AFM study on surface nanotopography of matrix olivines in Allende carbonaceous chondrite

By means of nanoscale surface observation, we have proposed a new approach for investigating fine crystals of cosmic materials to reveal their origin and growth conditions. Several different morphologies of polyhedral fine olivines with faceted faces have been found in Allende carbonaceous chondrite (4.5 byr in geochronological age). In the present work, molecular level topography of the faceted matrix olivine by Atomic Force Microscopy (AFM) has successfully been performed. The matrix olivine found to have preserved growth step pattern on its surface even though quite long time has passed since they formed in the early Solar System. The surface pattern suggests that the faceted matrix olivine could have been condensed from the gas phase, and possibly that these olivine crystals had continued to grow under a rapid cooling condition (0.1-1 K s⁻¹). The estimated cooling rate agrees well with predictions based on hypothetical rapid heating and cooling events such as shock wave heating.     

Internal characteristics and numerical analysis of plunging breaker on a slope

Many investigations about the direct measurements of velocities to clarify the internal mechanism of the breaker have been carried out as a result of recent progress in the measuring techniques.This research attempts to clarify the breaking wave transformation system on a slope by an experiment and numerical analysis. In an experiment, the velocities in the surf zone were measured directly using an electromagnetic current meter, and the space distribution characteristic of the vorticity ω = (∂u/∂y − ∂u/∂x) and the skewness γ = (∂u/∂y + ∂u/∂x) were examined. Also, occurrence situations of the vortices at the time of water mass inrush were measured by video tape recorder (VTR) image processing. However, because the breaker is a violent phenomenon that is entrained with plentiful bubbles, the extent to which we can clarify breaker transformation in experiments is limited. Numerical simulations are substituted for experiments as a method to clarify breaker transformation.In numerical analysis, finite amplitude wave analysis based on the potential theory (non-viscous fluid) is possible before wave breaking; however, the analysis must take into account the viscous fluid after breaking. So, we use the Reynolds equations to develop a numerical simulation system of the breaker transformation on a sloping bottom. The numerical energy dissipation model of the breaker was compared to the experimental results, and a modified Simplified Marker and Cell (SMAC) method is presented. The internal characteristics of the breaker transformation are described using application examples.     

Isotope dilution sector-field inductively coupled plasma mass spectrometry combined with extraction chromatography for rapid determination of 241Am in marine sediment samples: A case study in Sagami Bay, Japan

²⁴¹Am is a useful tracer for understanding biogeochemical processes in the marine environment. ²⁴¹Am also poses a potential radiation threat to human health due to the continuous increase of its concentration in the global environment. We report a rapid analytical method for determining ²⁴¹Am in marine sediments using isotope dilution sector-field inductively coupled plasma mass spectrometry (SF-ICP-MS) combined with a high-efficiency sample introduction system (APEX-Q). A selective CaF₂ co-precipitation procedure followed by TRU extraction chromatography was employed to effectively remove the major sediment matrix and to pre-concentrate ²⁴¹Am. We achieved an extremely low detection limit of 0.32 fg/g or 0.041 mBq/g (for 1 gram sediment), which is better than that of alpha spectrometry, and it allowed the accurate determination of ²⁴¹Am in low-level marine sediment samples. The accuracy and precision of the developed analytical method was evaluated using a laboratory prepared Am isotope standard solution and Ocean Sediment reference material (IAEA-368). The results were satisfactory. For sediment samples, overall chemical recoveries varied from 60–90%. The developed method was applied to the study of ²⁴¹Am depth distribution in Sagami Bay, Japan, where we observed different depth profiles between ²⁴¹Am activity and ^239+240Pu activity.     

Implementation of an integrated vulnerability and risk assessment model

An integrated vulnerability and risk assessment model (IVR) is proposed. The proposed model is a composite index that assesses the relationships among four critical components, namely exposure, hazard, vulnerability and capacities and measures, and how these can be used to illustrate the integrated risk and vulnerability situation of an area. These factors are assessed using individual variables. Fifty-four variables, objectively decided upon, were used to measure the contribution of each component factor. The general characteristics of vulnerability, risk, exposure and capacities and measures are well known; however, the relative importance of each variable and their inter-relatedness, in measuring risk and vulnerabilities, as demonstrated by the IVR; and how these in turn affect the impacts of natural hazards, are still debatable. The IVR though provides a valid, reliable and sensitive tool, which can be used to further explore these relationships. Through robust testing and application, subjectivity in the selection of variables can be reduced. Moreover, through the establishment of a database for data collection and storage, objectivity (reliability) can be achieved as well as, availability of the requisite data inputs. The sensitivity of the model allows for the quick identification of strategic action, which will ultimately lead to hazard loss reduction. The values yielded for each component factor can help decision-makers in the allocation of scarce developmental funds as well as identify trends in levels of risk, vulnerability, exposures and capacities and measures as well as determine areas where mitigation strategies are needed most.     

Radium isotopes in coastal and open ocean surface waters of the Western North Pacific

Using manganese-impregnated fiber extraction and high-efficiency gamma counting techniques, we measured the distribution of ²²⁸Ra and ²²⁶Ra in surface waters near the coast of Japan and in the western North Pacific. There is no evidence in our data that any significant amount of ²²⁸Ra is added to open ocean surface waters from the coastal waters around Tokyo Bay. High ²²⁸Ra concentrations (> 10 dpm/10³ kg), were observed along the Kuroshio Current as compared to < 2.5 dpm/10³ kg between 10° and 30°N of the central gyre, and hence the major source of ²²⁸Ra in the surface water is likely to be the East Asian continental shelf zones. A simple one-dimensional eddy diffusion and advection model is used to explain the observed decrease of ²²⁸Ra from coast to the open ocean. The model results indicate two mixing regimes across the Kuroshio Current System with apparent eddy diffusion coefficients of K_y = 4 × 10⁵ cm² s⁻¹ at distance y < 200 km from the coast, and K_y = 4 × 10⁷ cm² s⁻¹ at y > 200 km. Along 40°N where an eastward flow of the ‘Kuroshio Extension’ prevails, an advective flow of > 0.1 knot is consistent with the observation of nearly constant ²²⁸Ra along the track.The geographical distribution pattern of ²²⁸Ra is clearly different from that of atmospherically derived ²¹⁰Pb. Thus the ²²⁸Ra in surface water serves as a useful tracer that accompanies fluvially and coastally derived elements during their subsequent lateral transport toward the central gyre.     

Quaternary volcanism of the Japanese Islands

Abstract Quaternary volcanism of the Japanese Islands is examined from the perspective of experimental petrology, geographic distribution of volcanoes and spatial geochemical variations. The dehydration of amphibole and chlorite at a 110 km depth and of phlogopite at ∼180 km in the downdragged hydrous mantle layer would result in the occurrence of two volcanic chains parallel to the trench axis. Long-term subduction of the old Pacific plate and recent subduction of the young Philippine Sea plate beneath East Japan and West Japan volcanic belts respectively, would be critical for the significant difference in intensity, style and geochemistry of Quaternary volcanism between the two volcanic belts. The geochemistry of volcanic rocks in Northeast Japan and those in the Ryukyu arc is typical of 'island-arcs' having low LIL/HFS element ratios, while alkalic basalts along the Japan Sea coast side in Southwest Japan have high LIL/HFS ratios similar to intra-continental or oceanic island basalts. Across-arc variations in eruptive volume and distributional density of volcanoes and in geochemistry are documented in Northeast Japan and are well explained by the decreasing degrees of partial melting toward back-arc side, and the difference in geochemistry of fluids supplied by the downdragged hydrous layer.     

Size distributions of aerosol number concentrations and water-soluble constituents in Toyama, Japan: A comparison of the measurements during Asian dust period with non-dust period

Size-separated aerosol number concentrations and water-soluble constituents were measured in Toyama, the Hokuriku district, near the coast of the Japan Sea, during the spring and summer in 2003. The number concentrations of coarse particles were significantly high in April, which was due to Asian dust events called Kosa in Japanese. Particulate nssCa²⁺, which is mostly present in the coarse-mode particles, was significantly high in April. On the other hand, the concentrations of NH₄⁺ and nssSO₄²⁻, which mainly exist as the accumulation-mode particles were not high in April. The mass-size distributions of water-soluble constituents were compared with the size-separated number concentrations of particles. Backward trajectory analysis was also employed to examine the transport process of the air mass in Toyama.     

230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.