Formal definition and dating of the GSSP (Global Stratotype Section and Point) for the base of the Holocene using the Greenland NGRIP ice core,and selected auxiliary records

The Greenland ice core from NorthGRIP (NGRIP) contains a proxy climate record across the Pleistocene–Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision. This climatic event is most clearly reflected in an abrupt shift in deuterium excess values, accompanied by more gradual changes in δ¹⁸O, dust concentration, a range of chemical species, and annual layer thickness. A timescale based on multi‐parameter annual layer counting provides an age of 11 700 calendar yr b2 k (before AD 2000) for the base of the Holocene, with a maximum counting error of 99 yr. A proposal that an archived core from this unique sequence should constitute the Global Stratotype Section and Point (GSSP) for the base of the Holocene Series/Epoch (Quaternary System/Period) has been ratified by the International Union of Geological Sciences. Five auxiliary stratotypes for the Pleistocene–Holocene boundary have also been recognised. Copyright © 2008 John Wiley & Sons, Ltd.     

Size and compositional constraints of Ganymede's metallic core for driving an active dynamo

Ganymede has an intrinsic magnetic field which is generally considered to originate from a self-excited dynamo in the metallic core. Driving of the dynamo depends critically on the satellite's thermal state and internal structure. However, the inferred structure based on gravity data alone has a large uncertainty, and this makes the possibility of dynamo activity unclear; variations in core size and composition significantly change the heat capacity and alter the cooling history of the core. The main objectives of this study is to explore the structural conditions for a currently active dynamo in Ganymede using numerical simulations of the thermal history, and to evaluate under which conditions Ganymede can maintain the dynamo activity at present. We have investigated the satellite's thermal history using various core sizes and compositions satisfying the mean density and moment of inertia of Ganymede, and evaluate the temperature and heat flux at the core-mantle boundary (CMB). Based on the following two conditions, we evaluate the possibility of dynamo activity, thereby reducing the uncertainty of the previously inferred interior structure. The first condition is that the temperature at the CMB must exceed the melting point of a metallic core, and the second is that the heat flux through the CMB must exceed the adiabatic temperature gradient. The mantle temperature starts to increase because of the decay of long-lived radiogenic elements in the rocky mantle. After a few Gyr, radiogenic elements are exhausted and temperature starts to decrease. As the rocky mantle cools, the heat flux at the CMB steadily increases. If the temperature and heat flux at the CMB satisfy these conditions simultaneously, we consider the case as capable of driving a dynamo. Finally, we identify the Dynamo Regime, which is the specific range of internal structures capable of driving the dynamo, based on the results of simulations with various structures. If Ganymede's self-sustained magnetic field were maintained by thermal convection, the satellite's metallic core would be relatively large and, in comparison to other terrestrial-type planetary cores, strongly enriched in sulfur. The dynamo activity and the generation of the magnetic field of Ganymede should start from a much later stage, possibly close to the present.     

Observational characteristics and possible asphericity of overluminous Type Ia supernovae

A few Type Ia supernovae (SNe Ia) have been suggested to be an explosion of a super-Chandrasekhar-mass white dwarf (WD) in order to account for their large luminosities, requiring a large amount of ⁵⁶Ni. However, the candidate overluminous SNe Ia 2003fg, 2006gz and (moderately overluminous) SN 1991T have very different observational features: the characteristic time-scale and velocity are very different. We examine if and how the diversity can be explained, by one-dimensional spherical radiation transport calculations covering a wide range of model parameters (e.g. WD mass). The observations of SN 2006gz are naturally explained by the super-Chandrasekhar-mass model. SN 1991T represents a marginal case, which may either be a Chandrasekhar or a super-Chandrasekhar-mass WD explosion. In contrast, the low velocity and short time-scale seen in SN 2003fg indicate that the ejecta mass is smaller than the Chandrasekhar mass, which is in apparent contradiction to the large luminosity. We suggest that the problem is solved if the progenitor WD, and thus the SN explosion, is aspherical. This may reflect a rapid rotation of the progenitor star, likely a consequence of the super-Chandrasekhar-mass WD progenitor. The observed differences between SNe 2003fg and 2006gz may be attributed to different viewing orientations.     

Small-scale mélange fabric between serpentinite block and matrix: Magnetic evidence from the Mitsuishi ultramafic rock body, Hokkaido, Japan

The Mitsuishi ultramafic rock body in Hokkaido, Japan, consists mainly of serpentinized peridotites that originated from a depleted mantle. This study aims to show new evidence of small-scale mélange fabric of serpentinite matrix in the rock body. Each serpentinite block in the serpentine matrix shows large and stable intensities of natural remanent magnetization (NRM). However, the directions of serpentinite blocks' NRM in the matrix are randomly scattered. A Curie temperature (Tc) of 580 °C corresponding to pure magnetite was also observed. Additionally, there is no evidence of heating over 580 °C after serpentinization. The blocks in the matrix must have obtained crystallization remanent magnetization (CRM) during serpentinization. The directions of the blocks' characteristic remanent magnetization (ChRM) are also scattered. It shows that serpentinite blocks were magnetized prior to uplifting. The results of the study indicate that the magnetic carrier of the serpentinite blocks in the matrix is mainly composed of magnetite, and it can keep original magnetization before uplifting. The results also imply that the scattering directions of NRM indicate the presence of small-scale mélange fabric of serpentinite matrix.     

Behavior of polycyclic aromatic hydrocarbons at impact shock: Its implication for survival of organic materials delivered to the early Earth

Polycyclic aromatic hydrocarbons (PAHs) with a hydrous or an unhydrous mineral matrix were impacted and analyzed, to study the behavior of PAHs against shock. Results of the shock experiments suggested that volatiles discharged from the hydrous mineral did not influence the behavior of PAHs against shock. The shocked samples contained unreacted starting PAHs, soot-like materials insoluble in dichloromethane, and secondarily formed PAHs with molecular weights ranging from 128 to 404. Approximately 95% of starting PAHs decomposed at ∼30 GPa and the dominant product was the soot-like materials. Formation mechanisms of the shock products were explained by reaction processes under static high pressure-temperature conditions (e.g., carbonization, radical addition reaction, ring cross linking, and methylation).We applied these results to estimate the survival degree of organic matter delivered by carbonaceous asteroids against their impact pressures at the accretion stage of early Earth. If we use a simplified homogeneous accretion model without atmosphere to represent the stage, the radius of Earth causing 30 GPa, the pressure at which PAHs almost decompose, was calculated as 2270 km (4.0 km s⁻¹ of impact velocity) for the impact of carbonaceous asteroids. In the case of impactors striking not land but oceans on the early Earth, the impact velocity for the decomposition of PAHs was estimated to be 6.0 km s⁻¹. These impact velocities should have been commonly realized on the early Earth, due to the airburst and the aerobreak of impactors in the dense atmosphere. The early Earth should have been a favorable environment for obtaining and maintaining a large quantity of prebiotic organic materials leading to life.     

Size distributions of aerosol number concentrations and water-soluble constituents in Toyama, Japan: A comparison of the measurements during Asian dust period with non-dust period

Size-separated aerosol number concentrations and water-soluble constituents were measured in Toyama, the Hokuriku district, near the coast of the Japan Sea, during the spring and summer in 2003. The number concentrations of coarse particles were significantly high in April, which was due to Asian dust events called Kosa in Japanese. Particulate nssCa²⁺, which is mostly present in the coarse-mode particles, was significantly high in April. On the other hand, the concentrations of NH₄⁺ and nssSO₄²⁻, which mainly exist as the accumulation-mode particles were not high in April. The mass-size distributions of water-soluble constituents were compared with the size-separated number concentrations of particles. Backward trajectory analysis was also employed to examine the transport process of the air mass in Toyama.     

230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.