The High-Resolution Solar Reference Spectrum between 250 and 550 nm and its Application to Measurements with the Ozone Monitoring Instrument

We have constructed a new high resolution solar reference spectrum in the spectral range between 250 and 550 nm. The primary use of this spectrum is for the calibration of the Dutch – Finnish Ozone Monitoring Instrument (OMI), but other applications are mentioned. The incentive for deriving a new high resolution solar reference spectrum is that available spectra do not meet our requirements on radiometric accuracy or spectral resolution. In this paper we explain the steps involved in constructing the new spectrum, based on available low and high resolution spectra and discuss the main sources of uncertainty. We compare the result with solar measurements obtained with the OMI as well as with other UV-VIS space-borne spectrometers with a similar spectral resolution. We obtain excellent agreement with the OMI measurements, which indicates that both the newly derived solar reference spectrum and our characterization of the OMI instrument are well understood. We also find good agreement with previously published low resolution spectra. The absolute intensity scale, wavelength calibration and representation of the strength of the Fraunhofer lines have been investigated and optimized to obtain the resulting high resolution solar reference spectrum.     

Porphyry Molybdenum Prospectivity in the Zhongdian Arc,SW China: Use of Singularity and Factor Analyses for Resource Assessment

Natural Resources Research - The Zhongdian arc is an important mineral province in southwest China that hosts significant Cu- and Mo-rich ore deposits. These are mainly present as Late Triassic...     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

A first Holocene leaf wax isotope-based paleoclimate record from the semi-humid to semi-arid south-eastern Caucasian lowlands

The Holocene paleoclimate of the Caucasus region is rather complex and not yet well understood: while existing studies are mainly based on pollen records from high-altitude and humid lowland regions, no records are available from the semi-humid to semi-arid south-eastern Caucasian lowlands. Therefore, this study investigated compound-specific δ²H and δ¹³C isotopes of leaf wax biomarkers from Holocene floodplain soils in eastern Georgia. Our results show that the leaf wax δ²H signal from the paleosols mostly reflects changes in the moisture source and its isotopic composition. Depleted δ²H values before ~8 cal ka bp change towards enriched values after ~5 cal ka bp and become again depleted after ~1.6 cal ka bp. This trend could be caused by Holocene changes of the isotopic compositions of the Black and eastern Mediterranean Sea, and/or by varying contribution of both moisture sources linked with the North Atlantic Oscillation. The leaf wax δ¹³C signal from the paleosols directly indicates varying local water availability and drought stress. Depleted δ¹³C values before ~8 and after ~5 cal ka bp indicate wetter local conditions with higher water availability, whereas more enriched values during the middle Holocene (~8 until at least 5 cal ka bp ) indicate drier conditions with increased drought stress.     

Assessment of extreme drought and human interference on baseflow of the Yangtze River

Attention has been given to baseflow in large rivers, but up to now, no study on baseflow for the Yangtze River in combination with extreme drought and extensive human activities has been carried out. Discharge data in 2000–2005 and in the extreme drought years, 1978 and 2006, at stations along the main stream, lakes and distributaries of the Yangtze River were collected to analyse the features of baseflow in 2006 by using baseflow separation technique, HYSEP. It can be seen that the baseflow relative to the streamflow in 2006 was greater than those in other years. The variation of baseflow discharge in the Upper Yangtze River Stream (UYRS) was larger than that in the Mid‐Lower Yangtze River Stream (MLYRS). Human activities in MLYRS are more intensive than that in the UYRS and the baseflow discharge was greater. The baseflow is influenced by the extreme climate and human activities along the Yangtze River with the former being the dominant factor in 2006. The contribution of human interference to baseflow discharge was about 10% in 2006. Copyright © 2009 John Wiley & Sons, Ltd.     

Generalized LSG models with spatially varying Coriolis parameter

In this paper, we derive and study approximate balance models for nearly geostrophic shallow water flow where the Coriolis parameter is permitted to vary across the domain as long as it remains nondegenerate. This situation includes, for example, the β-plane approximation to the shallow water equations at mid-latitudes. Our approach is based on changing configuration space coordinates in the underlying variational principle in such a way that consistent asymptotics in the transformed Lagrangian leads to a degenerate Lagrangian structure. In this paper, we restrict our attention to first-order models. We show that the resulting models can be formulated in terms of an advected potential vorticity with a nonlinear vorticity inversion relation. We study the associated solvability conditions and identify a subfamily of models for which these conditions are satisfied without additional restrictions on the data. Finally, we provide the link between our framework and the theory of constrained Hamiltonian systems.     

Tendances et ruptures au niveau des pluies journalières extrêmes en Côte d'Ivoire (Afrique de l'Ouest)

Résumé

Le changement climatique est une réalité qui affecte plusieurs variables climatiques dont les précipitations. Néanmoins, son impact sur les évènements extrêmes et en particulier sur les pluies journalières extrêmes n'est pas encore certain car peu de travaux y ont été consacrés en Afrique de l'Ouest. Dans ce contexte, il a été proposé de détecter d'éventuels tendances et ruptures dans les propriétés statistiques (moyenne, variance) des pluies journalières extrêmes à l'aide de tests statistiques locaux et régionaux. Pour détecter ces changements, les indices caractérisant la pluie maximale journalière annuelle (PJmaxan), le nombre annuel de jours de pluie dépassant 50 mm (NJsup50) et la contribution des pluies dépassant 50 mm dans les cumuls annuels (R(PJsup50/Pan)) ont été définis. L'analyse de 44 postes pluviométriques en Côte d'Ivoire sur la période 1942–2002 ne montre pas de changement généralisé ni en moyenne, ni en variance. Toutefois, en subdivisant la Côte d'Ivoire en régions climatiques homogènes, des tendances à la baisse ont été observées dans les régions IV (au Nord) et II (au Sud-Est).

Editeur Z.W. Kundzewicz; Assistant editeur G. Mahé

Citation Goula, A.B.T., Gneneyougo Soro, E., Kouassi, W. et Srohourou, B., 2012. Tendances et ruptures au niveau des pluies journalières extrêmes en Côte d'Ivoire (Afrique de l'Ouest). Hydrological Sciences Journal, 57 (6), 1067–1080.     

Detection of smectites in ppm and sub-ppm concentrations using dye molecule sensors

Methylene blue and rhodamine 6G were used as molecular sensors for the spectrophotometric titrations of the aqueous colloids of clay minerals (montmorillonite, illite and kaolinite). The dyes adsorbed on colloid particles form molecular aggregates, which exhibit spectral properties significantly different from those of dye solutions. Spectrophotometric titrations provide the most sensitive detection of smectites in aqueous colloids (sub-ppm concentrations); and the sensitivity further increases using second derivative spectroscopy. The endpoint of spectrophotometric titrations can be used for the determination of exchange capacity of the mineral in colloids and in this way to estimate its amount. The method is selective only to expandable clays, which was proven by experiments with kaolinite and illite. Spectrophotometric titrations have promising future in the analysis of clays and can be applied in many fields of geology, mineralogy, chemistry, material sciences or in industry. Its application may expand to the analysis of other nanomaterials built from charged particles and exhibiting metachromasy in the systems with organic dyes.