Geochemical Characteristics of Apatite in Heavy REE‐rich Deep‐Sea Mud from Minami‐Torishima Area,Southeastern Japan

We have conducted geochemical and mineralogical investigations of the rare earth and yttrium (REY)‐rich mud from the Minami‐Torishima area in the Pacific in order to clarify the concentration of REY and their host‐phase in the mud. X‐ray diffraction analysis shows that the mud is mainly composed of phillipsite, fluorapatite, quartz, albite, illite and montmorillonite. Whole‐rock CaO, P₂O₅ and total REY contents of the mud are positively correlated. Relative abundance of apatite is also positively correlated to P₂O₅ and total REY contents. These correlations suggest that apatite is the main host of the P₂O₅ and REY in the mud. We make in situ compositional analyses of constituent minerals in the REY mud. The results show that the apatite is abundant in REY (9300–32,000 ppm) and is characterized by a negative Ce anomaly and enrichment in heavy rare‐earth elements. This abundance and composition of REY of the mud is similar those of fish debris apatites. In contrast, phillipsite is less abundant in REY (60–170 ppm). Therefore we conclude that the main REY host phase of the mud is apatite.     

Classification of Tsunami and Evacuation Areas

On March 11, 2011, a large earthquake that occurred offshore the north-east coast of Japan generated a large tsunami which devastated extensive areas of the Tohoku coastline. Despite Japan being considered a country well prepared for these types of disasters, large casualties were recorded, with numerous discussions amongst the Japanese coastal engineering community ensuing. As a result, two different levels of tsunamis have been proposed and now recognized in Japan, depending on the frequency of such extreme events. The idea that hard measures can protect the lives of inhabitants of coastal areas has been abandoned, and these measures are only considered to be effective in protecting properties against the more frequent but lower magnitude events. Soft measures should always be used to protect against the loss of lives, and to this respect, the authors of the paper propose the introduction of a Classification of Evacuation Areas, to show which of these should be prioritized by residents as they seek to evacuate.     

Global variation in the atmospheric electric field

Summary An analysis of the global nature of the atmospheric electric field is presented on the basis of comparison of measurements on the research vessel, Hakuho-Maru, on the Mid- and South-Pacific Ocean, with those at Syowa Station in Antartica and on two vessels on the Mid-Atlantic Ocean. The comparison of daily averages gave a different type of latitude dependence, which was characterized by a gradual decrease toward the antarctic region. Diurnal variations at these globally representative stations on the same day were checked with each other for the first time, and the correlation between them was found much higher than that between land stations. The regional effect, which might depend on the distance from the thunderstorm area, was not evidently detected. So the influence of the generator area was considered to propagate over the entire globe without significant attenuation.

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Zusammenfassung Auf der Grundlage von Vergleichen zwischen Messungen an Bord des Forschungsschiffes Hakohu-Maru im mittleren und südlichen Pazifischen Ozean, an der antarktischen Forschungsstation Syowa und an Bord von zwei Forschungsschiffen im mittleren Atlantik wird eine Analyse der weltweiten Natur des luftelektrischen Feldes vorgelegt. Der Vergleich von Tagesmitteln ergab eine spezielle Abhängigkeit von der geographischen Breite, gekennzeichnet durch eine allmähliche Abnahme in Richtung auf den antarktischen Bereich. Die Tagesgänge an diesen weltweitrepräsentativen Stationen wurden zum ersten Mal untereinander für jeweils die gleichen Tage verglichen. Es wurde gefunden, dass die Korrelation zwischen ihnen weitaus grösser war als sie zwischen Landstationen ist. Ein regionaler Effekt, vermutbar in der Form einer Abhängigkeit von der Entfernung zur Gewitterzone, wurde nicht sicher gefunden. Deswegen wird angenommen, dass die Auswirkungen des Generatorbereichs sich über die gesamte Erde ohne merkliche Verminderung erstrecken.

     

Arsenic species and their accumulation features in green turtles (Chelonia mydas)

Total arsenic (As) and its compounds were determined in liver, kidney, muscle, and stomach contents of green turtles (Chelonia mydas). Total As concentrations in the muscle were higher than those in the kidney and liver. Arsenobetaine (AB) was the predominant compound in all the three tissues and its levels were positively correlated with total As concentrations. This indicates that AB greatly contributes to As accumulation in green turtles. Higher concentrations of remaining As in the sample after extraction were detected in the liver, implying that lipid-soluble or protein bound As compounds accumulate in the liver of green turtles. Total As levels in tissues showed significant negative correlations with standard carapace length. The size-dependence of As accumulation in green turtles may be related to their feeding habit, shifting from carnivore to herbivore at different growth stages. Concentrations of AB and dimethylarsinic acid (DMA) were low in the stomach contents but high in the tissues, implying bioaccumulation of these arsenicals in green turtles.     

Characteristics of planetary-scale waves simulated by a new venusian mesosphere and thermosphere general circulation model

We have developed a new general circulation model (GCM) for the venusian mesosphere and thermosphere (80-about 180 km). Our GCM simulations show that winds in the subsolar-to-antisolar direction (SS–AS) are predominant above about 90 km. A weak return flow of the SS–AS is seen below about 90 km. We performed GCM simulations imposing the planetary-scale waves (thermal tides, Rossby wave, and Kelvin wave) at the lower boundary. Although the diurnal and semidiurnal tides are damped below 95 km, the Rossby wave propagates up to around 130 km. However, the amplitude of the Rossby wave is too small (<1 m/s) to affect the general circulation. On the other hand, the Kelvin wave propagates up to about 130 km with a maximum zonal wind fluctuation of approximately 5.9 m/s on average. The amplitude of the Kelvin wave sometimes exceeds 10 m/s around the terminator. The Kelvin wave causes a temporal variation in the wind velocity at the altitude of the O₂-1.27 μm nightglow emission (about 95 km). Using a newly developed 1-D nightglow model and the composition distribution calculated from our GCM, we investigated the impact of the Kelvin wave on the nightglow distribution. Our results suggest that the Kelvin wave would cause temporal variations in the nightglow emission in the 23:50–00:20 LT region with an intensity of 1.1–1.3 MR and a period of approximately 4 days.     

Chemical overprinting of magmatism by weathering: A practical method for evaluating the degree of chemical weathering of granitoids

Quantitative determination of the degree of chemical weathering of rocks is a fundamental task in environmental and engineering geology, and many weathering indices based on whole-rock chemistry have been proposed. However, most classical indices are of limited application to granitoids in a wide area, because these lithotypes generally exhibit wide chemical variation arising from their petrogenesis. The chemical evolution produced during rock weathering, therefore, overprints pre-existing magmatic chemical variation. This problem can cause many classical weathering indices to yield misleading results. This study proposes a method that compensates for the influence of petrogenesis on calculation of the weathering index. The method is based on a bivariate plot of the magmatic chemical variation (MCV) in granitoids, and the degree of chemical weathering (DCW). The MCV axis must be based on an element that reflects magmatic processes and is also relatively immobile during rock weathering. In this study TiO₂ contents are utilized for the MCV. The DCW axis is fundamentally defined by the ratios of more-mobile to less-mobile elements during weathering, and hence many classical indices can be applied. The improved value of the degree of chemical weathering (DCW_i) for a weathered rock is derived by:

DCWi=s×(MCVCV-MCV₁)+DCW₁${\text{DCW}}_{\text{i}}=\text{s}\times ({\text{MCV}}_{\text{CV}}-{\text{MCV}}_1)+{\text{DCW}}_1$

where MCV₁ is the measured composition (e.g. TiO₂ content) of the weathered rock. DCW₁ denotes the ratios of more-mobile to less-mobile elements of the weathered rock. The “s” parameter is the slope of the least square linear regression for fresh granitoids in the MCV–DCW relationship. MCV_CV is a correction factor which is given by the average point on the MCV axis (e.g. average TiO₂) of the fresh rocks. This method is useful for evaluating the degree of weathering of various granitoids, and enhances the practical application of many weathering indices.     

Wet surface resistance of forest canopy in monsoon Asia: Implications for eddy‐covariance measurement of evapotranspiration

During the Asian monsoon period, intense precipitation commonly occurs for an extended period in accompaniment with a reduction in solar radiation. This suggests that wet surface evapotranspiration is an important contributor to the total evapotranspiration. Therefore, investigating evapotranspiration over a wet canopy surface is critical to achieve a better understanding of water and energy cycles in Asia. In this study, we estimated surface resistances under wet conditions in a mixed forest influenced by the East Asian monsoon system. We showed that the surface resistance had a non‐negligible magnitude of about 30 sm^?1 even under wet conditions. We also found that the ratio between the actual and potential evapotranspiration depended on the friction velocity regardless of the time of day. Our analyses suggest that this dependency is tightly related to the underestimation of turbulent fluxes by the eddy‐covariance system under wet surface conditions. Together, our findings suggest that the wet surface resistance, although small, should be considered in simulating evapotranspiration because the forest ecosystem is strongly coupled to the overlying atmosphere. This could significantly improve the shortcomings of evapotranspiration measurement and modeling in Asian forest canopies influenced by the monsoon system. Copyright © 2012 John Wiley & Sons, Ltd.