Mechanisms of rapid cooling in underwater welding

Two inherent problems, rapid cooling and hydrogen embrittlement, associated with underwater ‘wet’ welding remain unsolved at the present time. Weld defects induced by rapid cooling usually appear in underwater welds. An understanding of the basic mechanisms is probably important and necessary in order to establish solutions to the problems of rapid cooling. Three types of weld defects related to rapid cooling during underwater welding are presented. A discussion on the thermal behaviour of underwater welding is then introduced. This discussion covers some important thermal-physical areas which control the cooling rate during underwater welding. It includes underwater bubble dynamics, underwater arc-heat distribution, Joule heating, heat input mechanism and boundary heat loss mechanism. Several important new concepts of reducing the effect of rapid cooling during underwater welding are finally recommended.     

Terrestrial heat flow in the Celebes and Sulu Seas

Five heat flow measurements were made in the Asiatic Mediterranean Sea; two in the Celebes Sea and three in the Sulu Sea. The mean of all five values of 2.0 cal/cm² sec is significantly greater than the over-all mean heat flow value for the oceans and is close to the mean value for marginal seas. The measurement indicate that there may be a difference in the flow of heat through the two seas.Contribution of the Scripps Institution of Oceanography, new series.     

High mercury levels in hair samples from residents of Taiji, a Japanese whaling town

We investigated the mercury concentrations in red meat from pilot whales consumed by some residents of the Japanese whaling town, Taiji, and in hair samples from 50 residents for their maker of mercury burden. The methyl mercury (M-Hg) level in the red meat was 5.9 μg/wet g, markedly higher than the US FDA action level and Cordex Alimentarius guideline level for predatory fish (1.0 μg/wet g). The average level of total mercury (T-Hg) in the hair from residents who ate whale meat more than once a month was 24.6 μg/g, whereas the average from the residents who did not consume any whale meat was 4.3 μg/g. The T-Hg concentrations in the hair from three donors exceeded 50 μg/g, the level for NOAEL set by WHO. The T-Hg level found in the Taiji whale meat consumers was markedly higher than that observed in the Japanese population overall (about 2 μg/g).     

Intrusion of less saline shelf water into the Kuroshio subsurface layer in the East China Sea

The possible origin and cause of the less saline shelf water detected in the Kuroshio subsurface layer around the shelf edge of the East China Sea are investigated using observational results obtained in May 1998–2001 in conjunction with a dataset archived by Japan Oceanographic Data Center and a numerical model. The observations show that subsurface intrusions of less saline water are always detected in May in layers above 24.5σθ isopycnal surface, and that salinity inversions (i.e., areas in which the less saline water lies beneath the saline water) are detected around the trough of the Kuroshio frontal eddy (or wave). Analyses of the archived dataset reveal that the isopycnal surface of 24.5σθ is the deepest layer of the Kuroshio pycnocline outcropping to the sea surface on the shallow shelf in early spring. Outcropping isopycnals above 24.5σθ encounter a less saline water plume originating from the Changjiang, especially in the western East China Sea. Thereafter, the less saline water moves along isopycnal layers and reaches the Kuroshio front around the shelf edge. Numerical models demonstrate that, when the frontal wave captures the less saline water, the shelf water takes the form of a salinity inversion in the trough because isohalines in the frontal wave have a phase lag between the upper and lower layers in consequence of the baroclinic instability.     

Estimation of heat discharge rates using infrared measurements by a helicopter-borne thermocamera over the geothermal areas of Unzen volcano, Japan

Unzen volcano is situated on Shimabara Peninsula, western Kyushu, Japan. On the flank of the volcano, the Obama, Unzen and Shimabara hot springs are aligned in a direction from the southwest to the northeast across the peak. At Obama and Shimabara, heat is transferred mainly by water flow. But at Unzen heat is transferred by the discharge of natural steam and by conduction as well as water flow. In order to estimate the heat discharge by mechanisms other than water flow, infrared measurements by a helicopter-borne thermocamera were conducted over the Unzen hot spring area. The heat discharge was calculated from the thermal image by a method based on heat balance of the ground surface resulting in a value of 1.9 × 10⁶ cal/s (7.9 MW). The heat discharged by all mechanisms including that by water flow is estimated to be 5.0 × 10⁶ cal/s (21 MW). Similar preliminary estimates have been made for heat discharge at the Obama and Shimabara hot springs giving values of about 1.2 × 10⁷ cal/s (50 MW) and 1.0 × 10⁵ cal/s (0.4 MW), respectively. These values indicate that the heat discharge decreases with distance from the southwest to the northeast direction across the volcano. The total heat discharge from three hot spring areas on Unzen volcano is about 1.7 × 10⁷ cal/s (71 MW).The heat balance method appears useful for quantitative analysis of regional trends but its accuracy may not be always sufficient for detailed surveys. Several methods of determining heat flow, including the heat balance method, were compared at a test field in the Unzen hot spring area. The values obtained by the heat balance method coincide roughly with the other results but more detailed analysis is necessary to improve the accuracy of current methods of geothermal measurements.     

Effectivity of dissolved SF6 tracer for clarification of rainfall–runoff processes in a forested headwater catchment

Understanding rainfall‐runoff processes is crucial for prevention and prediction of water‐related natural disasters. Sulfur hexafluoride (SF₆) is a potential tracer, but few researches have applied it for rainfall‐runoff process studies. We observed multiple tracers including SF₆ in spring water at 1‐ to 2‐hr intervals during rainstorm events to investigate the effectivity of SF₆ tracer in rainfall–runoff studies through the clarification of rainfall–runoff process. The target spring is a perennial spring in a forested headwater catchment with an area of 0.045 km² in Fukushima, Japan. The relationship between the SF₆ concentration in spring water and the spring discharge volume was negative trend; the SF₆ concentration in spring water becomes low as the spring discharge volume increases especially during rainstorms. The hydrograph separation using SF₆ and chloride ion tracers was applied for determining the contribution of principal sources on rainfall–runoff water. It suggested more than 60% contribution of bedrock groundwater at the rainfall peak and high percentage contribution continued even in the hydrograph recession phase. Based on observed low SF₆ concentration in groundwater after heavy rainfall, the replacement of groundwater near the spring with bedrock groundwater is indicated as a mechanism for water discharge with low SF₆ concentration during rainfall events. Consequently, rainstorm events play an important role as triggers in discharging water stored in the deeper subsurface area. In addition, SF₆ tracer is concluded as one of the strongest tracers for examining rainfall–runoff process studies. And, therefore, this study provided new insights into the dynamics of groundwater and its responses to rainfall in terms of SF₆ concentration variance in water in headwater regions.     

Deposition rates of polysilicic acid with up to 10 M calcium ions

Cementitious materials used for radioactive waste repository construction complicate the performance assessment of radioactive waste systems because the use of cement may greatly alter the pH (8–13) of groundwater and release constituents such as calcium ions. Under such conditions, it is important to clarify also the dynamic behavior of silica (silicic acid), in order to evaluate the alteration in the chemical and physical properties of the fractured layer or the host rock surrounding the repository. Since silica undergoes polymerization, precipitation or dissolution depending on the pH and/or temperature, the behavior of silica would be greatly complicated in the presence of other ions. This study is focused on the deposition rates of polysilicic acid and soluble silicic acid with up to 10⁻³ M Ca ions. In the experiment, Na₂SiO₃ solution (250 mL, pH > 10, 298 K) was poured into a polyethylene vessel containing amorphous silica powder (0.5 g), and a buffer solution, HNO₃, and CaNO₃ as Ca ions were sequentially added into the vessel. The pH of the solution was set to 8. The silica, initially in a soluble form at pH > 10 (1.4 × 10⁻² M), became supersaturated and either deposited on the solid surface or changed into the polymeric form. Then the concentrations of both poly- and soluble silicic acid were monitored over a 40-day period. The decrease of polysilicic acid became slow with an increase in the concentration of Ca ions in the range of up to 10⁻³ M. In general, the addition of electrolytes to a supersaturated solution accelerates the aggregation and precipitation of polymeric species. However, the experimental result showed that polysilicic acid in the presence of Ca ions is apparently stable in solution, compared with that under a Ca-free condition. On the other hand, the concentration of soluble silicic acid in the presence of Ca ions immediately became metastable, that is, slightly higher than the solubility of soluble silicic acid. Its dynamic behavior was similar to that in the Ca-free condition.     

Hg, Zn and Cu levels in the muscle and liver of tiger sharks (Galeocerdo cuvier) from the coast of Ishigaki Island, Japan: relationship between metal concentrations and body length

We analyzed Hg, Zn and Cu concentrations in the liver and muscle of tiger sharks (Galeocerdo cuvier) from the coast of Ishigaki Island, Japan. The Hg concentration in the muscle increased proportionally with body length in the tiger sharks, whereas that in the liver increased rapidly after maturity (defined by a length of over 2.7 m). Muscle Hg levels were higher than liver concentrations in immature sharks, with the inverse trend observed in mature sharks. Notably, the Zn and Cu concentrations in the liver tended to decrease with increasing body length. This rapid increase in hepatic Hg concentration concurrent with the onset of maturity in sharks may result from the continuous intake of Hg via food and the slower growth of mature sharks. The high concentrations of the essential metals Zn and Cu in immature sharks may be explained by the physiological demands related to rapid growth.