Dissolution of secondary copper sulphides using complex-forming agents (EDTA,EDA). Part II: Chalcocite dissolution in EDTA and EDA

This work is immediate continuation of Part I, using an identical method and evaluation for kinetic studies. The systems chalcocite-ethylene diamine tetra-acetic acid and chalcocite-ethylene diamine were studied. It was necessary to refine the geometrical model method for chalcocite in order to establish dissolution kinetics of polydispersions. This work confirms that chalcocite leaching proceeds through covellite even in the medium of complex-forming agents and kinetic equations for both leaching stages were evaluated with an attempt at physical interpretation.     

U-Pb dating of an early paleozoic bimodal magmatism in the french Massif Central and of its further metamorphic evolution

In the Marvejols area (Southern french Massif Central), the gneissic Marvejols supergroup is overthrust on the metasedimentary “Série du Lot”, deposited in part prior to 540 Ma. The allochtonous terranes are characterized by the occurrence of a leptyno-amphibolitic group, a complex association of mafic and felsic rocks of igneous and sedimentary derivation. A 480±10 Ma age has been obtained by U-Pb dating of zircons, for the crystallization of both mafic and felsic meta-igneous rocks. These rocks were emplaced during an important extensional tectonics. Relics of eclogites, pyrigarnites, coronite gabbros and HP-trondhjemites are clear evidence for a further HP-HT event dated at 415±6 Ma on zircons from a HP trondhjemite. Subsequently, the Marvejols supergroup underwent an amphibolite facies metamorphism with incipient mobilization dated at 345±10 Ma. Rifting and thinning of the continental crust in Cambro-Ordovician times appears to be a major geodynamic feature which could account for the thermal events often referred to the “Caledonian” orogeny. The Silurian (415 Ma) age of the HP episode is clearly older than the main Variscan tectonometamorphic event; it is in agreement with Rb-Sr dating of the Moldanubian granulites and with some radiometric data from Southern Brittany (France). These results point to a compressive phase, probably in a subduction context, in view of the high pressures reached (15–20 Kb), after the Cambro-Ordovician distensive phase. The main final tectono-metamorphic paroxysm (blocking of subduction process and continental collison ?) is not prior to the end of Devonian (340–350 Ma) and is related to the Variscan orogeny s.s     

Neotectonics of the Pontides: implications for ‘incompatible’ structures along the North Anatolian fault

Data for the post-Serravallian, ‘neotectonic’ evolution of the Pontides in northern Turkey indicate predominant ENE-WSW shortening with complementary NNW-SSE extension. We present a new fault plane solution for the Bartin earthquake (3 September 1968) and compare its mechanism with the movement picture of other neotectonic faults in the Pontides and northern Greece together with that of the Thessaloniki earthquake (20 May 1978). The general strain pattern exhibited by these structures agrees remarkably well with that inferred from early Tortonian-early Pleistocene structures reported from within the North Anatolian fault zone, which have been interpreted as indicating a possible reversal of the sense of movement along the North Anatolian transform fault. Here, we argue that such ‘incompatible’ structures may be related to the overall E-W shortening of Anatolia and the southern parts of the Black Sea resulting from the sideways continental escape from around the African and the Arabian promontories, rather than to hypothetical reversal of motion along the North Anatolian fault, for which there is no evidence other than the above-mentioned ‘incompatible’ structures. This new model also has important implications for seismicity and earthquake risk in regions contained within the southern part of the Black Sea plate.     

Earthquakes in the Czech Republic and Surrounding Regions in 1995–1999

In the time span from January 1995 to December 1999 the Czech National Seismological Network (CNSN), consisting of ten permanent digital broadband stations, several local networks and two data centers, detected and recorded 9530 regional natural seismic events, 27 greater than magnitude 2. Most of these events were located by the Czech Seismological Service (CSS), and the most prominent of them were analyzed in detail. A large number of quarry blasts were recorded as well but were not included in the analysis. We provide basic information on the configuration of the CNSN and on the way of routine data processing employed by the CSS in this paper. The over-all regional seismicity monitored by the CNSN in 1995–1999 is briefly reviewed. The main results of observations and evaluation of the local (NW-Bohemia/Vogtland, South Bohemia, Sudeten) and induced (Kladno, Píbram, Upper Silesia, Lubin/Poland) seismic activity within this period are presented in a condensed form. Finally, a summary on macroseismic observations on the territory of the Czech Republic in 1995–1999 is also presented.     

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.     

Numerical Modeling of the Ston-Slano (Croatia) Aftershock Sequence

The rate of aftershock occurrence after the M6 Ston-Slano (Croatia) earthquake is modeled as the Epidemic Type Aftershock Sequence (ETAS). Increase of the modeled cumulative number of aftershocks with time was fitted to observations by the least-squares criterion using the combined grid-search and Monte-Carlo approach. This enabled not only the estimation of the most probable ETAS parameters, but also the determination of their confidence limits, as well as the estimation of the bias between them. It has been found that the bias is significant for some of the parameter pairs, regardless of the threshold magnitude assumed. Residual analyses revealed that all strong aftershocks (M _L 4.5) occurred during the periods of normal to high aftershock activity. There were two periods of quiescence in the sequence, both of which were followed by a strong aftershock.     

Comparative Analysis of Type ii Bursts and of Thermal and non-Thermal Flare Signatures

The relationship between metric type II radio bursts and solar flares is studied. Well-defined correlations between the properties of type II bursts and the characteristics of associated microwave and soft X-ray bursts are established in two entirely independent data sets. It is shown that the correlations are strongly affected by the wide range of coronal Alfvén velocities involved, comprising values from only 150 up to 800 km s^–1, with a typical value of 400 km s^–1. After careful data analysis it was inferred that type II bursts are more closely related to the soft X-ray bursts than they are to microwave bursts. The correlations indicate that type II burst shocks are preferably generated by flares with a relatively strong thermal component, and that the shocks are probably ignited by the plasma expansion associated with the 'evaporation' process in the transition region. Although the results imply that the majority of metric type II bursts are caused by flares, a simple geometrical consideration shows that a fraction of non-flare type II bursts cannot be explained by behind-limb events and that roughly 10% of metric type II bursts should be attributed to non-flare coronal mass ejections.