Magmatic fluids of Tatun volcanic group,Taiwan

Two distinctive magmatic fluids were recognized in the Tatun volcanic group (TVG), Taiwan. One is a relatively reduced fluid represented by the fumarolic gases at Hsiao-you-ken (HYK) geothermal field. Another is an oxidized fluid containing high concentrations of HCl represented by the fumarolic gases at Da-you-ken (DYK). An intermediate gas was recognized at Gung-tze-ping (GTP) and She-hung-ping (SHP). The fumarolic gases at HYK and GTP possess the features of so-called primary steam generated on mixing of magmatic gas and meteoric groundwater. The fumarolic gases at DYK are a simple mixture between magmatic gas and water vapor of meteoric origin. The CO₂/H₂O molar ratio of the magmatic component in the fumarolic gases at DYK was estimated to be 0.018, meanwhile it was estimated to be 0.027 for the fumarolic gases at HYK and GTP, suggesting the magma beneath DYK is depleted in volatiles relative to the magma beneath HYK and GTP. The estimated CO₂/H₂O ratio for the magmatic component is comparable to that of some active volcanoes in Japan, suggesting the enrichment of volatiles in the magmas beneath TVG.     

Excessive degassing of Izu-Oshima volcano: magma convection in a conduit

Excess degassing of magmatic H₂O and SO₂ was observed at Izu-Oshima volcano during its latest degassing activity from January 1988 to March 1990. The minimum production rate for degassed magma was calculated to be about 1×10⁴ kg/s using emission rates of magmatic H₂O and SO₂, and H₂O and S contents of the magma. The minimum total volume of magma degassed during the 27-month period is estimated to be 2.6×10⁸ m³. This volume is 20 times larger than that of the magma ejected during the 1986 summit eruption. Convective transport of magma through a conduit is proposed as the mechanism that causes degassing from a magma reservoir at several kilometers depth. The magma transport rate is quantitatively evaluated based on two fluid-dynamic models: Poiseuille flow in a concentric double-walled pipe, and ascent of non-degassed magma spheres through a conduit filled with degassed magma. This process is further tested for an andesitic volcano and is concluded to be a common process for volcanoes that discharge excess volatiles.     

Petrographic features of a high-temperature granite just newly solidified magma at the Kakkonda geothermal field, Japan

A 3729-m-deep geothermal research well, WD-1a, provides us with a unique opportunity to study initial petrographic features of a high-temperature granite just after solidification of magma. The well succeeded in collecting three spot-cores of the Kakkonda Granite that is a pluton emplaced at a shallow depth and regarded as a heat source of the active Kakkonda geothermal system. The core samples were collected at the present formation temperatures of 370, 410 and over 500°C. These samples are granodiorite to tonalite consisting mainly of plagioclase, quartz, hornblende, biotite and K-feldspar. A sample collected at a formation temperature of over 500°C possesses the following remarkable petrographic features compared to the other two samples. Interstitial spaces are not completely sealed. K-feldspar exhibits no perthite by the exsolution of albite lamella. Quartz includes glassy melt inclusions without devitrification. Hornblende is less intensively altered to actinolite, and biotite is not altered. This study directly confirmed that perthite in K-feldspar is a recrystallization texture formed at 410–500°C based on a comparison of the in situ temperatures of the samples. Chemical compositions of minerals were analyzed to compare temperatures determined from geothermometers in several publications to the in situ temperatures of the samples.     

Mid–Cretaceous Episodic Magmatism and Tin Mineralization in Khingan-Okhotsk Volcano–Plutonic Belt, Far East Russia

Abstract: Age of magmatism and tin mineralization in the Khingan‐Okhotsk volcano–plutonic belt, including the Khingan, Badzhal and Komsomolsk tin fields, were reviewed in terms of tectonic history of the continental margin of East Asia. This belt consists mainly of felsic volcanic rocks and granitoids of the reduced type, being free of remarkable geomagnetic anomaly, in contrast with the northern Sikhote‐Alin volcano–plutonic belt dominated by oxidized‐type rocks and gold mineralization. The northern end of the Khingan‐Okhotsk belt near the Sea of Okhotsk, accompanied by positive geomagnetic anomalies, may have been overprinted by magmatism of the Sikhote‐Alin belt. Tin–associated magmatism in the Khingan‐Okhotsk belt extending over 400 km occurred episodically in a short period (9510 Ma) in the middle Cretaceous time, which is coeval with the accretion of the Kiselevka‐Manoma complex, the youngest accretionary wedge in the eastern margin of the Khingan‐Okhotsk accretionary terranes. The episodic magmatism is in contrast with the Cretaceous‐Paleogene long–lasted magmatism in Sikhote–Alin, indicating the two belts are essentially different arcs, rather than juxtaposed arcs derived from a single arc. The tin‐associated magmatism may have been caused by the subduction of a young and hot back‐arc basin, which is inferred from oceanic plate stratigraphy of the coeval accre‐tionary complex and its heavy mineral assemblage of immature volcanic arc provenance. The subduction of the young basin may have resulted in dominance of the reduced‐type felsic magmas due to incorporation of carbonaceous sediments within the accretionary complex near the trench. Subsequently, the back‐arc basin may have been closed by the oblique collision of the accretionary terranes in Sikhote–Alin, which was subjected to the Late Cretaceous to Paleogene magmatism related to another younger subduction system. These processes could have proceeded under transpressional tectonic regime due to oblique subduction of the paleo‐Pacific plates under Eurasian continent.     

Variations in trace elements,isotopes, and organic geochemistry during the Hangenberg Crisis,Devonian–Carboniferous transition,northeastern Vietnam

The Hangenberg Crisis at the Devonian–Carboniferous boundary is known as a polyphase extinction event that affected more than 45 % of marine and terrestrial genera. As the cause of this event is still debated, analyses were carried out on sedimentary samples from the Devonian–Carboniferous Pho Han Formation in northeastern Vietnam to reconstruct the paleoenvironment around the time of this event using stable carbon isotopes; total sulfur; manganese; vanadium; molybdenum; and sedimentary organic matter, such as dibenzothiophenes, cadalene, and regular steranes. These geochemical signatures provide a high‐resolution redox history for this section and show that transgression‐driven high primary productivity, possibly enhanced by terrestrial input, caused severe oxygen depletion along the continental margin of the South China block during the Hangenberg Crisis.     

Geomorphology of subglacial volcanoes in the Azas Plateau, the Tuva Republic, Russia

The Azas Plateau volcanic field is located in the Tuva Republic of the Russian Federation. The compositions of the Azas Plateau volcanics include low-viscosity trachybasalt and basanite. Volcanic edifices of Middle-Late Pleistocene age are widely distributed in the southeastern part of the volcanic field. There are subglacial volcanoes among the volcanic edifices, and their formation coincided with extensive ancient glaciations in the region. The dominant subglacial volcanoes in the area are tuyas. The general shapes of the tuyas (flat-tops with steep sides) are due to eruptions into meltwater lakes and confinement of ice walls, and effusive subaerial eruptions of basaltic lavas. There are also non-flat-topped subglacial volcanoes and at least one subaerial volcanic edifice in the area. Degradation appears to have modified the primary shapes of the tuya edifices, and such processes seem to include failures of over-steepened slopes, gully formation due to stream runoff and debris flows, cirque/valley glaciation, and modification by rock glaciers. The estimated thicknesses of the ice sheets covering the subglacial volcanoes during their eruptions range 300–600 m on average.     

Electron density distribution of FeTiO<Subscript>3</Subscript> ilmenite under high pressure analyzed by MEM using single crystal diffraction intensities

Many of ilmenites ABO₃ compounds bearing transition elements have semiconductive, ferroelectric and antiferromagnetic properties. The high-pressure diffraction studies of FeTiO₃ have been conducted up to 8.2 GPa using synchrotron radiation in KEK at Tsukuba with diamond anvil cell. The compression mechanism of FeTiO₃ ilmenite has been investigated by the structure refinements converged to the reliable factors R = 0.05. The deformations of the FeO₆ and TiO₆ octahedra were reduced with increasing pressure. In order to elucidate the electric conductivity change with pressure, electron density distribution of ilmenite have been executed by maximum entropy method (MEM) using single-crystal diffraction intensity data. MEM based on F _obs(hkl) of FeTiO₃ clearly shows electron density in comparison with the difference Fourier synthesis based on F _obs(hkl) − F _calc(hkl). The radial distribution of the electron density indicates electron localization around the cation positions. The bonding electron density found in bond Fe–O and Ti–O is lowered with pressure. The isotropic temperature factors B _iso become smaller with increasing pressure. Nevertheless the thermal vibration is considerably restrained by the compression, the electric conductivity is enhanced with pressure. Neither charge transfer nor electron hopping between Fe and Ti along the c axis in FeTiO₃ is plausible under high pressure. But the electric conductivity due to electron super-exchange in Fe–Fe and Ti–Ti has been clarified by the MEM electron density distribution. The anisotropy in the electric conductivity has been clarified.     

Notes on non-marine bivalve Trigonioides (Trigonioides?) from the mid-Cretaceous Goshoura Group, Kyushu, Japan

Trigonioides goshourensis n. sp. and Trigonioides amakusensis Kikuchi and Tashiro occur in the late Albian Eboshi Formation of the Goshoura Group in Kyushu, Japan. These Albian species are characterized by three radial pseudocardinal teeth on the thick and wide hinge plate, and are probably ancestors of Cenomanian species of Trigonioides (Kumamotoa) with four radial pseudocardinal teeth. This chronological relation may be important for the correlation of non-marine Cretaceous strata in East Asia. In addition, the habitat of T. amakusensis is interpreted as estuarine tidal flats under brackish water conditions, although Trigonioides is generally a freshwater bivalve genus.