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31.
Guillermo M. MUÑOZ CARO Frans J. M. RIETMEIJER Virginia SOUZA‐EGIPSY Maria Pilar VALLES‐GONZÁLEZ 《Meteoritics & planetary science》2012,47(2):248-261
Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe2O3) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored. 相似文献
32.
Víctor Alcaraz‐González Fabián Azael Fregoso‐Sanchez Hugo Oscar Mendez‐Acosta Victor Gonzalez‐Alvarez 《洁净——土壤、空气、水》2013,41(12):1157-1164
In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances. 相似文献
33.
Travel behavior of the present generation of youths is being increasingly explored due to their relevance in shaping future accessibility needs and mobility habits. The present study offers an original perspective on this topic by identifying territorial disparities that emerge in youth mobility patterns in rural and urban areas. Unlike most previous research, we propose taking a global view on mobility by analyzing all trip purposes and transportation modes. This is conducted by analyzing a comprehensive mobility survey in the Barcelona Metropolitan Region, which provides data on mobility engagement, trip purposes, modal split, travel times and territorial differences. In general, youngsters account for larger daily travel times than older adults, present a higher attachment to public transportation and walk less on a daily basis. These differences are enhanced in rural territories, where while older adults overcome accessibility issues with higher use of the private vehicle, youngsters are more likely to invest larger travel times on transit. 相似文献
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37.
Xiang‐Jun Liu Zhong‐Ping Lai 《Boreas: An International Journal of Quaternary Research》2013,42(2):333-341
Sand wedges and ice‐wedge casts in the Qinghai Lake area on the northeastern Qinghai‐Tibetan Plateau (QTP) occur within alluvial gravel or river terrace deposits. In this study, we report the results of quartz Optically Stimulated Luminescence (OSL) dating of the infill of five relict sand wedges and one ice‐wedge cast. Combining our dating results with previously published luminescence ages of permafrost wedges in the Qinghai Lake area, we show that sand/ice wedges formed at c. 62 ka, c. 45 ka and between 30 and 15 ka, and that the mean annual air temperature (MAAT) was depressed by at least ～3°C relative to present during the sand/ice‐wedge formation periods. This new work is partially corroborated by post‐LGM proxy records from lakes and aeolian deposits reported from the northeastern QTP. It also significantly extends the palaeoenvironmental record in the region in the period before the LGM, when other proxy records are rare, allowing a better understanding of the palaeoenvironmental conditions on the northeastern QTP. 相似文献
38.
Luis Gómez‐Orellana Pablo Ramil‐Rego Castor Muñoz Sobrino 《Boreas: An International Journal of Quaternary Research》2013,42(3):729-744
This paper describes and discusses the palaeobotanical data obtained from organic levels of two exposed deposits on the Atlantic shore of the northwestern Iberian Peninsula. Radiocarbon dating assigns these levels to a period of marine regression at the end of MIS 3 and the beginning of the Last Glacial Maximum. The pollen record shows an initial predominance of tree taxa (mainly deciduous, including the presence of Fagus far from its current limit), followed by an episode of partial forest retraction related to the end of MIS 3 and the beginning of the Last Glacial Maximum. However, the presence of numerous tree taxa in the record, even during the cold intervals associated with Heinrich events, points to the existence of sheltered refugia for these species during this period, in keeping with the conclusions of recent reviews of the vegetation dynamics of this region for the Lateglacial and the Holocene. 相似文献
39.
Multi‐scale investigations aided by the discrete element method (DEM) play a vital role for current state‐of‐the‐art research on the elementary behaviour of granular materials. Similar to laboratory tests, there are three important aspects to be considered carefully, which are the proper stress/strain definition and measurement, the application of target loading paths and the designed experiment setup, to be addressed in the present paper. Considering the volume sensitive characteristics of granular materials, in the proposed technique, the deformation of the tested specimen is controlled and measured by deformation gradient tensor involving both the undeformed configuration and the current configuration. Definitions of Biot strain and Cauchy stress are adopted. The expressions of them in terms of contact forces and particle displacements, respectively, are derived. The boundary of the tested specimen consists of rigid massless planar units. It is suggested that the representative element uses a convex polyhedral (polygonal) shape to minimize possible boundary arching effects. General loading paths are described by directly specifying the changes in the stress/strain invariants or directions. Loading can be applied in the strain‐controlled mode by specifying the translations and rotations of the boundary units, or in the stress‐controlled mode by using a servo‐control mechanism, or in the combination of the two methods to realize mixed boundary conditions. Taking the simulation results as the natural consequences originated from a complex system, virtual experiments provide particle‐scale information database to conduct multi‐scale investigations for better understanding in granular material behaviours and possible development of the constitutive theories provided the qualitative similarity between the simulation results from virtual experiments and observations on real material behaviour. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
40.
The movement of chemicals through soil to groundwater is a major cause of degradation of water resources. In many cases, serious human and stock health implications are associated with this form of pollution. The study of the effects of different factors involved in transport phenomena can provide valuable information to find the best remediation approaches. Numerical models are increasingly being used for predicting or analyzing solute transport processes in soils and groundwater. This article presents the development of a stochastic finite element model for the simulation of contaminant transport through soils with the main focus being on the incorporation of the effects of soil heterogeneity in the model. The governing equations of contaminant transport are presented. The mathematical framework and the numerical implementation of the model are described. The comparison of the results obtained from the developed stochastic model with those obtained from a deterministic method and some experimental results shows that the stochastic model is capable of predicting the transport of solutes in unsaturated soil with higher accuracy than deterministic one. The importance of the consideration of the effects of soil heterogeneity on contaminant fate is highlighted through a sensitivity analysis regarding the variance of saturated hydraulic conductivity as an index of soil heterogeneity. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献