calculated using the RCAO model for the period 2071–2100 and two control period scenarios for the period 1961–1990. The modified WINDA model was used to calculate the probability of wind damage for individual forest stands in simulated future states of the forest. The climate change scenarios used represent non-extreme projections on a 100-year time scale in terms of global mean warming. A 15–40% increase in NPP was estimated to result from climate change until the period 2071–2100. Increasing sensitivity of the forest to wind was indicated when the management rules of today were applied. A greater proportion of the calculated change in probability of wind damage was due to changes in wind climate than to changes in the sensitivity of the forest to wind. While regional climate scenarios based on the HadAM3H general circulation model (GCM) indicated no change (SRES A2 emission scenario) or a slightly reduced (SRES B2 emission scenario) probability of wind damage, scenarios based on the ECHAM4/OPYC3 GCM indicated increased probability of wind damage. The assessment should, however, be reviewed as the simulation of forest growth under climate change as well as climate change scenarios are refined.